Charge-Transfer Interaction in Single-Walled Carbon Nanotubes with Tetrathiafulvalene and Their Applications

2007 ◽  
Vol 7 (11) ◽  
pp. 4116-4119 ◽  
Author(s):  
Jin-Sun Kim ◽  
Kyuseok Choi ◽  
Ju-Jin Kim ◽  
Dong-Youn Noh ◽  
Sang-Kyu Park ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Charge Transfer ◽  
Photoelectron Spectroscopy ◽  
Specific Interaction ◽  
Building Blocks ◽  
Radial Breathing Mode ◽  
Industrial Applications ◽  
Binding Energies ◽  
Single Walled Carbon ◽  
Charge Transfer Interaction

We observed that single-walled carbon nanotube (SWNT) was aligned in the presence of TTF. This alignment was induced by a specific interaction between SWNT and tetrathiafulvalene (TTF), a well-known organic donor. The interaction between the two molecules can be explained by a charge-transfer, which was confirmed by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The binding energies of S (2P1/2) and S (2P3/2) were shifted from 163.0 eV and 164.1 eV to 163.9 eV and 165.1 eV, respectively. In Raman spectra of the SWNT-TTF, three peaks of SWNT in radial breathing mode were also upshifted by 4–5 cm−1. The charge-transfer interaction also contributed in modifying the electronic structure of SWNT and furthermore enhanced the electrical conductivity of SWNT. A more conductive thin film was fabricated using the SWNT-TTF. Four-probe measurement revealed that the surface resistance of the SWNT-TTF film was reduced to 4.359 Ω at room temperature while that of SWNT film was 6.894 Ω. These results enable carbon nanotubes to be utilized more for practically for industrial applications in fabricating peculiar nano-sized building blocks.

Exploration Study of Multifunctional Metallic Nanocomposite Utilizing Single-Walled Carbon Nanotubes for Micro/Nano Devices

2005 ◽  
Vol 219 (2) ◽  
pp. 67-72 ◽  
Author(s):  
Quanfang Chen ◽  
Guang Chai ◽  
Bo Li
Keyword(s):  
Carbon Nanotubes ◽  
Energy Transport ◽  
Metallic Matrix ◽  
Building Blocks ◽  
Copper Matrix ◽  
Interfacial Bonding ◽  
Single Walled Carbon ◽  
The Matrix ◽  
Raman Scattering Spectra ◽  
Multifunctional Properties

Carbon nanotubes (CNTs) are excellent multifunctional materials in terms of mechanical robustness, thermal, and electrical conductivities. These multifunctional properties, as well as the small size of the structures, make CNTs ideal building blocks in developing nanocomposites. However, the matrix materials and the fabrication processes are critical in achieving the expected multifunctional properties of a CNT-reinforced nanocomposite. This paper has proved that electrochemical co-deposition of a metallic nanocomposite is a good approach for achieving good interfacial bonding between CNTs and a metallic matrix. Good interfacial bonding between a single-walled carbon nanotube (SWCNT) and a copper matrix has been verified by enhanced fracture toughness (increased stickiness) and a shift in the Raman scattering spectra. For the Cu/SWCNT nanocomposite, the radial breath mode (RBM) has disappeared and the tangential or G-band has shifted and widened, which is an indication of better energy transport.

scholarly journals Charge transfer between lead halide perovskite nanocrystals and single-walled carbon nanotubes

2020 ◽  
Vol 2 (2) ◽  
pp. 808-813 ◽  
Author(s):  
Parul Bansal ◽  
Xiangtong Zhang ◽  
Hua Wang ◽  
Prasenjit Kar ◽  
William W. Yu
Keyword(s):  
Carbon Nanotubes ◽  
Charge Transfer ◽  
Single Walled Carbon Nanotubes ◽  
Perovskite Nanocrystals ◽  
Single Walled Carbon ◽  
Halide Perovskite ◽  
A Charge ◽  
Walled Carbon Nanotubes ◽  
Lead Halide ◽  
Transfer Study

A charge transfer study between lead halide-based perovskite nanocrystals and single-walled carbon nanotubes (PNC@CNT nanocomposite) was performed.

scholarly journals Reversible Charge Transfer with Single‐Walled Carbon Nanotubes Upon Harvesting the Low Energy Part of the Solar Spectrum

Small ◽  
2020 ◽  
Vol 16 (8) ◽  
pp. 1906745 ◽  
Author(s):  
Arjun Menon ◽  
Yuri L. Slominskii ◽  
Jan Joseph ◽  
Oleg P. Dimitriev ◽  
Dirk M. Guldi
Keyword(s):  
Carbon Nanotubes ◽  
Charge Transfer ◽  
Solar Spectrum ◽  
Single Walled Carbon Nanotubes ◽  
Low Energy ◽  
Single Walled Carbon ◽  
Energy Part ◽  
Walled Carbon Nanotubes

scholarly journals Synthesis and Cytotoxicity of POSS Modified Single Walled Carbon Nanotubes

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Yuhua Xue ◽  
Hao Chen
Keyword(s):  
Carbon Nanotubes ◽  
Photoelectron Spectroscopy ◽  
Single Walled Carbon Nanotubes ◽  
X Ray ◽  
Single Walled Carbon ◽  
Amine Functionalized ◽  
Low Toxicity ◽  
Organic Solutions ◽  
Oligomeric Silsesquioxane ◽  
Walled Carbon Nanotubes

Single walled carbon nanotubes (SWNTs) decorated with polyhedral oligomeric silsesquioxane (POSS) were synthesized via the amide linkages between the acid treated SWNTs and amine-functionalized POSS. The successful modification of SWNTs with POSS was confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and UV-Vis spectra. The resulting SWNTs-POSS can be dispersed in both water and organic solutions. The biocompatibility and cytotoxicity of the SWNTs and SWNTs-POSS were evaluated by CCK-8 viability assays, which indicated that SWNTs-POSS exhibit very extremely low toxicity. The low toxicity of the POSS modified SWNTs leads to more opportunities for using carbon nanotubes in biomedical fields.

Single-walled carbon nanotubes functionalized by a series of dichlorocarbenes: DFT study

2016 ◽  
Vol 30 (08) ◽  
pp. 1650118 ◽  
Author(s):  
Igor K. Petrushenko ◽  
Konstantin B. Petrushenko
Keyword(s):  
Carbon Nanotubes ◽  
Young’S Modulus ◽  
Elastic Properties ◽  
Density Functional ◽  
Young's Modulus ◽  
Strong Dependence ◽  
Single Walled Carbon Nanotubes ◽  
Binding Energies ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

The structural and elastic properties of neutral and ionized dichlorocarbene (CCl2) functionalized single-walled carbon nanotubes (SWCNTs) were studied using density functional theory (DFT). The Young’s modulus of ionized pristine SWCNTs is found to decrease in comparison to that of neutral models. The interesting effect of increase in Young’s modulus values of ionized functionalized SWCNTs is observed. We ascribe this feature to the concurrent processes of the bond elongation on ionization and the local deformation on cycloaddition. The strong dependence of the elasticity modulus on the number of addends is also observed. However, the CCl2-attached SWCNTs in their neutral and ionized forms remain strong enough to be suitable for the reinforcement of composites. In contrast to the elastic properties, the binding energies do not change significantly, irrespective of CCl2 coverage.

Charge Transfer Dynamics in Single-Wall Carbon Nanotubes Mat: In Situ Raman Spectroscopy

2003 ◽  
Vol 785 ◽  
Author(s):  
S. Gupta ◽  
M. Hughes ◽  
A.H. Windle ◽  
J. Robertson
Keyword(s):  
Carbon Nanotubes ◽  
Raman Spectroscopy ◽  
Charge Transfer ◽  
Bond Length ◽  
Mechanical Response ◽  
Radial Breathing Mode ◽  
Single Wall Carbon Nanotubes ◽  
In Situ Raman Spectroscopy ◽  
Single Wall Carbon

ABSTRACTCarbon nanotubes-based actuator has been investigated using in situ Raman spectroscopy in order to understand the actuation mechanism and to determine associated parameters. We built an actuator from a sheet of single-wall carbon nanotubes (SWNT mat) and studied in several alkali metal (Li, Na, and K) and alkaline earth (Ca) halide solutions. Since Raman can detect changes in C-C bond length: the radial breathing mode (RBM) at ∼190 cm-1 varies inversely with the nanotube diameter and the G band at ∼1590 cm-1 varies with the axial bond length, the variation of bonding was monitored with potential. In addition, the intensities of both the modes vary with either emptying/depleting or filling of the bonding and antibonding states due to electrochemical charge injection. We discuss the variation of intensity/frequency providing valuable information on the dynamics of charge transfer on the SWNT mat surface. We found the in-plane microscopic strain (∼ -0.25%) and the charge transfer per carbon atom (fc ∼ -0.005) as an upper bound for the electrolytes used. It is demonstrated that though the present analyses does comply with the proposition made earlier, but the quantitative estimates of the associated parameters are significantly lower if compared with those of reported values for carbon nanotubes. Moreover, the extent of variation (i.e. coupled electro-chemo-mechanical response) does depend upon the type of counter-ion used. The cyclic voltammetry (CV) is also described briefly.

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