Characterization of Mechanical Surface Treated 304 Stainless Steel by Electrochemical Impedance Spectroscopy

2014 ◽  
Vol 6 (10) ◽  
pp. 2179-2184 ◽  
Author(s):  
Teguh Dwi Widodo ◽  
Azizul Helmi Bin Sofian ◽  
Ryouji Suzuki ◽  
Youhei Hirohata ◽  
Kazuhiko Noda
CORROSION ◽  
10.5006/2680 ◽  
2018 ◽  
Vol 74 (6) ◽  
pp. 705-714 ◽  
Author(s):  
Yingying Yue ◽  
Chengjun Liu ◽  
Edouard Asselin ◽  
Peiyang Shi ◽  
Maofa Jiang

H2SO4-H2O2 mixtures are a promising and environmentally friendly passivation medium for the stainless-steel pickling process. The corrosion behavior of stainless steel is highly dependent on the kinetics of passive film growth. Long-term electrochemical measurements, including polarization resistance, open circuit potential (OCP), and electrochemical impedance spectroscopy (EIS) measurements were performed to investigate the evolution of the passive state of 304 stainless steel. According to the OCP results, an active-passive transition takes place in 10 ks in 0.5 M H2SO4 solution containing 0.005 M to 0.3 M H2O2. Polarization resistance results indicate that the passive film thickness keeps growing after OCP stabilization in the presence of H2O2. Electrochemical impedance spectroscopy (EIS) results confirmed that the growth of the passive film in H2SO4-H2O2 solutions takes about 9 h. Additionally, according to the Point Defect Model (PDM) and Mott–Schottky analysis, the semiconductor properties of the passive film on 304 stainless steel in H2SO4-H2O2 solution were studied. The results indicate that the passive film is an n-type semiconductor. The donor density is in the range of 1.6 × 10−21 cm−3 to 24 and decreases exponentially with increasing film formation potential (this potential coincides with the final OCP in the corresponding H2SO4-H2O2 solutions). By postulating that most donors are oxygen vacancies, the point defect properties including diffusivity and electrical field strength are obtained.


2011 ◽  
Vol 189-193 ◽  
pp. 3570-3574
Author(s):  
Jian Tao Dong ◽  
Zhen Luo ◽  
Da Hai Xia ◽  
Rui Wang

The corrosion behaviors of 304 stainless steel (304SS) which has been cut and 304SS which has not been cut in two different solutions were investigated using polarization curve and electrochemical impedance spectroscopy (EIS) methods. The results show that 304SS which has been cut and 304SS which has not been cut have the similar corrosion voltage in two different solutions. However, the corrosion velocity of 304SS which has been cut is more than 304SS which has not been cut both in the two solutions and the corrosion behaviors of two 304SS in the water solution are better than in the water which has little oil.


2020 ◽  
Vol 11 (3) ◽  
pp. 364-364
Author(s):  
Maciej Ratynski ◽  
Bartosz Hamankiewicz ◽  
Michał Krajewski ◽  
Maciej Boczar ◽  
Dominika A. Buchberger ◽  
...  

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