Synthesis of α-Fe Nanoparticles by Solventless Thermal Decomposition

2006 ◽  
Vol 6 (11) ◽  
pp. 3412-3416 ◽  
Author(s):  
Hyun Gil Cha ◽  
Young Hwan Kim ◽  
Chang Woo Kim ◽  
Don Keun Lee ◽  
Sung Doo Moon ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Fe Nanoparticles

Magnetic Property of á-Fe Nanoparticles Prepared by Solventless Thermal Decomposition Method

2006 ◽  
Vol 962 ◽  
Author(s):  
Young Chul Han
Keyword(s):  
Thermal Decomposition ◽  
Decomposition Method ◽  
High Vacuum ◽  
Vacuum System ◽  
X Ray Diffraction ◽  
Thermal Decomposition Method ◽  
Transmission Electron ◽  
Gas Atmosphere ◽  
Fe Nanoparticles ◽  
Pyrex Tube

ABSTRACTNano sized α-Fe particle was synthesized by modified thermal decomposition method. It resulted in the higher saturation magnetization (Ms) almost equivalent to the value of bulk Fe power (Mbulk = 210 emu/g). To prepare Fe nanoparticles, the Fe2+-(oleate)2 complex was annealed at 400 J in pyrex tube and the prepared Fe3O4 nanoparticle was reduced to Fe crystal structure at 700 J with NaCl under Ar+H2 gas atmosphere and annealed again under high vacuum system of 10−5 torr. The crystallinity and structure of the Fe nanoparticle was investigated by powder X-ray diffraction (XRD). The shape and size was confirmed by transmission electron microscope (TEM) images. The magnetic properties were characterized with coercivity and remanence from hysteresis loop by vibrating sample magnetometer (VSM)

Thermal decomposition and reducibility of silica-supported precursors of Cu, Fe and Cu–Fe nanoparticles

2018 ◽  
Vol 134 (1) ◽  
pp. 233-251 ◽  
Author(s):  
Olga Kirichenko ◽  
Gennadiy Kapustin ◽  
Vera Nissenbaum ◽  
Anna Strelkova ◽  
Elena Shuvalova ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Fe Nanoparticles ◽  
Supported Precursors

Halide ion-mediated growth of single crystalline Fe nanoparticles

Nanoscale ◽  
2014 ◽  
Vol 6 (9) ◽  
pp. 4852-4856 ◽  
Author(s):  
Sen Zhang ◽  
Guangming Jiang ◽  
Gabriel T. Filsinger ◽  
Liheng Wu ◽  
Huiyuan Zhu ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Single Crystalline ◽  
Fe Nanoparticles

We report a facile halide ion (Cl− or Br−) mediated synthesis of Fe nanoparticles (NPs) by thermal decomposition of Fe(CO)5.

Applications of Photoelectron Microscopy

1976 ◽  
Vol 34 ◽  
pp. 506-507
Author(s):  
William J. Baxter
Keyword(s):  
Electron Microscopy ◽  
Thermal Decomposition ◽  
Chemical Composition ◽  
Ultraviolet Radiation ◽  
Thin Layer ◽  
Edge Effects ◽  
Electron Optics ◽  
Surface Layers ◽  
Crystalline Orientation ◽  
Fluorescent Screen

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.

Preparation and characterisation of vanadium pentoxide supported rhodium catalyst

1988 ◽  
Vol 46 ◽  
pp. 946-947
Author(s):  
A. Legrouri
Keyword(s):  
Aqueous Solution ◽  
Thermal Decomposition ◽  
Physicochemical Properties ◽  
Surface Area ◽  
Vanadium Pentoxide ◽  
High Purity ◽  
Gas Adsorption ◽  
Rhodium Catalyst ◽  
Optical Methods ◽  
Reducible Oxides

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.

Observations of the Thermal Decomposition of Brucite

1968 ◽  
Vol 26 ◽  
pp. 446-447
Author(s):  
P. L. Burnett ◽  
W. R. Mitchell ◽  
C. L. Houck
Keyword(s):  
Thermal Decomposition ◽  
Magnesium Oxide ◽  
Basal Plane ◽  
Magnesium Ions ◽  
A Value ◽  
Reaction Proceeds

Natural Brucite (Mg(OH)2) decomposes on heating to form magnesium oxide (MgO) having its cubic ﹛110﹜ and ﹛111﹜ planes respectively parallel to the prism and basal planes of the hexagonal brucite lattice. Although the crystal-lographic relation between the parent brucite crystal and the resulting mag-nesium oxide crystallites is well known, the exact mechanism by which the reaction proceeds is still a matter of controversy. Goodman described the decomposition as an initial shrinkage in the brucite basal plane allowing magnesium ions to shift their original sites to the required magnesium oxide positions followed by a collapse of the planes along the original <0001> direction of the brucite crystal. He noted that the (110) diffraction spots of brucite immediately shifted to the positions required for the (220) reflections of magnesium oxide. Gordon observed separate diffraction spots for the (110) brucite and (220) magnesium oxide planes. The positions of the (110) and (100) brucite never changed but only diminished in intensity while the (220) planes of magnesium shifted from a value larger than the listed ASTM d spacing to the predicted value as the decomposition progressed.

A magnetic super lattice

1987 ◽  
Vol 45 ◽  
pp. 360-361 ◽  
Author(s):  
M.D. Bentzon ◽  
J. v. Wonterghem ◽  
A. Thölén
Keyword(s):  
Thermal Decomposition ◽  
Oleic Acid ◽  
Magnetic Fluid ◽  
Magnetic Particles ◽  
Carbon Film ◽  
Thick Layer ◽  
Amorphous Iron ◽  
Super Lattice ◽  
Carrier Liquid ◽  
Median Diameter

We report on the oxidation of a magnetic fluid. The oxidation results in magnetic super lattice crystals. The “atoms” are hematite (α-Fe2O3) particles with a diameter ø = 6.9 nm and they are covered with a 1-2 nm thick layer of surfactant molecules.Magnetic fluids are homogeneous suspensions of small magnetic particles in a carrier liquid. To prevent agglomeration, the particles are coated with surfactant molecules. The magnetic fluid studied in this work was produced by thermal decomposition of Fe(CO)5 in Declin (carrier liquid) in the presence of oleic acid (surfactant). The magnetic particles consist of an amorphous iron-carbon alloy. For TEM investigation a droplet of the fluid was added to benzine and a carbon film on a copper net was immersed. When exposed to air the sample starts burning. The oxidation and electron irradiation transform the magnetic particles into hematite (α-Fe2O3) particles with a median diameter ø = 6.9 nm.

Supersonic jet spectrometry of chemical species resulting from thermal decomposition of polystyrene and polycarbonate

1992 ◽  
Vol 64 (19) ◽  
pp. 931A-940A ◽  
Author(s):  
Totaro Imasaka ◽  
Masami Hozumi ◽  
Nobuhiko Ishibashi
Keyword(s):  
Thermal Decomposition ◽  
Supersonic Jet ◽  
Chemical Species
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