scholarly journals Electrospun Core-Shell Hollow Structure Cocatalysts for Enhanced Photocatalytic Activity

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Fengyun Guo ◽  
Ziyi Guo ◽  
Lei Gao ◽  
Dongming Qi ◽  
Guichu Yue ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Hollow Structure ◽  
Composite Fiber ◽  
Core Shell ◽  
Composite Fibers ◽  
The Core ◽  
Excellent Photocatalytic Activity ◽  
Repeated Use ◽  
Shell Composite ◽  
High Temperature Calcination

The core-shell NaYF4/Yb/Tm/TiO2 hollow composite fibers were prepared by coaxial electrospinning and high-temperature calcination. The composite fibers exhibit excellent photocatalytic activity under the dual synergistic of regulating the core-shell hollow microstructure and the composition by doping nanoparticles. Compared with commercial P25 and hollow fiber without nanoparticles, the degradation efficiency of rhodamine B using the core-shell composite fiber was significantly improved up to 99%. Moreover, the nanoparticles in the composite fibers can exist stably and maintain good structure and photocatalytic activity after repeated use. Therefore, the composite fiber has a wide application prospect in photocatalytic degradation of organic pollutants.

Magnetic Properties of Fe3O4/CoFe2O4 Composite Nanoparticles with Core/Shell Architecture

2020 ◽  
Vol 65 (10) ◽  
pp. 904
Author(s):  
V. O. Zamorskyi ◽  
Ya. M. Lytvynenko ◽  
A. M. Pogorily ◽  
A. I. Tovstolytkin ◽  
S. O. Solopan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Spinel Ferrite ◽  
Composite Nanoparticles ◽  
Core Shell ◽  
Cofe2o4 Nanoparticles ◽  
Core Diameter ◽  
The Core ◽  
Shell Particles ◽  
Interface Parameters ◽  
Shell Composite

Magnetic properties of the sets of Fe3O4(core)/CoFe2O4(shell) composite nanoparticles with a core diameter of about 6.3 nm and various shell thicknesses (0, 1.0, and 2.5 nm), as well as the mixtures of Fe3O4 and CoFe2O4 nanoparticles taken in the ratios corresponding to the core/shell material contents in the former case, have been studied. The results of magnetic research showed that the coating of magnetic nanoparticles with a shell gives rise to the appearance of two simultaneous effects: the modification of the core/shell interface parameters and the parameter change in both the nanoparticle’s core and shell themselves. As a result, the core/shell particles acquire new characteristics that are inherent neither to Fe3O4 nor to CoFe2O4. The obtained results open the way to the optimization and adaptation of the parameters of the core/shell spinel-ferrite-based nanoparticles for their application in various technological and biomedical domains.

CORE-SHELL Zn/ZnO STRUCTURES WITH IMPROVED PHOTOCATALYTIC PROPERTIES SYNTHESIZED BY AQUEOUS SOLUTION METHOD

2013 ◽  
Vol 06 (06) ◽  
pp. 1350058 ◽  
Author(s):  
YUAN MING HUANG ◽  
QING-LAN MA ◽  
BAO-GAI ZHAI
Keyword(s):  
Aqueous Solution ◽  
Photocatalytic Activity ◽  
Solution Method ◽  
Core Shell ◽  
Green Method ◽  
X Ray ◽  
The Core ◽  
Semiconductor Junction ◽  
Aqueous Solution Method ◽  
Scanning Electron

A facile and green method was utilized to synthesize core-shelled Zn / ZnO microspheres by boiling Zn microparticles in water for improving the photocatalytic activity of ZnO . The synthesized Zn / ZnO core-shells were investigated by means of scanning electron microscope, X-ray diffractometer and photoluminescence spectrometer, respectively. The morphology analysis showed that the metallic Zn core was about 6 μm in diameter while the ZnO shell was about 600 nm in thickness. Compared to ZnO nanoparticles, the core-shelled Zn / ZnO microspheres exhibited improved photocatalytic activity in degrading methyl orange in water. Our results suggest that the metal–semiconductor junction formed at the Zn / ZnO interface is responsible for the enhanced photocatalytic activity of ZnO .

Synthesis of Core-Shell Composite of Conductive Polymeric Materials onto Silica Using Supercritical Carbon Dioxide

MRS Advances ◽  
2020 ◽  
Vol 5 (40-41) ◽  
pp. 2121-2127
Author(s):  
Ssu-Hao Huang ◽  
Pei-Hua Chen ◽  
Yan-Ping Chen ◽  
Muoi Tang
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Polymeric Materials ◽  
Optimal Operation ◽  
Molar Ratio ◽  
Core Shell ◽  
The Core ◽  
Operation Conditions ◽  
Shell Composite ◽  
Supercritical Carbon

ABSTRACTThe polymerization of 3,4-ethylenedioxythiophene (EDOT) onto nanosilica (SiO2) was synthesized in this study by using supercritical carbon dioxide (SCCO2). With the addition of dopants of p-toluenesulfonic acid (p-TSA) or decylbenzene sulfonic acid (DBSA), the PEDOT/SiO2 composite became conductive. The product was characterized by FTIR spectroscopy and the core-shell structure was confirmed through the TEM images. The electrical properties were analyzed by UV-vis absorbance and four-point probe measurement. DBSA is shown as the better dopants with the molar ratio (DBSA/EDOT) of 0.2 at the reaction time of 48 hours. The maximum coating percentage is 63 wt% under the optimal operation conditions at 40oC and 280 bar. The conductivity is tuned up to 6.6×10-2 S/cm after the coating process.

scholarly journals Ag3PO4@holmium phosphate core@shell composites with enhanced photocatalytic activity

RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34705-34713 ◽  
Author(s):  
Fengfeng Li ◽  
Zhihong Li ◽  
Mingxi Zhang ◽  
Yi Shen ◽  
Yongfeng Cai ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Core Shell ◽  
Heterojunction Structure ◽  
The Core ◽  
Composite Photocatalysts

In this study, Ag3PO4@holmium phosphate (HP) composite photocatalysts were firstly prepared. The core–shell heterojunction structure of Ag3PO4@HP significantly improved the photocatalytic activity of Ag3PO4.

Synthesis Technology of Silica Aerogels/Polystyrene Core-Shell Composite Materials

2010 ◽  
Vol 168-170 ◽  
pp. 1833-1836
Author(s):  
Gang Qiang Geng ◽  
Jing Tao Guo ◽  
Jun Jun Zou ◽  
Gong Xun Bian
Keyword(s):  
Composite Materials ◽  
Polymerization Process ◽  
System Component ◽  
Core Shell ◽  
Ultrasound Technique ◽  
The Core ◽  
Optimum Reaction ◽  
The Impact ◽  
Shell Composite

In order to obtain super aerogels heat insulating composite materials with silane coupling agent on the in-situ surface treatment. The core-shell structure composite materials have been prepared by dispersion polymerization process of polystyrene grafted on the SiO2 particles. By TEM on these samples the impact of the system components initiator polymerization parameters and dispersion process was discussed. The results showed that the system component of the greatest impact on conversion rate is the ratio of aerogels /St ,the optimum reaction temperature is 75 °C.With organic initiator KPS as initiator after a unique ultrasound technique to obtain the core-shell composite materials structure which coating is 70%.

Structural, Dielectric, and Magnetic Studies on Electrospun Magnesium Ferrite-Polyvinylidene Fluoride Core–Shell Composite Fibers

2014 ◽  
Vol 27 (4) ◽  
pp. 557-562 ◽  
Author(s):  
V. Revathi ◽  
S. Dinesh Kumar ◽  
P. Chithra Lekha ◽  
V. Subramanian ◽  
T. S. Natarajan ◽  
...  
Keyword(s):  
Polyvinylidene Fluoride ◽  
Core Shell ◽  
Magnesium Ferrite ◽  
Composite Fibers ◽  
Magnetic Studies ◽  
Shell Composite

Use of a core-shell composite Ag 3 PO 4 @TCNQ to improve photocatalytic activity and stability

2017 ◽  
Vol 425 ◽  
pp. 329-339 ◽  
Author(s):  
Panru Hu ◽  
Li Liu ◽  
Weijia An ◽  
Yinghua Liang ◽  
Wenquan Cui
Keyword(s):  
Photocatalytic Activity ◽  
Core Shell ◽  
Shell Composite

Polypyrrole-stabilized gold nanorods with enhanced photothermal effect towards two-photon photothermal therapy

2015 ◽  
Vol 3 (22) ◽  
pp. 4539-4545 ◽  
Author(s):  
Cuiling Du ◽  
Anhe Wang ◽  
Jinbo Fei ◽  
Jie Zhao ◽  
Junbai Li
Keyword(s):  
Tumor Cells ◽  
Gold Nanorods ◽  
Photothermal Therapy ◽  
Photothermal Effect ◽  
Core Shell ◽  
Two Photon ◽  
The Core ◽  
Shell Composite

The core–shell composite of Au–polypyrrole nanorods with high two-photon photothermal effect and stability could efficiently kill tumor cells under irradiation.

Controlling the Core–Shell Structure of CuS@CdS Heterojunction via Seeded Growth with Tunable Photocatalytic Activity

2018 ◽  
Vol 6 (11) ◽  
pp. 15867-15875 ◽  
Author(s):  
Naixu Li ◽  
Wenlong Fu ◽  
Chen Chen ◽  
Maochang Liu ◽  
Fei Xue ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Shell Structure ◽  
Core Shell ◽  
Seeded Growth ◽  
The Core ◽  
Core Shell Structure

Novel core–shell structured BiVO4 hollow spheres with an ultra-high surface area as visible-light-driven catalyst

CrystEngComm ◽  
2014 ◽  
Vol 16 (27) ◽  
pp. 6059-6065 ◽  
Author(s):  
Yang Lu ◽  
Yong-Song Luo ◽  
Hong-Mei Xiao ◽  
Shao-Yun Fu
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Surface Area ◽  
High Surface ◽  
Hollow Spheres ◽  
High Surface Area ◽  
Core Shell ◽  
Hydrothermal Route ◽  
Excellent Photocatalytic Activity ◽  
Visible Light Driven

Novel core–shell-structured BiVO4 hollow spheres synthesized via a simple hydrothermal route exhibit an excellent photocatalytic activity.

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