Studies of X-Ray Induced Thermally Stimulated Luminescence of Cu2+-Doped AeSO4 (Ae = Ca, Ba, Sr and Mg) and Analysis of Kinetic Parameters by Using Glow-Curve Deconvolution Technique

2014 ◽  
Vol 3 (1) ◽  
pp. 41-47
Author(s):  
Subrata Das ◽  
Mukesh Kumar Pandey ◽  
J. Manam
2013 ◽  
Vol 200 ◽  
pp. 220-224 ◽  
Author(s):  
Volodymyr Tsybulskyi ◽  
Myron R. Panasyuk ◽  
Ivan M. Solskii ◽  
Viktor Rudyk ◽  
Volodymyr B. Kapustianyk

The effect of annealing in the oxygen flow atmosphere of calcium molybdate crystals on their absorption spectra and thermally stimulated luminescence (TSL) glow curve was studied. The thermally stimulated depolarization (TSD), polarization (TSP) currents and temperature dependence of X-ray luminescence of CaMoO4were investigated in the temperature range of 100-320 K. One of the trap detected by TSL was found to disappear after high-temperature annealing of calcium molybdate single crystals. The nature of the absorption bands is discussed. The values of activation energy were calculated for the detected traps.


2006 ◽  
Vol 459 (3) ◽  
pp. 1007-1019 ◽  
Author(s):  
J. H. Croston ◽  
M. Arnaud ◽  
E. Pointecouteau ◽  
G. W. Pratt

2018 ◽  
Vol 29 (18) ◽  
pp. 15732-15740 ◽  
Author(s):  
H. Durán-Muñoz ◽  
M. Hernández-Ortíz ◽  
C. Sifuentes-Gallardo ◽  
J. I. Galván-Tejeda ◽  
R. Sánchez-Zeferino ◽  
...  

Crystals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 557 ◽  
Author(s):  
Nil Kucuk

In this work, structural and thermoluminescence (TL) characteristics for ZnB2O4:xTb3+ (x = 0.01, 0.02, 0.03, 0.04, 0.05, and 0.10 mole) phosphors were investigated. The phosphors were prepared via synthesis of nitric acid. The X-ray diffraction (XRD) studies show that the synthesized samples can be indexed to nearly single-phase cubic ZnB2O4. The TL characteristics following 90Sr beta irradiation (40 mCi) were studied. TL intensity is found to depend on Tb concentration. The optimal concentration of the doped Tb3+ is 0.03 mol in TL measurements. TL dose responses of the phosphors to beta doses of 0.143, 0.715, 1.43, 15, 30 and 60 Gy showed fairly linear behavior. The minimum detectable dose (MDD) value for ZnB2O4:0.04Tb3+ was found to be 87 mGy. The kinetic parameters of the ZnB2O4:0.03Tb3+ sample were estimated by the glow curve deconvolution, the initial rise, the curve fitting, and the peak shape methods. The results indicate that these phosphors are thought to be promising candidates as TL materials. The results provide valuable knowledge of the characteristics of Tb-doped ZnB2O4 for use in dosimetry research.


2002 ◽  
Vol 101 (1) ◽  
pp. 99-102 ◽  
Author(s):  
M. Skopec ◽  
J. L. Price ◽  
N. Guardala ◽  
M. Loew ◽  
M. Moscovitch

1983 ◽  
Vol 36 (9) ◽  
pp. 1865 ◽  
Author(s):  
SF Lincoln ◽  
AM Hounslow ◽  
NJ Maeji ◽  
TW Hambley ◽  
MR Snow ◽  
...  

The molecular structure of N,N,N',N',2,2-hexamethylpropanediamide has been determined in the solid state by X-ray diffraction methods. The structure of Me2NCOCMe2CONMe2 may be broadly described as two planar Me2NCO entities intersecting at the tetrahedral -CMe2- site. The angle between the normals to the two Me2NCO planes is 104.6�, and the two oxygen atoms are disposed outwards from the molecule and away from each other. Proton (270-MHz) n.m.r. studies yield k(320 K) 32.0 � 3.2 s-1, ΔH‡ 69.5 � 0.4 kJ mol-1 and ΔS‡ 0.6 � 1.1 J K-1 mol-1 for rotation of the N-methyl groups about the carbon-nitrogen bonds in CD3NO2 solution. Similar magnitudes for the kinetic parameters characterizing this process are obtained in CDCl3, and CD3CN solutions.


Sign in / Sign up

Export Citation Format

Share Document