A Spectroscopic Study in Solution and Solid States: Synthesis, Spectroscopic and Thermal Studies on Intermolecular Charge-Transfer Complexes Associated with the In Situ Reaction of Triamterene Drug with σ- and π-Electron Acceptors

2019 ◽  
Vol 11 (9) ◽  
pp. 1241-1251
Author(s):  
Abeer A. El-Habeeb ◽  
Salma F. Al-Qahtani ◽  
Nouf F. Al-Suhaim ◽  
Amjad R. Al-Mukhalfi
Keyword(s):  
Charge Transfer ◽  
Spectroscopic Study ◽  
Thermal Studies ◽  
Electron Acceptors ◽  
Charge Transfer Complexes ◽  
In Situ Reaction ◽  
Solid States ◽  
Intermolecular Charge Transfer

scholarly journals Triphenylene‐Derived Electron Acceptors and Donors on Ag(111): Formation of Intermolecular Charge‐Transfer Complexes with Common Unoccupied Molecular States

Small ◽  
2019 ◽  
Vol 15 (33) ◽  
pp. 1901741 ◽  
Author(s):  
Kathrin Müller ◽  
Nico Schmidt ◽  
Stefan Link ◽  
René Riedel ◽  
Julian Bock ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electron Acceptors ◽  
Charge Transfer Complexes ◽  
Intermolecular Charge Transfer

scholarly journals An In-Situ Reaction Route to Molecular Level Dispersed Bisimide and ZnO Nanorod Hybrids with Efficient Photo-Induced Charge Transfer

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chunzheng Lv ◽  
Lirong He ◽  
Jiahong Tang ◽  
Feng Yang ◽  
Chuhong Zhang
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Self Assembly ◽  
Molecular Level ◽  
Surface Photovoltage ◽  
Zno Nanorod ◽  
In Situ Reaction ◽  
Perylene Bisimide ◽  
Induced Charge

AbstractAs an important photoconductive hybrid material, perylene/ZnO has attracted tremendous attention for photovoltaic-related applications, but generally faces a great challenge to design molecular level dispersed perylenes/ZnO nanohybrids due to easy phase separation between perylenes and ZnO nanocrystals. In this work, we reported an in-situ reaction method to prepare molecular level dispersed H-aggregates of perylene bisimide/ZnO nanorod hybrids. Surface photovoltage and electric field-induced surface photovoltage spectrum show that the photovoltage intensities of nanorod hybrids increased dramatically for 100 times compared with that of pristine perylene bisimide. The enhancement of photovoltage intensities resulting from two aspects: (1) the photo-generated electrons transfer from perylene bisimide to ZnO nanorod due to the electric field formed on the interface of perylene bisimide/ZnO; (2) the H-aggregates of perylene bisimide in ZnO nanorod composites, which is beneficial for photo-generated charge separation and transportation. The introduction of ordered self-assembly thiol-functionalized perylene-3,4,9,10-tetracarboxylic diimide (T-PTCDI)/ ZnO nanorod composites induces a significant improvement in incident photo-to-electron conversion efficiency. This work provides a novel mentality to boost photo-induced charge transfer efficiency, which brings new inspiration for the preparation of the highly efficient solar cell.

Spectroscopic Study of Charge Transfer Complexes of Biphenyl

2013 ◽  
Vol 577 (1) ◽  
pp. 127-142 ◽  
Author(s):  
Parimal Trivedi ◽  
D. N. Bhavsar ◽  
R. G. Patel ◽  
A. T. Oza
Keyword(s):  
Charge Transfer ◽  
Spectroscopic Study ◽  
Charge Transfer Complexes
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