Surface Plasmon Resonance in Nanocrystalline Gold–Copper Alloy Films

2007 ◽  
Vol 7 (12) ◽  
pp. 4486-4493 ◽  
Author(s):  
S. Hussain ◽  
Subhadeep Datta ◽  
R. K. Roy ◽  
A. K. Pal

Nanocrystalline Aux Cu1–x films were synthesized by depositing Cu/Au/Cu multilayer in nanocrystalline thin film form with requisite thickness of individual layers onto fused silica substrates by high pressure sputtering technique. The absorbance spectra showed only one surface plasmon peak for all the compositions with the exception that the peak position did not indicate gradual shift as gold concentration was increased. Peak position for the two compositions corresponding to the two superlattice structures, AuCu3 and AuCu, deviated significantly from linear variation. The experimental results have been discussed in light of the existing Mie theory and the Core-shell model.

NANO ◽  
2006 ◽  
Vol 01 (03) ◽  
pp. 229-234
Author(s):  
R. K. RAKSHIT ◽  
SAYANTANI BHATTACHARYA ◽  
R. C. BUDHANI

Oxidation characteristics of colloidal silver nanoparticles produced by pulsed laser ablation in pure and chemically treated water are studied as a function of the degree of ozonization. The bright yellow colloidal solution of silver characterized by a sharp surface plasmon mode at ~400 nm, becomes colorless in the initial stages of O 3 flow, and then acquires a brown hue with a broad plasmon peak centered at ~440 to ~450 nm on further ozonization. The solution again becomes colorless in a few days once the O 3 flow is stopped. We present a qualitative model for the reaction dynamics and analyze the optical absorption in the framework of an effective medium theory. The aqueous phase laser ablation chemistry described here provides a unique means to produce ionic silver for enhanced antimicrobial effects.


2007 ◽  
Vol 111 (51) ◽  
pp. 18906-18911 ◽  
Author(s):  
Keiko Munechika ◽  
Jessica M. Smith ◽  
Yeechi Chen ◽  
David S. Ginger

RSC Advances ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 444-449 ◽  
Author(s):  
O. Stroyuk ◽  
A. Raevskaya ◽  
G. Grodzyuk ◽  
N. Andriushina ◽  
M. Skoryk ◽  
...  

Interaction of forming Au nanocrystals with single-layer carbon nitride nanosheets allows the surface plasmon resonance peak position of gold/carbon nitride composites to be tuned in a range of 520–610 nm.


2016 ◽  
Vol 848 ◽  
pp. 228-232
Author(s):  
Xin Li ◽  
Jian Sheng Yao ◽  
Xiao Guang Liu ◽  
Hong Na Fan ◽  
Shu Xin Niu

Fused silica-based ceramics are often used as sacrificial cores in investment castings to produce hollow, precise, and complex-shaped blades. In this work, the content of mullite fiber and its effects on mechanical and dimension behavior of silica-based ceramic cores were investigated. In order to simulate the single crystal blades casting process, the sintered samples were also heated up to 1540°C and kept for 0.5 h. Flexural strength test at 1540°Cwas carried out for the samples. The shrinkage, creep behavior and erode behavior were characterized. The results showed that in the premise of maintaining strength of materials, mullite fiber could decrease significantly the shrinkage. Many gains appeared on the surface of fiber after creep test of the core samples at 1540°C.


2011 ◽  
Vol 19 (3) ◽  
Author(s):  
K. Grochowska ◽  
N. Nedyalkov ◽  
P. Atanasov ◽  
G. Śliwiński

AbstractThe particle size distribution, morphology and optical properties of the Au nanoparticle (NP) structures for surface enhanced Raman signal (SERS) application are investigated in dependence on their preparation conditions. The structures are produced from relatively thin Au films (10–20 nm) sputtered on fused silica glass substrate and irradiated with several pulses (6 ns) of laser radiation at 266 nm and at fluencies in the range of 160–412 mJ/cm2. The SEM inspection reveals nearly homogeneously distributed, spherical gold particles. Their initial size distribution of the range of 20–60 nm broadens towards larger particle diameters with prolonged irradiation. This is accompanied by an increase in the uncovered surface of the glass substrate and no particle removal is observed. In the absorption profiles of the nanostructures, the broad peak centred at 546 nm is ascribed to resonant absorption of surface plasmons (SPR). The peak position, halfwidth and intensity depend on the shape, size and size distribution of the nanostructured particles in agreement with literature. From peak intensities of the Raman spectra recorded for Rhodamine 6G in the range of 300–1800 cm−1, the relative signal enhancement by factor between 20 and 603 for individual peaks is estimated. The results confirm that the obtained structures can be applied for SERS measurements and sensing.


2018 ◽  
Vol 26 (17) ◽  
pp. 21939 ◽  
Author(s):  
Tomasz Stefaniuk ◽  
Grzegorz Stępniewski ◽  
Dariusz Pysz ◽  
Ryszard Stępień ◽  
Ryszard Buczyński

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 899 ◽  
Author(s):  
Hanna Stawska ◽  
Maciej Popenda ◽  
Elżbieta Bereś-Pawlik

In this paper, we present numerical studies of several different structures of anti-resonant, hollow core optical fibers. The cladding of these fibers is based on the Kagomé lattice concept, with some of the core-surrounding lattice cells removed. This modification, by creating additional, glass-free regions around the core, results in a significant improvement of some important optical fiber parameters, such as confinement loss (CL), bending loss (BL), and dispersion parameter (D). According to the conducted simulations (with fused silica glass being the structure’s material), CL were reduced from ~0.36 dB/m to ~0.16 dB/m (at 760 nm wavelength) in case of the structure with removed cells, and did not exceed the value of 1 dB/m across the 700–850 nm wavelength range. Additionally, proposed structure exhibits a remarkably low value of D—from 1.5 to 2.5 ps/(nm × km) at the 700–800 nm wavelength range, while the BL were estimated to be below 0.25 dB/m for bending radius of ~1.5 cm. CL and D were simulated, additionally, for structures made of acrylic glass polymethylmethacrylate, (PMMA), with similarly good results—DPMMA ∊ [2, 4] ps/(nm × km) and CLPMMA ≈ 0.13 dB/m (down from 0.41 dB/m), for the same spectral regions (700–800 nm bandwidth for D, and 760 nm wavelength for CL).


2019 ◽  
Vol 3 (1) ◽  
pp. 25 ◽  
Author(s):  
Johan Duque ◽  
Brayan Madrigal ◽  
Henry Riascos ◽  
Yenny Avila

In this article we report the production of metal oxide (TiFe2O4, ZnFe2O4) nanoparticles by pulsed laser ablation technique in a liquid environment. We used nanosecond Nd: YAG laser systems working at 532 nm and 1064 nm of wavelength and the energy of the laser beam was kept constant at 80 mJ. Absorbance spectra, surface plasmon resonance, optical band-gap, and nanoparticle morphology were investigated using ultraviolet-visible (UV-Vis) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Changing the wavelength of the laser for growth, nanoparticles showed shift between the absorbance and surface plasmon resonance peaks in their UV-Vis spectra, which implies that the optical properties of the colloid nanoparticles depend on laser parameters. This was confirmed with the variation of the band gap energy. Furthermore, redshift for the absorbance peak was observed for samples as-grown at 532 nm around 150 nm as a function of time preparation. Conversely, for the samples as-grown at 1064 nm there was no shift in the absorbance spectra, which could be due to agglomeration and formation of larger particles. The characterization results showed appropriate plasmonic photo-catalysts properties of the particles, hence the photoactivation of the nanoparticles was examined on antibacterial effect using colonies of Staphylococcus aureus and Escherichia coli.


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