Reactive Nanopattern in a Triple Structured Bio-Inspired Honeycomb Film as a Clickable Platform

2018 ◽  
Author(s):  
Pierre Marcasuzaa ◽  
Samuel Pearson ◽  
Karell Bosson ◽  
Laurence Pessoni ◽  
Jean-Charles Dupin ◽  
...  
Keyword(s):  
Self Assembly ◽  
Double Porosity ◽  
Surface Groups ◽  
Specific Chemical ◽  
Site Specific ◽  
Surface Functionality ◽  
Wenzel State ◽  
Breath Figure ◽  
Responsive Surfaces ◽  
Secondary Population

A hierarchically structured platform was obtained from spontaneous self-assembly of a poly(styrene)-<i>b</i>-poly(vinylbenzylchloride) (PS-<i>b</i>-PVBC) block copolymer (BCP) during breath figure (BF) templating. The BF process using a water/ethanol atmosphere gave a unique double porosity in which hexagonally arranged micron-sized pores were encircled by a secondary population of smaller, nano-sized pores. A third level of structuration was simultaneously introduced between the pores by directed BCP self-assembly to form out-of-the-plane nano-cylinders, offering very rapid bottom-up access to a film with unprecedented triple structure which could be used as a reactive platform for introducing further surface functionality. The surface nano-domains of VBC were exploited as reactive nano-patterns for site-specific chemical functionalization by firstly substituting the exposed chlorine moiety with azide, then “clicking” an alkyne by copper (I) catalyzed azide-alkyne Huisgen cycloaddition (CuAAC). Successful chemical modification was verified by NMR spectroscopy, FTIR spectroscopy, and XPS, with retention of the micro- and nanostructuration confirmed by SEM and AFM respectively. Protonation of the cyclotriazole surface groups triggered a switch in macroscopic behavior from a Cassie-Baxter state to a Wenzel state, highlighting the possibility of producing responsive surfaces with hierarchical structure.

scholarly journals Kähler groups and subdirect products of surface groups

2020 ◽  
Vol 24 (2) ◽  
pp. 971-1017
Author(s):  
Claudio Llosa Isenrich
Keyword(s):  
Surface Groups ◽  
Kähler Groups ◽  
Subdirect Products

scholarly journals Solid-phase extraction cartridges with multi-walled carbon nanotubes and effect of the oxygen functionalities on the recovery efficiency of organic micropollutants

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Marta O. Barbosa ◽  
Rui S. Ribeiro ◽  
Ana R. L. Ribeiro ◽  
M. Fernando R. Pereira ◽  
Adrián M. T. Silva
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Surface Groups ◽  
Phase Extraction ◽  
Organic Micropollutants ◽  
Oxidation Method ◽  
Hydrothermal Oxidation ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

AbstractPristine and functionalized multi-walled carbon nanotubes (MWCNTs) were investigated as adsorbent materials inside solid-phase extraction (SPE) cartridges for extraction and preconcentration of 8 EU-relevant organic micropollutants (with different pKa and polarity) before chromatographic analysis of surface water. The recoveries obtained were > 60% for 5/8 target pollutants (acetamiprid, atrazine, carbamazepine, diclofenac, and isoproturon) using a low amount of this reusable adsorbent (50 mg) and an eco-friendly solvent (ethanol) for both conditioning and elution steps. The introduction of oxygenated surface groups in the carbon nanotubes by using a controlled HNO3 hydrothermal oxidation method, considerably improved the recoveries obtained for PFOS (perfluorooctanesulfonic acid) and methiocarb, which was ascribed to the hydrogen bond adsorption mechanism, but decreased those observed for the pesticide acetamiprid and for two pharmaceuticals (carbamazepine and diclofenac), suggesting π–π dispersive interactions. Moreover, a good correlation was found between the recovery obtained for methiocarb and the amount of oxygenated surface groups on functionalized MWCNTs, which was mainly attributed to the increase of phenols and carbonyl and quinone groups. Thus, the HNO3 hydrothermal oxidation method can be used to finely tune the surface chemistry (and texture) of MWCNTs according to the specific micropollutants to be extracted and quantified in real water samples.

Hierarchical Crumpled NiMn2O4@MXene Composites for High Rate Ion Transport Electrochemical Supercapacitors

2021 ◽  
Author(s):  
Hailong Yan ◽  
Jinbing Cheng ◽  
Zuxue Bai ◽  
Tao Peng ◽  
Jang-Kyo Kim ◽  
...  
Keyword(s):  
Ion Transport ◽  
Electronic Conductivity ◽  
High Rate ◽  
Surface Groups ◽  
Hydrophilic Surface ◽  
Electrochemical Supercapacitors ◽  
Excellent Performance ◽  
Volumetric Capacitance

MXenes have received great attention due to their excellent performance such as metal-like electronic conductivity, hydrophilic surface groups, and high volumetric capacitance. However, many performances of MXenes are still unsatisfied...

scholarly journals Topological mirror symmetry for rank two character varieties of surface groups

2021 ◽  
Author(s):  
Mirko Mauri
Keyword(s):  
Moduli Spaces ◽  
Mirror Symmetry ◽  
Surface Groups ◽  
Character Varieties ◽  
Hitchin System ◽  
Global Topology ◽  
Hodge Numbers

AbstractThe moduli spaces of flat $${\text{SL}}_2$$ SL 2 - and $${\text{PGL}}_2$$ PGL 2 -connections are known to be singular SYZ-mirror partners. We establish the equality of Hodge numbers of their intersection (stringy) cohomology. In rank two, this answers a question raised by Tamás Hausel in Remark 3.30 of “Global topology of the Hitchin system”.

Reactivity of surface groups formed onto a plasma treated poly(propylene) film

1999 ◽  
Vol 200 (5) ◽  
pp. 989-996 ◽  
Author(s):  
Fabienne Poncin-Epaillard ◽  
Jean-Claude Brosse ◽  
Thierry Falher
Keyword(s):  
Surface Groups ◽  
Poly Propylene

Domains of discontinuity for surface groups

2009 ◽  
Vol 347 (17-18) ◽  
pp. 1057-1060 ◽  
Author(s):  
Olivier Guichard ◽  
Anna Wienhard
Keyword(s):  
Surface Groups
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