Time-Dependent Growth and Optical Properties of Stannous Oxide Architectures

2014 ◽  
Vol 3 (2) ◽  
pp. 92-97 ◽  
Author(s):  
M. Zubair Iqbal ◽  
Fengping Wang ◽  
Riaz Hussain ◽  
M. Yasir Rafique ◽  
Shujjat Ali ◽  
...  
RSC Advances ◽  
2015 ◽  
Vol 5 (122) ◽  
pp. 101101-101109 ◽  
Author(s):  
Birgitte H. McDonagh ◽  
Gurvinder Singh ◽  
Sulalit Bandyopadhyay ◽  
Sina M. Lystvet ◽  
Joseph A. Ryan ◽  
...  

While the size-dependent optical properties of BSA-stabilized gold nanoclusters are well known, the time-dependent growth mechanism remains to be described.


2017 ◽  
Vol 813 ◽  
Author(s):  
Anita A. Dey ◽  
Yahya Modarres-Sadeghi ◽  
Jonathan P. Rothstein

It is well known that when a flexible or flexibly mounted structure is placed perpendicular to the flow of a Newtonian fluid, it can oscillate due to the shedding of separated vortices. Here, we show for the first time that fluid–structure interactions can also be observed when the fluid is viscoelastic. For viscoelastic fluids, a flexible structure can become unstable in the absence of fluid inertia, at infinitesimal Reynolds numbers, due to the onset of a purely elastic flow instability. Nonlinear periodic oscillations of the flexible structure are observed and found to be coupled to the time-dependent growth and decay of viscoelastic stresses in the wake of the structure.


2010 ◽  
Vol 8 (6) ◽  
pp. 1192-1202 ◽  
Author(s):  
Marek Drozd ◽  
Mariusz Marchewka

AbstractThe bis(melaminium) sulphate dihydrate, 2,4,6-triamine-1,3,5-triazin-1,3-ium tartrate monohydrate, 2,4,6-triamine-1,3,5-triazin-1-ium hydrogenphthalate, 2,4,6-triamine-1,3,5-triazin-1-ium acetate acetic acid solvate monohydrate, 2,4,6-triamine-1,3,5-triazin-1-ium bis(selenate) trihydrate, melaminium diperchlorate hydrate, melaminium bis(trichloroacetate) monohydrate and melaminium bis(4-hydroxybenzenesulphonate) dihydrate were discovered recently as perspective materials for nonlinear optical applications. On the basis of X-ray structures for eight melaminium compounds the time dependent Hartree Fock (TDHF) method was used for calculation of the polarizability, and first and second hyperpolarizability. Detailed directional studies of calculated hyperpolarizability for all investigated melaminium compounds are shown. The theoretical results are compared with experimental values of β.


2016 ◽  
Vol 7 ◽  
pp. 312-327 ◽  
Author(s):  
Liz M Rösken ◽  
Felix Cappel ◽  
Susanne Körsten ◽  
Christian B Fischer ◽  
Andreas Schönleber ◽  
...  

Microbial biosynthesis of metal nanoparticles as needed in catalysis has shown its theoretical ability as an extremely environmentally friendly production method in the last few years, even though the separation of the nanoparticles is challenging. Biosynthesis, summing up biosorption and bioreduction of diluted metal ions to zero valent metals, is especially ecofriendly, when the bioreactor itself is harmless and needs no further harmful reagents. The cyanobacteriumAnabaena cylindrica(SAG 1403.2) is able to form crystalline Au0-nanoparticles from Au3+ions and does not release toxic anatoxin-a. X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and laser-induced breakdown spectroscopy (LIBS) are applied to monitor the time-dependent development of gold nanoparticles for up to 40 hours. Some vegetative cells (VC) are filled with nanoparticles within minutes, while the extracellular polymeric substances (EPS) of vegetative cells and the heterocyst polysaccharide layer (HEP) are the regions, where the first nanoparticles are detected on most other cells. The uptake of gold starts immediately after incubation and within four hours the average size remains constant around 10 nm. Analyzing the TEM images with an image processing program reveals a wide distribution for the diameter of the nanoparticles at all times and in all regions of the cyanobacteria. Finally, the nanoparticle concentration in vegetative cells ofAnabaena cylindricais about 50% higher than in heterocysts (HC). These nanoparticles are found to be located along the thylakoid membranes.


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