scholarly journals Adsorption of Water Vapor by Bare Soil in an Olive Grove in Southern Spain

2006 ◽  
Vol 7 (5) ◽  
pp. 1011-1027 ◽  
Author(s):  
A. Verhoef ◽  
A. Diaz-Espejo ◽  
J. R. Knight ◽  
L. Villagarcía ◽  
J. E. Fernández

Abstract Data for water vapor adsorption and evaporation are presented for a bare soil (sandy loam, clay content 15%) in a southern Spanish olive grove. Water losses and gains were measured using eight high-precision minilysimeters, placed around an olive tree, which had been irrigated until the soil reached field capacity (∼0.22 m3 m−3). They were subsequently left to dry for 10 days. A pair of lysimeters was situated at each of the main points of the compass (N, E, S, W), at a distance of 1 m (the inner set of lysimeters; ILS) and 2 m (the outer set of lysimeters; OLS), respectively, from the tree trunk. Distinct periods of moisture loss (evaporation) and moisture gain (vapor adsorption) could be distinguished for each day. Vapor adsorption often started just after noon and generally lasted until the (early) evening. Values of up to 0.7 mm of adsorbed water per day were measured. Adsorption was generally largest for the OLS (up to 100% more on a daily basis), and increased during the dry down. This was mainly the result of lower OLS surface soil moisture contents (period-average absolute difference ∼0.005 m3 m−3), as illustrated using various analyses employing a set of micrometeorological equations describing the exchange of water vapor between bare soil and the atmosphere. These analyses also showed that the amount of water vapor adsorbed by soils is very sensitive to changes in atmospheric forcing and surface variables. The use of empirical equations to estimate vapor adsorption is therefore not recommended.

Author(s):  
Hemant Mittal ◽  
Ali Al-Alili ◽  
Saeed M. Alhassan

Abstract Deliquescent salts have high water vapor adsorption capacity, but they dissolve in water by forming crystalline hydrates. That restricts their use in different water vapor adsorption applications. However, this limitation can be overcome by incorporating deliquescent salts within a polymer matrix which will keep the salt solution in place. Furthermore, if the polymer matrix used is also capable of adsorbing water vapor, it will further improve the overall performance of desiccant system. Therefore, in this work, we are proposing the synthesis and use of a highly effective new solid polymer desiccant material, i.e. superporous hydrogel (SPHs) of poly(sodium acrylate-co-acrylic acid (P(SA-co-AA)), and subsequently its composite with deliquescent salt, i.e. calcium chloride (CaCl2), to adsorb water vapors from humid air without the dissolution of the salt in the adsorbed water. Parental PAA-SPHs matrix alone exhibited an adsorption capacity of 1.02 gw/gads which increased to 3.35 gw/gads after incorporating CaCl2 salt in the polymer matrix. Both materials exhibited type-III adsorption isotherm and the experimental isotherm data fitted to the Guggenheim, Anderson and Boer (GAB) isotherm model. However, the adsorption kinetics followed linear driving force model which suggested that this extremely high adsorption capacity was due to the diffusion of water molecules into the interconnected pores of SPHs via capillary channels followed by the attachment of adsorbed water molecules to the CaCl2 salt present in the polymer matrix. Furthermore, the adsorbents were used successively for six cycles of adsorption with a very little loss in adsorption capacity. Therefore, the proposed polymer desiccant material overcomes the problem of dissolution of deliquescent salts and opens the doors for a new class of highly effective solid desiccant material.


Author(s):  
Aasif A. Dabbawala ◽  
K. Suresh kumar Reddy ◽  
Hemant Mittal ◽  
Yasser Al Wahedi ◽  
Balasubramanian V. Vaithilingam ◽  
...  

Fuel ◽  
2017 ◽  
Vol 197 ◽  
pp. 326-333 ◽  
Author(s):  
Cheng Wang ◽  
Qi Liu ◽  
Douglas G. Ivey ◽  
Thomas H. Etsell

2006 ◽  
Vol 32 (2) ◽  
pp. 186-189 ◽  
Author(s):  
Jun Kobayashi ◽  
Takahiro Imamura ◽  
Masaaki Ichikawa ◽  
Mitsuhiro Kubota ◽  
Fujio Watanabe ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document