scholarly journals Chemical Reaction and Electrical Properties of Amorphous RuO2-Ag-Glass Ternary System

1978 ◽  
Vol 5 (1) ◽  
pp. 27-32 ◽  
Author(s):  
Akira Ikegami ◽  
Kiichi Shinriki
Keyword(s):  
Isothermal Section ◽  
Electrical Properties ◽  
Ternary System ◽  
Chemical Reaction ◽  
Glass Phase ◽  
Differential Analysis ◽  
X Ray Diffraction ◽  
Composition Region ◽  
X Ray ◽  
The Relationship

The relationship between composition, electrical properties, and the chemical reaction during firing of amorphous RuO2-Ag-Glass ternary system are investigated. The results are as follows.1) Iso-resistivity, iso-TCR and iso-noise index curves of the system are determined. They have a common feature with regard to their bending in the composition region containing less than about 10wt% Ag.2) X-ray diffraction and thermal differential analysis reveals the solution of Ag into glass phase in addition to the crystallization of amorphous RuO2.3) The triaxial diagram of isothermal section at 850℃ is given.4) Electrical isograms in the system are discussed in relation to the solubility of Ag into glass phase.

Effects of Different Sintering Temperature on the Microstructure and Piezoelectric Properties of Pb(Nb2/3Zn1/3)x(Zr52Ti48)1-XO3 Ceramics

2014 ◽  
Vol 1061-1062 ◽  
pp. 83-86
Author(s):  
Hong Wu ◽  
De Yi Zheng
Keyword(s):  
Electrical Properties ◽  
Electromechanical Coupling ◽  
Piezoelectric Properties ◽  
Sintering Temperature ◽  
Electromechanical Coupling Coefficient ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ceramic Samples ◽  
Xrd Patterns ◽  
The Relationship

In this paper, the effects of different sintering temperature on the microstructure and piezoelectric properties of Pb(Nb2/3Zn1/3)0.03(Zr52Ti48)0.97O3(PNZZT) ceramic samples were investigated. The Pb(Nb2/3Zn1/3)0.03(Zr52Ti48)0.97O3 ceramics materials was prepared by a conventional mixed oxide method. In the period of the experiment, the relationship between crystallographic phase and microstructure were analyzed by X-ray diffraction(XRD) and scanning electron microscopy(SEM) respectively. The XRD patterns shows that all of the ceramic samples are with a tetragonal perovskite structure. Along with sintering temperature increased and the x is 0.03, the grain size gradually become big. Through this experiment, it has been found that when the x is 0.03 and sintered at 1130°C for 2 h, the grains grow well, the grain-boundary intersection of the sample combined well and the porosity of the ceramics decreased, an excellent comprehensive electrical properties of the Pb(Nb2/3Zn1/3)0.03(Zr52Ti48)0.97O3 samples can be obtained. Its best electrical properties are as follows: dielectric constant (ε) is 1105, dielectric loss(tg) is 0.017, electromechanical coupling coefficient (Kp) is 0.287, piezoelectric constant(d33) is 150PC/N

600°C Isothermal Section of the Zn-Fe-Nb Ternary System at the Zn-Rich Corner

2011 ◽  
Vol 391-392 ◽  
pp. 1210-1214
Author(s):  
Hao Tu ◽  
Xin Ming Wang ◽  
Ya Liu ◽  
Chang Jun Wu ◽  
Jian Hua Wang ◽  
...  
Keyword(s):  
Isothermal Section ◽  
Ternary System ◽  
Diffusion Couple ◽  
Ternary Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Eds Analysis ◽  
Δ Phase

The isothermal section of the Fe-Zn-Nb ternary system at 600 oC was determined using the equilibrated alloys with the aid of diffusion couple approach. The specimens were investigated by means of SEM-EDS analysis, SEM-WDS analysis and X-ray diffraction. A true ternary phase T was identified, this phase is in equilibrium with ε, NbZn3, Γ, δ, and η - Zn phases respectively in the system. The solubility of Nb in η - Zn and δ phase is limited and that of Zn in ε is up to 10.0%.

Structure and Morphology of Metallic-Conductive Polyacetylene

1992 ◽  
Vol 247 ◽  
Author(s):  
Jun Tsukamoto ◽  
Akio Takahashi
Keyword(s):  
Crystal Structure ◽  
Electrical Properties ◽  
Resonance Raman ◽  
Granular Structure ◽  
X Ray Diffraction ◽  
Raman Analysis ◽  
X Ray ◽  
Sem Observation ◽  
Structure And Morphology ◽  
The Relationship

ABSTRACTWe have carried out structural analyses of highly conductive polyacetylene in order to elucidate the relationship between stucture and electrical properties. Sharp X-ray diffraction lines were observed for the heavily iodine-doped polyacetylene showing high conductivity, in contrast with the diffused diffractions of the conventional one. SEM observation reveals that granular structure of the new polyacetylene is composed of densely packed micro-fibrils. The result from the resonance Raman analysis indicates that the new cis-polyacetylene contains more longer conjugated segments than conventional polyacetylene. The relationship between the structure and conductivity is discussed, basing on the crystal structure and morphology observed.

ChemInform Abstract: Y-Fe-Al Ternary System: Partial Isothermal Section at 1070 K. Powder X-Ray Diffraction and Moessbauer Spectroscopy Study.

ChemInform ◽  
2010 ◽  
Vol 32 (41) ◽  
pp. no-no
Author(s):  
J. C. Waerenborgh ◽  
P. Salamakha ◽  
O. Sologub ◽  
S. Serio ◽  
M. Godinho ◽  
...  
Keyword(s):  
Isothermal Section ◽  
Ternary System ◽  
Partial Isothermal Section ◽  
Spectroscopy Study ◽  
X Ray Diffraction ◽  
Moessbauer Spectroscopy ◽  
X Ray

scholarly journals Isothermal section of the Ho–Cu–Sn ternary system at 670 K

2019 ◽  
Vol 19 (2) ◽  
pp. 139-146
Author(s):  
L. Romaka ◽  
I. Romaniv ◽  
V. Romaka ◽  
M. Konyk ◽  
A. Horyn ◽  
...  
Keyword(s):  
Solid Solution ◽  
Isothermal Section ◽  
Ternary System ◽  
Binary Compound ◽  
X Ray Diffraction ◽  
Interstitial Solid Solution ◽  
Space Group ◽  
X Ray ◽  
Type Space ◽  
Ternary Compounds

The interaction of the components in the Ho-Cu-Sn ternary system was investigated at 670 K over the whole concentration range using X-ray diffraction and EPM analyses. Four ternary compounds were formed in the Ho–Cu–Sn system at 670 K: HoCuSn (LiGaGe type, space group P63mc), Ho3Cu4Sn4 (Gd3Cu4Ge4-type, space group Immm), HoCu5Sn (CeCu5Au-type, space group Pnma), and Ho1.9Cu9.2Sn2.8 (Dy1.9Cu9.2Sn2.8-type, space group P63/mmc). The formation of the interstitial solid solution based on HoSn2 (ZrSi2-type) binary compound up to 5 at. % Cu was found.

Fabrication and study the effect of the laser on the properties of the compound Tl2-xHgxBa2-ySryCa2Cu3O10+δ superconductor

2018 ◽  
pp. 168
Author(s):  
A. Kareem Dahash Ali ◽  
Nihad Ali Shafeek
Keyword(s):  
Transition Temperature ◽  
Solid State ◽  
Hydrostatic Pressure ◽  
Electrical Properties ◽  
Co2 Laser ◽  
Temperature Shift ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structural And Electrical Properties

This study included the fabrication of    compound (Tl2-xHgxBa2-ySryCa2Cu3O10+δ) in a manner solid state and under hydrostatic pressure ( 8 ton/cm2) and temperature annealing(850°C), and determine the effect of the laser on the structural and electrical properties elements in the compound, and various concentrations of x where (x= 0.1,0.2,0.3 ). Observed by testing the XRD The best ratio of compensation for x is 0.2 as the value of a = b = 5.3899 (A °), c = 36.21 (A °) show that the installation of four-wheel-based type and that the best temperature shift is TC= 142 K  .When you shine a CO2 laser on the models in order to recognize the effect of the laser on these models showed the study of X-ray diffraction of these samples when preparing models with different concentrations of the values ​​of x, the best ratio of compensation is 0.2 which showed an increase in the values ​​of the dimensions of the unit cell a=b = 5.3929 (A °), c = 36.238 (A°). And the best transition temperature after shedding laser is TC=144 K. 

scholarly journals Local Strain Distribution in ZnO Microstructures Visualized with Scanning Nano X‐Ray Diffraction and Impact on Electrical Properties

2021 ◽  
pp. 2100201
Author(s):  
Philipp Jordt ◽  
Stjepan B. Hrkac ◽  
Jorit Gröttrup ◽  
Anton Davydok ◽  
Christina Krywka ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Strain Distribution ◽  
Local Strain ◽  
X Ray Diffraction ◽  
X Ray

scholarly journals Irregular Electrodeposition of Cu-Sn Alloy Coatings in [EMIM]Cl Outside the Glove Box with Large Layer Thickness

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 310
Author(s):  
Lars Lehmann ◽  
Dominik Höhlich ◽  
Thomas Mehner ◽  
Thomas Lampke
Keyword(s):  
Layer Thickness ◽  
Alloy System ◽  
Liquid Solution ◽  
Complexing Agents ◽  
X Ray Diffraction ◽  
X Ray ◽  
Argon Stream ◽  
Ionic Liquid Solution ◽  
The Relationship ◽  
Layer Composition

Thick Cu−Sn alloy layers were produced in an [EMIM]Cl ionic-liquid solution from CuCl2 and SnCl2 in different ratios. All work, including the electrodeposition, took place outside the glovebox with a continuous argon stream over the electrolyte at 95 °C. The layer composition and layer thickness can be adjusted by the variation of the metal-salts content in the electrolyte. A layer with a thickness of up to 15 µm and a copper content of up to ωCu = 0.86 was obtained. The phase composition was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray fluorescence (XRF). Furthermore, it was found that the relationship between the alloy composition and the concentration of the ions in the electrolyte is described as an irregular alloy system as according to Brenner. Brenner described such systems only for aqueous electrolytes containing complexing agents such as cyanide. In this work, it was confirmed that irregular alloy depositions also occur in [EMIM]Cl.

scholarly journals Photocurrent density and electrical properties of Bi0.5Na0.5TiO3-BaNi0.5Nb0.5O3 ceramics

2021 ◽  
Author(s):  
Mingqiang Zhong ◽  
Qin Feng ◽  
Changlai Yuan ◽  
Xiao Liu ◽  
Baohua Zhu ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Photovoltaic Effect ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Photocurrent Density ◽  
Open Circuit ◽  
Light Conditions ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray

AbstractIn this work, the (1−x)Bi0.5Na0.5TiO3-xBaNi0.5Nb0.5O3 (BNT-BNN; 0.00 ⩽ x ⩽ 0.20) ceramics were prepared via a high-temperature solid-state method. The crystalline structures, photovoltaic effect, and electrical properties of the ceramics were investigated. According to X-ray diffraction, the system shows a single perovskite structure. The samples show the normal ferroelectric loops. With the increase of BNN content, the remnant polarization (Pr) and coercive field (Ec) decrease gradually. The optical band gap of the samples narrows from 3.10 to 2.27 eV. The conductive species of grains and grain boundaries in the ceramics are ascribed to the double ionized oxygen vacancies. The open-circuit voltage (Voc) of ∼15.7 V and short-circuit current (Jsc) of ∼1450 nA/cm2 are obtained in the 0.95BNT-0.05BNN ceramic under 1 sun illumination (AM1.5G, 100 mW/cm2). A larger Voc of 23 V and a higher Jsc of 5500 nA/cm2 are achieved at the poling field of 60 kV/cm under the same light conditions. The study shows this system has great application prospects in the photovoltaic field.

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