Synthesis of 1,4-Dihydropyridine as a Fluorescent and Colorimetric Chemosensor for Detection of Fe3+ Ion

2019 ◽  
Vol 17 (10) ◽  
pp. 747-754
Author(s):  
Zohreh Kheil Kordi ◽  
Ghodsi Mohammadi Ziarani ◽  
Alireza Badiei ◽  
Negar Lashgari

A new fluorescent and colorimetric sensor for Fe3+ ion were synthesized via four-component reaction of acetophenone, dimedone, benzaldehyde and ammonium acetate in the presence of SrFe12O19. The chemosensor shows excellent sensitivity toward Fe3+ ion. The sensing ability of the chemosensor was studied by fluorescent and UV-Vis spectroscopy. The detection limits for Fe3+ were calculated respectively about 8.3 × 10–6 M and 2.3 × 10–6 M for fluorescence and UV-Vis techniques.

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16586-16597 ◽  
Author(s):  
Ka Young Ryu ◽  
Jae Jun Lee ◽  
Jin Ah Kim ◽  
Dae Yul Park ◽  
Cheal Kim

New Schiff-base was developed as colorimetric sensor for Cu2+, CN−and S2−with the detection limits lower than the given guidelines.


Compounds ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 29-40
Author(s):  
Sutapa Sahu ◽  
Yeasin Sikdar ◽  
Riya Bag ◽  
Dilip K. Maiti ◽  
José P. Cerón-Carrasco ◽  
...  

This work presents the development of a quinoxaline and rhodamine conjugate system that acts as a colorimetric chemosensor for hydrogen sulfate (HSO4−) ions in methanol media. This sensor has been characterized both theoretically and experimentally. The detection limits for HSO4− are small as 0.71 µM and 3.8 µM for the absorption and emission experiments, respectively. The effectiveness of the probe in recognizing HSO4− both in gel and solid phase is evaluated as well. Thus, this works presents a simple strategy to detect the environmental HSO4− pollutant event at tiny concentrations.


2017 ◽  
Vol 5 (33) ◽  
pp. 8553-8558 ◽  
Author(s):  
Sangwan Kim ◽  
Sunjong Lee ◽  
Yejin Ahn ◽  
Hyun Ki Kim ◽  
Joonseok Koh ◽  
...  

A polydiacetylene-based colorimetric sensor was devised to detect malondialdehyde as a food spoilage indicator.


2008 ◽  
Vol 61 (4) ◽  
pp. 310 ◽  
Author(s):  
Zhi-Hong Chen ◽  
Yong-Bing He ◽  
Chen-Guang Hu ◽  
Xiao-Huan Huang ◽  
Ling Hu

Chiral colorimetric sensor 4 has been synthesized, and the structure characterized by IR and 1H NMR spectroscopy, mass spectrometry, and elemental analysis. The chiral recognition of the receptor was studied by 1H NMR and UV-vis spectroscopy. The results of non-linear curve fitting indicate that the receptor 4 and l- or d-mandelate and alanine anions form a 1:1 stoichiometric complex. The obvious colour change of receptor 4 can be observed by the naked eye when the enantiomers of mandelate and alanine anions are added, which demonstrates that receptor 4 may be used as the colorimetric sensor for the two carboxylic anions.


2020 ◽  
Vol 840 ◽  
pp. 385-391
Author(s):  
Trisno Afandi ◽  
Bambang Purwono ◽  
Winarto Haryadi

Chemosensor of imidazole derivative (4-(4,5-diphenyl-1H-imidazol-2-yl)-2-methoxy-6-nitrophenol) (IMD-1) has been synthesized and tested for amines sensor. IMD-1 was synthesized from the reaction of 5-nitrovanillin, 1,2-diphenylethane-1,2-dione (benzil), and ammonium acetate using reflux method. IMD-1 showed fast respond and color change from light orange to orange in naked eye compared with the imidazole derivative without nitro group (IMD-0). The IMD-1 could detect butylamine quantitatively with detection limit of 1.03 x 10-4 M.


RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30635-30645
Author(s):  
Shengliang Zhao ◽  
Liqiong Chen ◽  
Feiyan Liu ◽  
Yongyao Fan ◽  
Yiheng Liu ◽  
...  

A colorimetric sensor based on TADA–AuNPs accompanied by a masking agent DPC was constructed, with which the rapid quantification of Al3+ can be realized by UV-vis spectroscopy or naked eye observation.


2020 ◽  
Vol 44 (5) ◽  
pp. 1376-1385 ◽  
Author(s):  
Roomia MEMON ◽  
Ayaz Ali MEMON ◽  
Syed Tufail Hussain SHERAZI ◽  
Sirajuddin Sirajuddin ◽  
Aamna BALOUCH ◽  
...  

The presented work demonstrates the preparation of copper nanoparticles (CuNPs) via aqueous leaves extract of Ziziphus mauritiana L. (Zm) using hydrazine as a reducing agent. Various parameters such as volume of extract, concentration of hydrazine hydrate, concentration of copper chloride, and pH of the solution were optimized to obtain Ziziphus mauritiana L. leaves extract derived copper nanoparticles (Zm-CuNPs). Brownish red color was initial indication of the formation of Zm-CuNPs while it was confirmed by surface plasmon resonance (SPR) band at wavelength of 584 nm using ultraviolet-visible (UV-vis) spectroscopy. Synthesized Zm-CuNPs were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffractometry (XRD). AFM images showed that the particle size of Zm-CuNPs was from 7 to 17 nm with an average size of 11.3 nm. Fabricated sensor (Zm-CuNPs) were used as a colorimetric sensor for the detection of Ag+ at a linear range between 0.67 × 10–6 – 9.3 × 10–6 with R2 value of 0.992. For real water samples, limit of quantification (LOQ) and limit of detection (LOD) for Ag+ was found to be 330 × 10–9 and 100 × 10–9, respectively.


Chemosensors ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 7
Author(s):  
Muhammad Zulfajri ◽  
Ganesh Kumar Dhandabani ◽  
Hui-Fen Chen ◽  
Jeh-Jeng Wang ◽  
Genin Gary Huang

A dibenzo[b,j][1,10]phenanthroline (DBPhen) scaffold as a novel colorimetric Cu2+ sensor was proposed and prepared in this study. The optical properties of DBPhen were measured utilizing UV light, UV-VIS spectroscopy, and fluorescence spectroscopy. The findings denote that DBPhen exhibited a particular selectivity and great sensitivity to Cu2+ compared with other metal ions. The addition of Cu2+ in the DBPhen solution induced the color change from yellow to purple, and a new peak in the visible range (~545 nm) was observed. The detection limit of Cu2+ in the aqueous solution was calculated to be as low as 0.14 μM. Besides, the color change of the DBPhen/Cu2+ complex could be reversibly restored by adding CN−. Therefore, DBPhen could have a prospective implementation as a practical colorimetric sensor to detect Cu2+ ions in environmental fields.


RSC Advances ◽  
2020 ◽  
Vol 10 (73) ◽  
pp. 44860-44875
Author(s):  
Meman Sahu ◽  
Amit Kumar Manna ◽  
Shubhamoy Chowdhury ◽  
Goutam Kumar Patra

A novel colorimetric chemosensor L has been developed for the detection of Ni2+ and Cu2+ ions. The obtained L–Cu2+ complex can be used as a new cascade fluorescent-colorimetric sensor for the nanomolar detection of CN− ions. This chemosensor has practical application.


2017 ◽  
Vol 16 (11) ◽  
pp. 1677-1689 ◽  
Author(s):  
Min Seon Kim ◽  
Seong Youl Lee ◽  
Jae Min Jung ◽  
Cheal Kim

A new Schiff-base colorimetric chemosensor 1 with low detection limits was developed for the detection of Cu2+, Co2+ and S2−.


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