Electrical conductivity and dielectric relaxation studies of biocomposites based on green microcrystalline cellulose-reinforced vinyl resin matrix

2019 ◽  
Vol 53 (20) ◽  
pp. 2801-2808 ◽  
Author(s):  
L Kreit ◽  
I Bouknaitir ◽  
A Zyane ◽  
M El Hasnaoui ◽  
M E Achour ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Glass Transition ◽  
Microcrystalline Cellulose ◽  
Interfacial Polarization ◽  
Relaxation Frequency ◽  
Resin Matrix ◽  
Matrix Interface ◽  
Frequency Range ◽  
Low Frequencies ◽  
Dielectric Relaxations

The dielectric properties of biocomposite materials based on vinyl resin filled with microcrystalline cellulose, in the frequency range from 100 Hz to 1 MHz and in the temperature range from 280 to 400 K, are presented. Two dielectric relaxations were identified. The first one is attributed to the α-relaxation, associated with the glass transition of biocomposite, and the second one, appearing above the glass transition and at low frequencies, was identified as the interfacial polarization effect, which is attributed to the accumulation of charges at the cellulose microcrystalline/matrix interface. Furthermore, the thermal analysis of their relaxation frequency and the electrical conductivity behaviors showed that the activation energy of these composite is more pronounced for the temperatures above the glass transition temperature, suggesting that the interaction between MCC particles and polymeric matrix became significant with the increase of temperature.

scholarly journals A Study on the Dielectric Behaviour of Epoxy/Hafnium Oxide Nanopowder Composites

2011 ◽  
Vol 20 (5) ◽  
pp. 096369351102000 ◽  
Author(s):  
S.N. Georga
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Permittivity ◽  
High Temperatures ◽  
High Frequency ◽  
Dielectric Response ◽  
Hafnium Oxide ◽  
Filler Concentration ◽  
High Frequency Range ◽  
Frequency Range ◽  
Low Frequencies

The dielectric response of 10 and 15phr epoxy/HfO2 nanocomposite systems has been studied in a wide frequency and temperature range. The experimental results show an enhancement of the dielectric permittivity with increasing filler concentration. The dielectric spectra reveal the presence of α-relaxation and a weak MWS effect. In the high frequency range the real part of the electrical conductivity obeys the Universal Dielectric Response (UDR), whereas at low frequencies and high temperatures DC conductivity is observed. VFT (Vogel-Fulcher-Tamann) parameters are calculated for all measured specimens.

A waveform inversion technique for measuring elastic wave attenuation in cylindrical bars

Geophysics ◽  
1992 ◽  
Vol 57 (6) ◽  
pp. 854-859 ◽  
Author(s):  
Xiao Ming Tang
Keyword(s):  
Elastic Wave ◽  
Wave Attenuation ◽  
Waveform Inversion ◽  
Finite Size ◽  
Low Frequency ◽  
Frequency Range ◽  
Multiple Reflections ◽  
Low Frequencies ◽  
The Time Domain ◽  
Attenuation Values

A new technique for measuring elastic wave attenuation in the frequency range of 10–150 kHz consists of measuring low‐frequency waveforms using two cylindrical bars of the same material but of different lengths. The attenuation is obtained through two steps. In the first, the waveform measured within the shorter bar is propagated to the length of the longer bar, and the distortion of the waveform due to the dispersion effect of the cylindrical waveguide is compensated. The second step is the inversion for the attenuation or Q of the bar material by minimizing the difference between the waveform propagated from the shorter bar and the waveform measured within the longer bar. The waveform inversion is performed in the time domain, and the waveforms can be appropriately truncated to avoid multiple reflections due to the finite size of the (shorter) sample, allowing attenuation to be measured at long wavelengths or low frequencies. The frequency range in which this technique operates fills the gap between the resonant bar measurement (∼10 kHz) and ultrasonic measurement (∼100–1000 kHz). By using the technique, attenuation values in a PVC (a highly attenuative) material and in Sierra White granite were measured in the frequency range of 40–140 kHz. The obtained attenuation values for the two materials are found to be reliable and consistent.

Dynamic Viscoelastic Properties of SBS Modified Asphalt Based on DSR Testing

2012 ◽  
Vol 598 ◽  
pp. 473-476 ◽  
Author(s):  
Yong Mei Guo ◽  
Wei Chen
Keyword(s):  
Complex Modulus ◽  
Superposition Principle ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Frequency Range ◽  
Master Curves ◽  
Temperature Property ◽  
Low Frequencies ◽  
High Temperature Property ◽  
Frequency Sweeps

Five SBS modified asphalts and one base asphalt were selected to carry out frequency sweeps over a wider frequency range using the dynamic shear rheometer (DSR). Six asphalt binders were subjected to sinusoidal loading at 30°C-90°C within the linear viscoelastic limits, and master curves of complex modulus (G*) and phase angle (δ) could be constructed by means of the time-temperature superposition principle (TTSP). The results show that the G* values of SBS modified asphalts are significantly greater than those of base asphalt at low frequencies, but are slightly smaller at high frequencies. Compared with the base asphalt, SBS modified asphalts have narrower master curves of complex modulus, and their phase angles are much smaller within the whole frequency range. This indicates that various properties of SBS modified asphalts, such as high-temperature property, low-temperature property, temperature susceptibility and elastic recoverability, are superior to those of the base asphalt. The G* values of the rolling thin-film oven (RTFO) aged asphalt are larger than those of the unaged asphalt in the whole range of frequencies, demonstrating that the anti-rutting performance of asphalt binder is improved after short-term aging.

Optimally Sensitive and Efficient Compact Loudspeakers for Low Audio Frequencies

2007 ◽  
Vol 38 (7) ◽  
pp. 11-17
Author(s):  
Ronald M. Aarts
Keyword(s):  
Optimality Criterion ◽  
Low Frequency ◽  
Audio Signal ◽  
Design Procedure ◽  
Frequency Range ◽  
Force Factor ◽  
Low Frequencies ◽  
Limited Frequency ◽  
The Cost ◽  
Higher Sensitivity

Conventionally, the ultimate goal in loudspeaker design has been to obtain a flat frequency response over a specified frequency range. This can be achieved by carefully selecting the main loudspeaker parameters such as the enclosure volume, the cone diameter, the moving mass and the very crucial “force factor”. For loudspeakers in small cabinets the results of this design procedure appear to be quite inefficient, especially at low frequencies. This paper describes a new solution to this problem. It consists of the combination of a highly non-linear preprocessing of the audio signal and the use of a so called low-force-factor loudspeaker. This combination yields a strongly increased efficiency, at least over a limited frequency range, at the cost of a somewhat altered sound quality. An analytically tractable optimality criterion has been defined and has been verified by the design of an experimental loudspeaker. This has a much higher efficiency and a higher sensitivity than current low-frequency loudspeakers, while its cabinet can be much smaller.

Application of bandlimited anelastic models to wave propagation in highly attenuative media

1995 ◽  
Vol 85 (5) ◽  
pp. 1359-1372
Author(s):  
Hsi-Ping Liu
Keyword(s):  
Wave Propagation ◽  
Quality Factor ◽  
Lower Limit ◽  
Relaxation Function ◽  
Function Approach ◽  
Creep Function ◽  
Frequency Range ◽  
Quality Factors ◽  
Low Frequencies ◽  
Near Surface

Abstract Because of its simple form, a bandlimited, four-parameter anelastic model that yields nearly constant midband Q for low-loss materials is often used for calculating synthetic seismograms. The four parameters used in the literature to characterize anelastic behavior are τ1, τ2, Qm, and MR in the relaxation-function approach (s1 = 1/τ1 and s2 = 1/τ2 are angular frequencies defining the bandwidth, MR is the relaxed modulus, and Qm is approximately the midband quality factor when Qm ≫ 1); or τ1, τ2, Qm, and MR in the creep-function approach (s1 = 1/τ1 and s2 = 1/τ2 are angular frequencies defining the bandwidth, and Qm is approximately the midband quality factor when Qm ≫ 1). In practice, it is often the case that, for a particular medium, the quality factor Q(ω0) and phase velocity c(ω0) at an angular frequency ω0 (s1 < ω0 < s2; s1 < ω0 < s2) are known from field measurements. If values are assigned to τ1 and τ2 (τ2 < τ1), or to τ1 and τ2 (τ2 < τ1), then the two remaining parameters, Qm and MR, or Qm and MR, can be obtained from Q(ω0). However, for highly attenuative media, e.g., Q(ω0) ≦ 5, Q(ω) can become highly skewed and negative at low frequencies (for the relaxation-function approach) or at high frequencies (for the creep-function approach) if this procedure is followed. A negative Q(ω) is unacceptable because it implies an increase in energy for waves propagating in a homogeneous and attenuative medium. This article shows that given (τ1, τ2, ω0) or (τ1, τ2, ω0), a lower limit of Q(ω0) exists for a bandlimited, four-parameter anelastic model. In the relaxation-function approach, the minimum permissible Q(ω0) is given by ln [(1 + ω20τ21)/(1 + ω20τ22)]/{2 arctan [ω0(τ1 − τ2)/(1 + ω20τ1τ2)]}. In the creep-function approach, the minimum permissible Q(ω0) is given by {2 ln (τ1/τ2) − ln [(1 + ω20τ21)/(1 + ω20τ22)]}/{2 arctan [ω0(τ1 − τ2)/(1 + ω20τ1τ2)]}. The more general statement that, for a given set of relaxation mechanisms, a lower limit exists for Q(ω0) is also shown to hold. Because a nearly constant midband Q cannot be achieved for highly attenuative media using a four-parameter anelastic model, a bandlimited, six-parameter anelastic model that yields a nearly constant midband Q for such media is devised; an expression for the minimum permissible Q(ω0) is given. Six-parameter anelastic models with quality factors Q ∼ 5 and Q ∼ 16, constant to 6% over the frequency range 0.5 to 200 Hz, illustrate this result. In conformity with field observations that Q(ω) for near-surface earth materials is approximately constant over a wide frequency range, the bandlimited, six-parameter anelastic models are suitable for modeling wave propagation in highly attenuative media for bandlimited time functions in engineering and exploration seismology.

Effects of material texture and packing density on the interfacial polarization of granular soils

Geophysics ◽  
2021 ◽  
pp. 1-58
Author(s):  
Hang Chen ◽  
Qifei Niu
Keyword(s):  
Electrical Conductivity ◽  
Packing Density ◽  
Characteristic Frequency ◽  
Effective Permittivity ◽  
Scale Up ◽  
Interfacial Polarization ◽  
Granular Soils ◽  
Geologic Materials ◽  
Effective Electrical Conductivity ◽  
Material Texture

Many electrical and electromagnetic (EM) methods operate at MHz frequencies, at which the interfacial polarization occurring at the solid-liquid interface in geologic materials may dominate the electrical signals. To correctly interpret electrical/EM measurements, it is therefore critical to understand how the interfacial polarization influences the effective electrical conductivity and permittivity spectra of geologic materials. We have used pore-scale simulation to study the role of material texture and packing in interfacial polarization in water-saturated granular soils. Synthetic samples with varying material textures and packing densities are prepared with the discrete element method. The effective electrical conductivity and permittivity spectra of these samples are determined by numerically solving the Laplace equation in a representative elementary volume of the samples. The numerical results indicate that the effective permittivity of granular soils increases as the frequency decreases due to the polarizability enhancement from the interfacial polarization. The induced permittivity increment is mainly influenced by the packing state of the samples, increasing with the packing density. Material textures such as the grain shape and size distribution may also affect the permittivity increment, but their effects are less significant. The frequency characterizing the interfacial polarization (i.e., the characteristic frequency) is mainly related to the electrical contrast of the solid and water phases. The model based on the traditional differential effective medium (DEM) theory significantly underestimates the permittivity increment by a factor of more than two and overestimates the characteristic frequency by approximately 1 MHz. These inaccurate predictions are due to the fact that the electrical interactions between neighboring grains are not considered in the DEM theory. A simple empirical equation is suggested to scale up the theoretical depolarization factor of grains entering the DEM theory to account for the interaction of neighboring grains in granular soils.

scholarly journals Molecular Dynamics of Functional Azide-Containing Acrylic Films

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 859 ◽  
Author(s):  
Marta Carsí ◽  
Maria Sanchis ◽  
Saul Vallejos ◽  
Félix García ◽  
José García
Keyword(s):  
General Structure ◽  
Glassy State ◽  
Interfacial Polarization ◽  
Dielectric Analysis ◽  
Azide Group ◽  
Low Frequencies ◽  
Polarization Effects ◽  
Dynamic Mobility ◽  
Models Comparison ◽  
Ohmic Conductivity

A report on the syntheses, thermal, mechanical and dielectric characterizations of two novel polymeric acrylic materials with azide groups in their pendant structures is presented. Having the same general structure, these polymers differ in length of oxyethylene units in the pendant chain [-CONH-CH2CH2-(O-CH2CH2)nN3], where n is 1 (poly(N-(2-(2-azidoethoxy)ethyl)methacrylamide), PAzMa1) or 2 (poly(N-2-(2-(2-azidoethoxy)ethoxy)ethyl)methacrylamide), PAzMa2), leading with changes in their dynamics. As the thermal decomposition of the azide group is observed above 100 °C, dielectric analysis was carried out in the temperature range of −120 °C to 100 °C. Dielectric spectra of both polymers exhibit in the glassy state two relaxations labelled in increasing order of temperature as γ- and β-processes, respectively. At high temperatures and low frequencies, the spectra are dominated by ohmic conductivity and interfacial polarization effects. Both, dipolar and conductive processes were characterized by using different models. Comparison of the dielectric activity obtained for PAzMa1 and PAzMa2 with those reported for crosslinked poly(2-ethoxyethylmethacrylate) (CEOEMA) was performed. The analysis of the length of oxyethylene pendant chain and the effect of the methacrylate or methacrylamide nature on the dynamic mobility was analysed.

scholarly journals THE PECULIARITIES OF THE SOUND FIELD ENERGY DECAY IN A ROOM WITH THE USE OF DIFFERENT PULSED SOUND SOURCES/GARSO LAUKO ENERGIJOS SLOPIMO PATALPOJE YPATUMAI, NAUDOJANT SKIRTINGUS IMPULSINIUS GARSO ŠALTINIUS

1999 ◽  
Vol 5 (2) ◽  
pp. 135-140
Author(s):  
Vytautas Stauskis
Keyword(s):  
Noise Level ◽  
Sound Field ◽  
Maximum Energy ◽  
Reverberation Time ◽  
Frequency Range ◽  
Sound Sources ◽  
Low Frequencies ◽  
High Frequencies ◽  
The Difference ◽  
Field Decay

The paper deals with the differences between the energy created by four different pulsed sound sources, ie a sound gun, a start gun, a toy gun, and a hunting gun. A knowledge of the differences between the maximum energy and the minimum energy, or the signal-noise ratio, is necessary to correctly calculate the frequency dependence of reverberation time. It has been established by investigations that the maximum energy excited by the sound gun is within the frequency range of 250 to 2000 Hz. It decreases by about 28 dB at the low frequencies. The character of change in the energy created by the hunting gun differs from that of the sound gun. There is no change in the maximum energy within the frequency range of 63–100 Hz, whereas afterwards it increases with the increase in frequency but only to the limit of 2000 Hz. In the frequency range of 63–500 Hz, the energy excited by the hunting gun is lower by 15–30 dB than that of the sound gun. As frequency increases the difference is reduced and amounts to 5–10 dB. The maximum energy of the start gun is lower by 4–5 dB than that of the hunting gun in the frequency range of up to 1000 Hz, while afterwards the difference is insignificant. In the frequency range of 125–250 Hz, the maximum energy generated by the sound gun exceeds that generated by the hunting gun by 20 dB, that by the start gun by 25 dB, and that by the toy gun—by as much as 35 dB. The maximum energy emitted by it occupies a wide frequency range of 250 to 2000 Hz. Thus, the sound gun has an advantage over the other three sound sources from the point of view of maximum energy. Up until 500 Hz the character of change in the direct sound energy is similar for all types of sources. The maximum energy of direct sound is also created by the sound gun and it increases along with frequency, the maximum values being reached at 500 Hz and 1000 Hz. The maximum energy of the hunting gun in the frequency range of 125—500 Hz is lower by about 20 dB than that of the sound gun, while the maximum energy of the toy gun is lower by about 25 dB. The maximum of the direct sound energy generated by the hunting gun, the start gun and the toy gun is found at high frequencies, ie at 1000 Hz and 2000 Hz, while the sound gun generates the maximum energy at 500 Hz and 1000 Hz. Thus, the best results are obtained when the energy is emitted by the sound gun. When the sound field is generated by the sound gun, the difference between the maximum energy and the noise level is about 35 dB at 63 Hz, while the use of the hunting gun reduces the difference to about 20–22 dB. The start gun emits only small quantities of low frequencies and is not suitable for room's acoustical analysis at 63 Hz. At the frequency of 80 Hz, the difference between the maximum energy and the noise level makes up about 50 dB, when the sound field is generated by the sound gun, and about 27 dB, when it is generated by the hunting gun. When the start gun is used, the difference between the maximum signal and the noise level is as small as 20 dB, which is not sufficient to make a reverberation time analysis correctly. At the frequency of 100 Hz, the difference of about 55 dB between the maximum energy and the noise level is only achieved by the sound gun. The hunting gun, the start gun and the toy gun create the decrease of about 25 dB, which is not sufficient for the calculation of the reverberation time. At the frequency of 125 Hz, a sufficiently large difference in the sound field decay amounting to about 40 dB is created by the sound gun, the hunting gun and the start gun, though the character of the sound field curve decay of the latter is different from the former two. At 250 Hz, the sound gun produces a field decay difference of almost 60 dB, the hunting gun almost 50 dB, the start gun almost 40 dB, and the toy gun about 45 dB. At 500 Hz, the sound field decay is sufficient when any of the four sound sources is used. The energy difference created by the sound gun is as large as 70 dB, by the hunting gun 50 dB, by the start gun 52 dB, and by the toy gun 48 dB. Such energy differences are sufficient for the analysis of acoustic indicators. At the high frequencies of 1000 to 4000 Hz, all the four sound sources used, even the toy gun, produce a good difference of the sound field decay and in all cases it is possible to analyse the reverberation process at varied intervals of the sound level decay.

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