Controlled Synthesis of Two Pyrazole-3-Carboxylic Acid Mononuclear- and Binuclear-Copper Complexes and Their Highly Selective Oxidation of Benzylic sp3 C–H Bonds

2019 ◽  
Vol 11 (2) ◽  
pp. 223-229
Author(s):  
Dan-Dan Zhong ◽  
Chun-Xia Li ◽  
Ying-Jie Li ◽  
Yu-Hang Wang ◽  
Hai-Chao Zhang ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Selective Oxidation ◽  
Copper Complexes ◽  
Controlled Synthesis ◽  
Binuclear Copper

Redox and magnetic properties of binuclear copper complexes

1985 ◽  
Vol 107 (1) ◽  
pp. L1-L2 ◽  
Author(s):  
J.M. Latour ◽  
D. Limosin ◽  
S.S. Tandon
Keyword(s):  
Magnetic Properties ◽  
Copper Complexes ◽  
Binuclear Copper

ChemInform Abstract: RESONANCE RAMAN STUDIES OF PHENOLATE-BRIDGED BINUCLEAR COPPER COMPLEXES. RELEVANCE TO HEMOCYANIN AND TYROSINASE

1985 ◽  
Vol 16 (20) ◽  
Author(s):  
J. W. PYRZ ◽  
K. D. KARLIN ◽  
T. N. SORRELL ◽  
G. C. VOGEL ◽  
L. JUN. QUE
Keyword(s):  
Copper Complexes ◽  
Resonance Raman ◽  
Binuclear Copper

Geometry-Dependent Phosphodiester Hydrolysis Catalyzed by Binuclear Copper Complexes

2003 ◽  
Vol 42 (24) ◽  
pp. 7912-7920 ◽  
Author(s):  
Lei Zhu ◽  
Osvaldo dos Santos ◽  
Chi Wan Koo ◽  
Marc Rybstein ◽  
Louise Pape ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Binuclear Copper ◽  
Phosphodiester Hydrolysis

Binuclear copper complexes: an open and shut case. A strong antiferromagnetically coupled .mu.-monohydroxo bridged complex

1981 ◽  
Vol 103 (5) ◽  
pp. 1273-1274 ◽  
Author(s):  
Patrick L. Burk ◽  
John A. Osborn ◽  
Marie Therese Youinou ◽  
Yvette Agnus ◽  
Remy Louis ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Binuclear Copper

Modeling the active site in hemocyanin: Synthesis and reactivity of binuclear copper complexes

1989 ◽  
Vol 166 (1) ◽  
pp. 71-77 ◽  
Author(s):  
Thomas N. Sorrell ◽  
Martha L. Garrity ◽  
Debora J. Ellis
Keyword(s):  
Active Site ◽  
Copper Complexes ◽  
Binuclear Copper

ChemInform Abstract: BINUCLEAR COPPER COMPLEXES: AN OPEN AND SHUT CASE. A STRONG ANTIFERROMAGNETICALLY COUPLED μ-MONOHYDROXO BRIDGED COMPLEX

1981 ◽  
Vol 12 (25) ◽  
Author(s):  
P. L. BURK ◽  
J. A. OSBORN ◽  
M.-T. YOUINOU ◽  
Y. AGNUS ◽  
R. LOUIS ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Binuclear Copper

Selective oxidation of alkenes and alkynes catalyzed by copper complexes

2007 ◽  
Vol 325 (2) ◽  
pp. 303-308 ◽  
Author(s):  
Leonardo X. Alvarez ◽  
M. Lorraine Christ ◽  
Alexander B. Sorokin
Keyword(s):  
Selective Oxidation ◽  
Copper Complexes

Structures and anti-cancer properties of two binuclear copper complexes

2013 ◽  
Vol 42 (41) ◽  
pp. 14681 ◽  
Author(s):  
Xiu Ying Qin ◽  
Li Cong Yang ◽  
Fang Ling Le ◽  
Qian Qian Yu ◽  
Dong Dong Sun ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Binuclear Copper ◽  
Anti Cancer

Selective Aerobic Oxidation of Primary Alcohols to Aldehydes

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1554-1557 ◽  
Author(s):  
Masatoshi Shibuya ◽  
Keisuke Furukawa ◽  
Yoshihiko Yamamoto
Keyword(s):  
Carboxylic Acid ◽  
Selective Oxidation ◽  
Aerobic Oxidation ◽  
Primary Alcohols ◽  
Co Catalyst ◽  
Tert Butyl ◽  
Selective Aerobic Oxidation

The 2-azaadamantane-N-oxyl (AZADO)- and 9-azanoradamantane-N-oxyl (nor-AZADO)-catalyzed selective oxidation of primary alcohols to the corresponding aldehydes is described. The use of tert-butyl nitrite as the co-catalyst enables efficient aerobic oxidation in MeCN instead of previously reported AcOH; this is important for the selectivity of the reaction. The addition of a solution of saturated aqueous NaHCO3 after the completion of the reaction was effective to suppress the overoxidation of the product to the corresponding carboxylic acid during the workup.

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