Sol–Gel-Driven Al and Ta Co-Doped Li7La3Zr2O12 Solid Ceramic Electrolyte for All-Solid-State Lithium Ion Batteries

2018 ◽  
Vol 10 (4) ◽  
pp. 491-496
Author(s):  
Nu Ri Oh ◽  
Hae Been Kim ◽  
Ji Heon Ryu ◽  
Heon Lee ◽  
Hee Chul Lee
Author(s):  
Wei Liu ◽  
Ryan Milcarek ◽  
Kang Wang ◽  
Jeongmin Ahn

In this study, a multi-layer structure solid electrolyte (SE) for all-solid-state electrolyte lithium ion batteries (ASSLIBs) was fabricated and characterized. The SE was fabricated by laminating ceramic electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) with polymer (PEO)10-Li(N(CF3SO2)2 electrolyte and gel-polymer electrolyte of PVdF-HFP/ Li(N(CF3SO2)2. It is shown that the interfacial resistance is generated by poor contact at the interface of the solid electrolytes. The lamination protocol, material selection and fabrication method play a key role in the fabrication process of practical multi-layer SEs.


2019 ◽  
Vol 6 (11) ◽  
pp. 3288-3294 ◽  
Author(s):  
Ziye Shen ◽  
Zhongxue Zhang ◽  
Song Wang ◽  
Zenan Liu ◽  
Lijuan Wang ◽  
...  

LM6ZTW3O co-doped with Mg2+–W6+ with excellent low temperature electrochemical performance has been synthesized using a simple solid-state method.


2017 ◽  
Vol 356 ◽  
pp. 163-171 ◽  
Author(s):  
Penghao Lu ◽  
Fei Ding ◽  
Zhibin Xu ◽  
Jiaquan Liu ◽  
Xingjiang Liu ◽  
...  

2021 ◽  
Author(s):  
Dongjian Li ◽  
Hongtao Guo ◽  
Shaohua Jiang ◽  
Guilin Zeng ◽  
Wei Zhou ◽  
...  

Mg–Zr-Ti co-modified NCM with excellent electrochemical performance is obtained by a solid-state method.


2018 ◽  
Vol 67 ◽  
pp. 03028
Author(s):  
B Priyono ◽  
NY Radiawan ◽  
AH Yuwono ◽  
C Hudaya ◽  
A Subhan ◽  
...  

Lithium-ion batteries have been a substantial power source for most electrical devices nowadays. Performance optimization for anode of lithium-ion batteries (LIBs) can be conducted by adding ZnO through sol-gel solid-state reaction. In this research, the Li4Ti5O12 (LTO) used was synthesized through sol-gel solid-state process and directly added with ZnO-nanorods obtained from aging and annealing process. LTO-ZnO obtained was characterized to determine the main phase and chemical composition by XRD and SEM-EDS respectively. Electrochemical performance of LTO-ZnO was tested by EIS, CV, and CD. ZnO-nanorods characterization with SEM-EDS results shows that the ZnO inside the LTO dispersed homogeneously. Characterization using XRD revealed that the ZnO successfully enter the LTO with the variation of amount of 4, 7, and 10 wt % of ZnO. Electric conductivity test shows improvement at an optimum addition amount of ZnO at 4 wt%, although BET result shows at the optimum amount of surface area with 96.459 m2/g. Electrochemical performance result shows optimum performance in ZnO at 4 wt% for its ability to withstand EIS test at 20C compared to 7 wt% and 10 wt%. Also, capacity of 4 wt% added is 150.8 mAh/g compared to 7 wt% with 134.1 mAh/g and 10 wt% with 118.3 mAh/g.


2017 ◽  
Vol 41 (20) ◽  
pp. 12190-12197 ◽  
Author(s):  
Ali Reza Madram ◽  
Mahbubeh Faraji

In this study, Na and K co-doped LiFePO4/C samples with controlled Na and K sites, i.e., the Li1−x−yNaxKyFePO4/C and LiFe1−x−yNaxKyPO4/C (x = 0.02, y = 0.01) have been first synthesized via a common solid-state synthesis and the effects of the alien metal occupied site on the structure, morphology and electrochemical performance of LiFePO4/C are studied.


RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90455-90461 ◽  
Author(s):  
Peng Lu ◽  
Xiaobing Huang ◽  
Yurong Ren ◽  
Jianning Ding ◽  
Haiyan Wang ◽  
...  

Na+ and Zr4+ co-doped lithium titanates were successfully synthesized via a solid-state reaction in air. Particularly, Li3.97Na0.03Ti4.97Zr0.03O12 exhibits the best rate capability. Even at 20C, it delivers a discharge capacity of 140 mA h g−1.


2013 ◽  
Vol 724-725 ◽  
pp. 1067-1070
Author(s):  
Ning Yu Gu ◽  
Yang Li ◽  
Chao Li

To enhance the electrochemical performance of LiFePO4/C, Na and V have been co-doped in cathode material of the lithium ion batteries. A series of Na and V doped samples Li0.97Na0.03Fe(1-x)VxPO4/C (x=0, 0.01, 0.03, 0.05) cathode materials are synthesized by solid state method. Results show that the Li0.97Na0.03Fe0.97V0.03PO4/C exhibited the best electrochemical performances.


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