scholarly journals Mixing and Chemical Ozone Loss during and after the Antarctic Polar Vortex Major Warming in September 2002

2005 ◽  
Vol 62 (3) ◽  
pp. 848-859 ◽  
Author(s):  
Paul Konopka ◽  
Jens-Uwe Grooß ◽  
Karl W. Hoppel ◽  
Hildegard-Maria Steinhorst ◽  
Rolf Müller
Keyword(s):  
Potential Temperature ◽  
Polar Vortex ◽  
Vertical Shear ◽  
Lagrangian Model ◽  
Ozone Loss ◽  
Time Period ◽  
The Difference ◽  
Antarctic Polar Vortex ◽  
The Antarctic ◽  
Vortex Split

Abstract The 3D version of the Chemical Lagrangian Model of the Stratosphere (CLAMS) is used to study the transport of CH4 and O3 in the Antarctic stratosphere between 1 September and 30 November 2002, that is, over the time period when unprecedented major stratospheric warming in late September split the polar vortex into two parts. The isentropic and cross-isentropic velocities in CLAMS are derived from ECMWF winds and heating/cooling rates calculated with a radiation module. The irreversible part of transport, that is, mixing, is driven by the local horizontal strain and vertical shear rates with mixing parameters deduced from in situ observations. The CH4 distribution after the vortex split shows a completely different behavior above and below 600 K. Above this potential temperature level, until the beginning of November, a significant part of vortex air is transported into the midlatitudes up to 40°S. The lifetime of the vortex remnants formed after the vortex split decreases with the altitude with values of about 3 and 6 weeks at 900 and 700 K, respectively. Despite this enormous dynamical disturbance of the vortex, the intact part between 400 and 600 K that “survived” the major warming was strongly isolated from the extravortex air until the end of November. According to CLAMS simulations, the air masses within this part of the vortex did not experience any significant dilution with the midlatitude air. By transporting ozone in CLAMS as a passive tracer, the chemical ozone loss was estimated from the difference between the observed [Polar Ozone and Aerosol Measurement III (POAM III) and Halogen Occultation Experiment (HALOE)] and simulated ozone profiles. Starting from 1 September, up to 2.0 ppmv O3 around 480 K and about 70 Dobson units between 450 and 550 K were destroyed until the vortex was split. After the major warming, no additional ozone loss can be derived, but in the intact vortex part between 450 and 550 K, the accumulated ozone loss was “frozen in” until the end of November.

scholarly journals Ozone Chemistry during the 2002 Antarctic Vortex Split

2005 ◽  
Vol 62 (3) ◽  
pp. 860-870 ◽  
Author(s):  
Jens-Uwe Grooß ◽  
Paul Konopka ◽  
Rolf Müller
Keyword(s):  
Ozone Depletion ◽  
Polar Region ◽  
Polar Vortex ◽  
Dilution Effect ◽  
Lagrangian Model ◽  
Chemical Effect ◽  
Small Scale ◽  
Air Masses ◽  
Antarctic Polar Vortex ◽  
The Antarctic

Abstract In September 2002, the Antarctic polar vortex was disturbed, and it split into two parts caused by an unusually early stratospheric major warming. This study discusses the chemical consequences of this event using the Chemical Lagrangian Model of the Stratosphere (CLaMS). The chemical initialization of the simulation is based on Halogen Occultation Experiment (HALOE) measurements. Because of its Lagrangian nature, CLaMS is well suited for simulating the small-scale filaments that evolve during this period. Filaments of vortex origin in the midlatitudes were observed by HALOE several times in October 2002. The results of the simulation agree well with these HALOE observations. The simulation further indicates a very rapid chlorine deactivation that is triggered by the warming associated with the split of the vortex. Correspondingly, the ozone depletion rates in the polar vortex parts rapidly decrease to zero. Outside the polar vortex, where air masses of midlatitude origin were transported to the polar region, the simulation shows high ozone depletion rates at the 700-K level caused mainly by NOx chemistry. Owing to the major warming in September 2002, ozone-poor air masses were transported into the midlatitudes and caused a decrease of midlatitude ozone by 5%–15%, depending on altitude. Besides this dilution effect, there was no significant additional chemical effect. The net chemical ozone depletion in air masses of vortex origin was low and did not differ significantly from that of midlatitude air, in spite of the different chemical composition of the two types of air masses.

scholarly journals Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 1: A global climatology

2009 ◽  
Vol 9 (18) ◽  
pp. 7031-7044 ◽  
Author(s):  
J. Urban ◽  
M. Pommier ◽  
D. P. Murtagh ◽  
M. L. Santee ◽  
Y. J. Orsolini
Keyword(s):  
Nitric Acid ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Data Sets ◽  
High Latitudes ◽  
Vertical Range ◽  
Spatial And Seasonal Variation ◽  
Antarctic Polar Vortex ◽  
Different Characteristics ◽  
The Antarctic

Abstract. The Sub-Millimetre Radiometer (SMR) on board the Odin satellite, launched in February 2001, observes thermal emissions of stratospheric nitric acid (HNO3) originating from the Earth limb in a band centred at 544.6 GHz. Height-resolved measurements of the global distribution of nitric acid in the stratosphere were performed approximately on two observation days per week. An HNO3 climatology based on more than 7 years of observations from August 2001 to April 2009 covering the vertical range between typically ~19 and 45 km (~1.5–60 hPa or ~500–1800 K in terms of potential temperature) was created. The study highlights the spatial and seasonal variation of nitric acid in the stratosphere, characterised by a pronounced seasonal cycle at middle and high latitudes with maxima during late fall and minima during spring, strong denitrification in the lower stratosphere of the Antarctic polar vortex during winter (the irreversible removal of NOy by the sedimentation of cloud particles containing HNO3), as well as large quantities of HNO3 formed every winter at high-latitudes in the middle and upper stratosphere. A strong inter-annual variability is observed in particular at high latitudes. A comparison with a stratospheric HNO3 climatology, based on over 7 years of UARS/MLS (Upper Atmosphere Research Satellite/Microwave Limb Sounder) measurements from the 1990s, shows good consistency and agreement of the main morphological features in the potential temperature range ~465 to ~960 K, if the different characteristics of the data sets such as the better altitude resolution of Odin/SMR as well as the slightly different altitude ranges are considered. Odin/SMR reaches higher up and UARS/MLS lower down in the stratosphere. An overview from 1991 to 2009 of stratospheric nitric acid is provided (with a short gap between 1998 and 2001), if the global measurements of both experiments are taken together.

scholarly journals Chemical ozone loss in Arctic and Antarctic polar winter/spring season derived from SCIAMACHY limb measurements 2002–2009

2011 ◽  
Vol 11 (2) ◽  
pp. 6555-6599 ◽  
Author(s):  
T. Sonkaew ◽  
C. von Savigny ◽  
K.-U. Eichmann ◽  
M. Weber ◽  
A. Rozanov ◽  
...  
Keyword(s):  
Mass Loss ◽  
Total Ozone ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
The Arctic ◽  
Absorption Bands ◽  
Data Set ◽  
Ozone Loss ◽  
The Difference ◽  
The Antarctic

Abstract. Stratospheric ozone profiles are retrieved for the period 2002–2009 from SCIAMACHY measurements of limb-scattered solar radiation in the Hartley and Chappuis absorption bands of ozone. This data set is used to determine the chemical ozone loss in both the Arctic and Antarctic polar vortices using the vortex average method. The chemical ozone loss at isentropic levels between 450 K and 600 K is derived from the difference between observed ozone abundances and the ozone modelled considering diabatic cooling, but no chemical ozone loss. The results show chemical ozone losses of up to 20–40% between the beginning of January and the end of March inside the Arctic polar vortex. Strong inter-annual variability of the Arctic ozone loss is observed, with the cold winters 2004/2005 and 2006/2007 showing the largest chemical ozone losses. The ozone mass loss inside the polar vortex is also estimated. In the coldest Arctic winter 2004/2005 the total ozone mass loss is about 30 million tons inside the polar vortex between the 450 K and 600 K isentropic levels from the beginning of January until the end of March. The Antarctic vortex averaged ozone loss as well as the size of the polar vortex do not vary much from year to year. At the 475 K isentropic level ozone losses of 70–80% between mid-August and mid-November are observed every year inside the vortex, also in the anomalous year 2002. The total ozone mass loss inside the Antarctic polar vortex between the 450 K and 600 K isentropic levels is about 55–75 million tons for the period between mid-August and mid-November. Comparisons of the vertical variation of ozone loss derived from SCIAMACHY observations with several independent techniques for the Arctic winter 2004/2005 show very good agreement.

Longitudinally Dependent Ozone Increase in the Antarctic Polar Vortex Revealed by Balloon and Satellite Observations

2009 ◽  
Vol 66 (6) ◽  
pp. 1807-1820 ◽  
Author(s):  
K. Sato ◽  
Y. Tomikawa ◽  
G. Hashida ◽  
T. Yamanouchi ◽  
H. Nakajima ◽  
...  
Keyword(s):  
Potential Temperature ◽  
Polar Vortex ◽  
Mixing Ratio ◽  
Vertical Movements ◽  
Horizontal Structure ◽  
Vertical Coordinate ◽  
Zonal Wavenumber ◽  
Lateral Mixing ◽  
Antarctic Polar Vortex ◽  
The Antarctic

Abstract The horizontal structure of processes causing increases in ozone in the Antarctic polar vortex was examined using data measured in 2003 from an ozonesonde observation campaign at Syowa Station (39.6°E, 69.0°S) and from the Improved Limb Atmospheric Spectrometer II (ILAS-II) onboard the Advanced Earth Observing Satellite II. The ILAS-II data are daily and distributed uniformly at 14 points in the zonal direction, mostly at polar latitudes. The Antarctic ozone hole that developed in 2003 was one of the largest recorded. The period of focus in this study is 26 September through 24 October, when a strong polar vortex was situated in the stratosphere. An ozone mixing ratio contour (1.0 ppmv) moved downward near a height of 20 km during the period of focus. This increase in ozone is likely to result from downward transport of ozone-rich air originating from lower latitudes by Brewer–Dobson circulation. First, the descent rate of the mixing ratio contour was estimated by taking the geometric height as the vertical coordinate for the deep vortex interior around 20 km. A significant longitudinal dependence was observed. An analysis using ECMWF operational data shows that this dependence can be approximately explained by longitudinally dependent vertical movements of the isentropes caused by a zonal wavenumber-1 quasi-stationary planetary wave with amplitude and phases varying on a seasonal time scale. Next, the descent rate was calculated around 500 K (around 20 km) by taking the potential temperature (isentrope) as the vertical coordinate. The longitudinal dependence was still present using this coordinate, meaning that the ozone mixing ratio and its increase are not constant on the isentropic layer even in the interior of the polar vortex. A backward trajectory analysis showed that air parcels with large ozone mixing ratios were mostly transported from the polar vortex boundary region. This result suggests that lateral transport/mixing is important even before the breakup of the polar vortex. Results from a tracer–tracer correlation analysis of O3 and long-lived constituent N2O were also consistent with this inference. The contribution of lateral mixing to the increase in ozone was estimated at about 17% ± 4% that of the Brewer–Dobson circulation around 20 km, using the calculated descent rates. The results of this study also imply that Lagrangian downward motions in the vortex interior are not correctly estimated without accounting for lateral mixing, even if the polar vortex is dynamically stable.

scholarly journals On the discrepancy of HCl processing in the core of the wintertime polar vortices

2018 ◽  
Vol 18 (12) ◽  
pp. 8647-8666 ◽  
Author(s):  
Jens-Uwe Grooß ◽  
Rolf Müller ◽  
Reinhold Spang ◽  
Ines Tritscher ◽  
Tobias Wegner ◽  
...  
Keyword(s):  
Cosmic Rays ◽  
Polar Vortex ◽  
Galactic Cosmic Rays ◽  
Lagrangian Model ◽  
The Arctic ◽  
Late Winter ◽  
Model Simulations ◽  
Ozone Loss ◽  
The Antarctic ◽  
Eulerian Models

Abstract. More than 3 decades after the discovery of the ozone hole, the processes involved in its formation are believed to be understood in great detail. Current state-of-the-art models can reproduce the observed chemical composition in the springtime polar stratosphere, especially regarding the quantification of halogen-catalysed ozone loss. However, we report here on a discrepancy between simulations and observations during the less-well-studied period of the onset of chlorine activation. During this period, which in the Antarctic is between May and July, model simulations significantly overestimate HCl, one of the key chemical species, inside the polar vortex during polar night. This HCl discrepancy is also observed in the Arctic. The discrepancy exists in different models to varying extents; here, we discuss three independent ones, the Chemical Lagrangian Model of the Stratosphere (CLaMS) as well as the Eulerian models SD-WACCM (the specified dynamics version of the Whole Atmosphere Community Climate Model) and TOMCAT/SLIMCAT. The HCl discrepancy points to some unknown process in the formulation of stratospheric chemistry that is currently not represented in the models. We characterise the HCl discrepancy in space and time for the Lagrangian chemistry–transport model CLaMS, in which HCl in the polar vortex core stays about constant from June to August in the Antarctic, while the observations indicate a continuous HCl decrease over this period. The somewhat smaller discrepancies in the Eulerian models SD-WACCM and TOMCAT/SLIMCAT are also presented. Numerical diffusion in the transport scheme of the Eulerian models is identified to be a likely cause for the inter-model differences. Although the missing process has not yet been identified, we investigate different hypotheses on the basis of the characteristics of the discrepancy. An underestimated HCl uptake into the polar stratospheric cloud (PSC) particles that consist mainly of H2O and HNO3 cannot explain it due to the temperature correlation of the discrepancy. Also, a direct photolysis of particulate HNO3 does not resolve the discrepancy since it would also cause changes in chlorine chemistry in late winter which are not observed. The ionisation caused by galactic cosmic rays provides an additional NOx and HOx source that can explain only about 20 % of the discrepancy. However, the model simulations show that a hypothetical decomposition of particulate HNO3 by some other process not dependent on the solar elevation, e.g. involving galactic cosmic rays, may be a possible mechanism to resolve the HCl discrepancy. Since the discrepancy reported here occurs during the beginning of the chlorine activation period, where the ozone loss rates are small, there is only a minor impact of about 2 % on the overall ozone column loss over the course of Antarctic winter and spring.

scholarly journals Antarctic air over New Zealand following vortex breakdown in 1998

2003 ◽  
Vol 21 (11) ◽  
pp. 2175-2183 ◽  
Author(s):  
J. Ajtic ◽  
B. J. Connor ◽  
C. E. Randall ◽  
B. N. Lawrence ◽  
G. E. Bodeker ◽  
...  
Keyword(s):  
New Zealand ◽  
Middle Atmosphere ◽  
Vortex Breakdown ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Atmospheric Composition ◽  
Composition And Structure ◽  
Ozone Profile ◽  
Antarctic Polar Vortex ◽  
The Antarctic

Abstract. An ozonesonde profile over the Network for Detection of Stratospheric Change (NDSC) site at Lauder (45.0° S, 169.7° E), New Zealand, for 24 December 1998 showed atypically low ozone centered around 24 km altitude (600 K potential temperature). The origin of the anomaly is explained using reverse domain filling (RDF) calculations combined with a PV/O3 fitting technique applied to ozone measurements from the Polar Ozone and Aerosol Measurement (POAM) III instrument. The RDF calculations for two isentropic surfaces, 550 and 600 K, show that ozone-poor air from the Antarctic polar vortex reached New Zealand on 24–26 December 1998. The vortex air on the 550 K isentrope originated in the ozone hole region, unlike the air on 600 K where low ozone values were caused by dynamical effects. High-resolution ozone maps were generated, and their examination shows that a vortex remnant situated above New Zealand was the cause of the altered ozone profile on 24 December. The maps also illustrate mixing of the vortex filaments into southern midlatitudes, whereby the overall mid-latitude ozone levels were decreased.Key words. Atmospheric composition and structure (middle atmosphere composition and chemistry) – Meteorology and atmospheric dynamics (middle atmosphere dynamics)

scholarly journals Nitric acid in the stratosphere based on Odin observations from 2001 to 2007 – Part 1: A global climatology

2008 ◽  
Vol 8 (3) ◽  
pp. 9569-9590 ◽  
Author(s):  
J. Urban ◽  
M. Pommier ◽  
D. P. Murtagh ◽  
M. L. Santee ◽  
Y. J. Orsolini
Keyword(s):  
Nitric Acid ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Data Sets ◽  
High Latitudes ◽  
Thermal Emissions ◽  
Spatial And Seasonal Variation ◽  
Antarctic Polar Vortex ◽  
Different Characteristics ◽  
The Antarctic

Abstract. The Sub-Millimetre Radiometer (SMR) on board the Odin satellite, launched in February 2001, observes thermal emissions of stratospheric nitric acid (HNO3) originating from the Earth limb in a band centred at 544.6 GHz. Height-resolved measurements of the global distribution of nitric acid in the stratosphere between ~18–45 km (~1.5–60 hPa) were performed approximately on two observation days per week. An HNO3 climatology based on roughly 6 years of observations from August 2001 to December 2007 was created. The study highlights the spatial and seasonal variation of nitric acid in the stratosphere, characterised by a pronounced seasonal cycle at middle and high latitudes with maxima during late fall and minima during spring, strong denitrification in the lower stratosphere of the Antarctic polar vortex during winter (the irreversible removal of NOy by the sedimentation of cloud particles containing HNO3), as well as high quantities of HNO3 formed every winter at high-latitudes in the middle and upper stratosphere. A strong inter-annual variability is observed in particular at high latitudes. A comparison with a stratospheric HNO3 climatology based on UARS/MLS measurements from the 1990s shows a good consistency and agreement of the main morphological features in the potential temperature range ~465 to ~960 K, if the different characteristics of the data sets such as altitude range and resolution are considered.

scholarly journals Antarctic ozone loss in 1989–2010: evidence for ozone recovery?

2012 ◽  
Vol 12 (4) ◽  
pp. 10775-10814 ◽  
Author(s):  
J. Kuttippurath ◽  
F. Lefèvre ◽  
J.-P. Pommereau ◽  
H. K. Roscoe ◽  
F. Goutail ◽  
...  
Keyword(s):  
Confidence Intervals ◽  
Polar Vortex ◽  
Ozone Monitoring Instrument ◽  
Ozone Loss ◽  
Ozone Trends ◽  
Antarctic Ozone ◽  
Ozone Monitoring ◽  
Antarctic Polar Vortex ◽  
Scanning Imaging ◽  
The Antarctic

Abstract. We present a detailed estimation of chemical ozone loss in the Antarctic polar vortex from 1989 to 2010. The analyses include ozone loss estimates for 12 Antarctic ground-based (GB) stations. All GB observations show minimum ozone in the late September–early October period. Among the stations, the lowest minimum ozone values are observed at South Pole and the highest at Dumont d'Urville. The ozone loss starts by mid-June at the vortex edge and then progresses towards the vortex core with time. The loss intensifies in August–September, peaks by the end of September–early October, and recovers thereafter. The average ozone loss in the Antarctic is revealed to be about 33–50% in 1989–1992 in agreement with the increase in halogens during this period, and then stayed at around 48% due to saturation of the loss. The ozone loss in the warmer winters (e.g. 2002, and 2004) is lower (37–46%) and in the colder winters (e.g. 2003, and 2006) is higher (52–55%). Because of small inter-annual variability, the correlation between ozone loss and the volume of polar stratospheric clouds yields ~0.51. The GB ozone and ozone loss values are in good agreement with those found from the space-based observations of the Total Ozone Mapping Spectrometer/Ozone Monitoring Instrument (TOMS/OMI), the Global Ozone Monitoring Experiment (GOME), the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY), and the Aura Microwave Limb Sounder (MLS), where the differences are within ±5% and are mostly within the error bars of the measurements. The piece-wise linear trends computed from the September–November vortex average GB and TOMS/OMI ozone show about −4 to −5.6 DU (Dobson Unit) yr−1 in 1989–1996 and about +1 DU yr−1 in 1997–2010. The trend during the former period is significant at 95% confidence intervals, but the trend in 1997–2010 is significant only at 85% confidence intervals. Our analyses suggest a period of about 9–10 yr to get the first detectable ozone recovery signal at the 95% confidence intervals with the current ozone trends in the Antarctic. Thus, this study reveals that the recovery of the Antarctic ozone is well on course.

scholarly journals Chemical ozone losses in Arctic and Antarctic polar winter/spring season derived from SCIAMACHY limb measurements 2002–2009

2013 ◽  
Vol 13 (4) ◽  
pp. 1809-1835 ◽  
Author(s):  
T. Sonkaew ◽  
C. von Savigny ◽  
K.-U. Eichmann ◽  
M. Weber ◽  
A. Rozanov ◽  
...  
Keyword(s):  
Mass Loss ◽  
Total Ozone ◽  
Potential Temperature ◽  
Polar Vortex ◽  
The Arctic ◽  
Absorption Bands ◽  
Data Set ◽  
Ozone Loss ◽  
Annual Variability ◽  
The Antarctic

Abstract. Stratospheric ozone profiles are retrieved for the period 2002–2009 from SCIAMACHY measurements of limb-scattered solar radiation in the Hartley and Chappuis absorption bands of ozone. This data set is used to determine the chemical ozone losses in both the Arctic and Antarctic polar vortices by averaging the ozone in the vortex at a given potential temperature. The chemical ozone losses at isentropic levels between 450 K and 600 K are derived from the difference between observed ozone abundances and the ozone modelled taking diabatic cooling into account, but no chemical ozone loss. Chemical ozone losses of up to 30–40% between mid-January and the end of March inside the Arctic polar vortex are reported. Strong inter-annual variability of the Arctic ozone loss is observed, with the cold winters 2004/2005 and 2006/2007 showing chemical ozone losses inside the polar vortex at 475 K, where 1.7 ppmv and 1.4 ppmv of ozone were removed, respectively, over the period from 22 January to beginning of April and 0.9 ppmv and 1.2 ppmv, respectively, during February. For the winters of 2007/2008 and 2002/2003, ozone losses of about 0.8 ppmv and 0.4 ppmv, respectively are estimated at the 475 K isentropic level for the period from 22 January to beginning of April. Essentially no ozone losses were diagnosed for the relatively warm winters of 2003/2004 and 2005/2006. The maximum ozone loss in the SCIAMACHY data set was found in 2007 at the 600 K level and amounted to about 2.1 ppmv for the period between 22 January and the end of April. Enhanced losses close to this altitude were found in all investigated Arctic springs, in contrast to Antarctic spring. The inter-annual variability of ozone losses and PSC occurrence rates observed during Arctic spring is consistent with the known QBO effects on the Arctic polar vortex, with exception of the unusual Arctic winter 2008/2009. The maximum total ozone mass loss of about 25 million tons was found in the cold Arctic winter of 2004/2005 inside the polar vortex between the 450 K and 600 K isentropic levels from mid-January until the middle of March. The Antarctic vortex averaged ozone loss as well as the size of the polar vortex do not vary much from year to year. The total ozone mass loss inside the Antarctic polar vortex between the 450 K and 600 K isentropic levels is about 50–60 million tons and the vortex volume for this altitude range varies between about 150 and 300 km3 for the period between mid-August and mid-November of every year studied, except for 2002. In 2002 a mid-winter major stratospheric warming occurred in the second half of September and the ozone mass loss was only about half of the value in the other years. However, inside the polar vortex we find chemical ozone losses at the 475 K isentropic level that are similar to those in all other years studied. At this isentropic level ozone losses of 70–90% between mid-August and mid-November or about 2.5 ppmv are observed every year. At isentropic levels above 500 K the chemical ozone losses were found to be larger in 2002 than in all other years studied. Comparisons of the vertical variation of ozone losses derived from SCIAMACHY observations with several independent techniques for the Arctic winter 2004/2005 show that the SCIAMACHY results fall in the middle of the range of previously published results for this winter. For other winters in both hemispheres – for which comparisons with other studies were possible – the SCIAMACHY results are consistent with the range of previously published results.

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