scholarly journals Introduction to the New Copolymer of Chloroprene and Acrylonitrile with Differentiated Properties

2021 ◽  
Vol 2021 ◽  
pp. 1-17
Author(s):  
Mousumi De Sarkar ◽  
Wataru Nishino ◽  
Yuhei Ishigaki ◽  
Takashi Sunada
Keyword(s):  
Low Temperature ◽  
Fatigue Resistance ◽  
Random Copolymer ◽  
High Heat ◽  
Industrial Applications ◽  
Nitrile Rubber ◽  
Scanning Calorimetry ◽  
Fluid Resistance ◽  
Random Microstructure ◽  
Chloroprene Rubber

The random copolymer of chloroprene and acrylonitrile is a newly developed rubber whose features and value propositions are not scientifically explored yet. This article focuses on the basic characterizations and properties of acrylonitrile-chloroprene rubber. Qualitative analyses through infrared (FTIR) and nuclear magnetic resonance (1H-NMR) spectra confirm the presence of both the -Cl and -CN groups in the new rubber. As evidenced through differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA), the single glass transition temperature of acrylonitrile-chloroprene rubber reflects its monophasic random microstructure. While compared against commercial grades of chloroprene rubber (CR) and nitrile rubber (NBR), the new rubber provides a distinctive combination of properties that are not available with either of the elastomer alone. Acrylonitrile-chloroprene rubber demonstrates slightly lower specific gravity, an improved low-temperature compression set, higher flex-fatigue resistance, and lower volume swelling in IRM 903 and Fuel C to chloroprene rubber. As compared to nitrile rubber, the new copolymer shows appreciably better heat aging and ozone resistance. Good abrasion resistance, low heat buildup, and remarkably high flex-fatigue resistance indicate excellent durability of the acrylonitrile-chloroprene rubber under dynamic loading. Based on the preliminary results, it is apparent that the new copolymer can be a candidate elastomer for various industrial applications which demand good fluid resistance, high heat and low-temperature tolerances, good weatherability, and durability under static and dynamic conditions.

Chemical Heat Storage with LiOH/LiOH·H2O Reaction for Low-Temperature Heat below 373 K

2014 ◽  
Vol 953-954 ◽  
pp. 757-760 ◽  
Author(s):  
Mitushiro Kubota ◽  
Satoshi Matsumoto ◽  
Hitoki Matsuda ◽  
Hong Yu Huang ◽  
Zhao Hong He ◽  
...  
Keyword(s):  
Low Temperature ◽  
Heat Storage ◽  
Reaction System ◽  
Energy System ◽  
High Heat ◽  
Chemical Heat ◽  
Scanning Calorimetry ◽  
Fundamental Study ◽  
Storage Density ◽  
Temperature Heat

There is a great demand on promotion of heat utilization below 373 K to establish highly-efficient energy system, because such heat is enormously unused and discharged from every process. Towards this demand, we have focused on chemical heat storage due to its high heat storage density. In this study, the promising inorganic hydrates were investigated for low-temperature heat storage with the differential scanning calorimetry. Consequently, it is found that lithium hydroxide monohydrate dehydrates at 337 K with endothermic heat of 1,440 kJ/kg-LiOH・H2O. Due to its high storage density and the simplicity of dehydration reaction, LiOH/LiOH・H2O reaction was chose as the most promising reaction for chemical heat storage below 373 K. From the chemical equilibrium calculation, this reaction system is found to be more suitable for chemical heat storage than chemical heat pump. Fundamental study of dehydration behavior of LiOH・H2O was also performed with a thermogravimetric analyzer, and the apparent activation energy of dehydration of LiOH・H2O was determined to be 51.7 kJ/mol in the conversion ranges of 0.4-0.7.

scholarly journals Synthesis of Low Temperature Resistant Hydrogenated Nitrile Rubber Based on Esterification Reaction

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4096
Author(s):  
Lin Wang ◽  
Yanqiang Ni ◽  
Xin Qi ◽  
Liqun Zhang ◽  
Dongmei Yue
Keyword(s):  
Low Temperature ◽  
Nitrile Rubber ◽  
Petroleum Exploration ◽  
Esterification Reaction ◽  
Grafted Polymers ◽  
Scanning Calorimetry ◽  
Temperature Resistance ◽  
Molecular Weights ◽  
Cold Environments ◽  
Low Temperature Resistance

Hydrogenated Nitrile Rubber (HNBR) is widely used in aerospace, petroleum exploration and other fields because of its excellent performances. However, there remains a challenge of balancing the oil resistance and the low temperature resistance for HNBR. In this work, a series of grafted carboxyl nitrile rubber (XNBR) was prepared by the esterification reaction between active functional groups (–COOH) of XNBR and alkanols of different molecular chain lengths (C8H17OH, C12H25OH, C16H33OH, C18H37OH) or Methoxypolyethylene glycols (MPEG) of different molecular weights (Mn = 350, 750, 1000). The structure and low temperature resistance of as-obtained grafted polymers were characterized by Fourier Transform Infrared (FTIR), 1H-NMR and Differential scanning calorimetry (DSC). It was found that the glass transition temperatures (Tg) of grafted XNBR were significantly decreased. MPEG grafted polymers with better low temperature resistance were then selected for hydrogenation. As-prepared hydrogenated XNBR grafted with MPEG-1000 (HXNBR-g-1000) showed the lowest Tg of −29.8 °C and the best low temperature resistance. This work provides a novel and simple preparation method for low temperature resistant HNBR, which might be used potentially in extremely cold environments.

Study on low temperature toughness and crystallization behavior of polypropylene random copolymer

2017 ◽  
Vol 37 (7) ◽  
pp. 715-727 ◽  
Author(s):  
Yingchun Li ◽  
Shuai He ◽  
Hui He ◽  
Peng Yu ◽  
Dongqing Wang
Keyword(s):  
Low Temperature ◽  
Crystallization Behavior ◽  
Annealing Treatment ◽  
Random Copolymer ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Polyolefin Elastomer ◽  
The Matrix ◽  
Low Temperature Toughness ◽  
Polymorphic Composition

Abstract This research designed a series of novel approaches aiming to tackle a long-standing problem that is the brittleness of polypropylene (PP) random copolymer (PPR) at low temperature. By introducing polyolefin elastomer (POE), the toughness of PPR was improved; talc improved the stiffness of PPR, low density polyethylene (LDPE) or high density PE (HDPE) improved the low temperature toughness of PPR, and annealing treatment also improved the low temperature toughness of PPR significantly. The addition of dicumyl peroxide (DCP) and triallyl isocyanurate (TAIC) increased its stiffness through the formation of cross-linking networks. Also, the crystallization behavior and morphology were investigated in detail. Differential scanning calorimetry (DSC) results indicated that the adoption of annealing treatment can improve the crystallinity of PPR, while a polarizing microscope revealed that the incorporation of foreign matter can facilitate the crystallization process of the matrix. X-ray diffraction (XRD) tests showed an unchanged polymorphic composition of PPR after introducing different additives, and scanning electron microscopy (SEM) indicated that annealing treatment can enhance interfacial interactions between the matrix and fillers.

scholarly journals Quadruple Hydrogen Bond-Containing A-AB-A Triblock Copolymers: Probing the Influence of Hydrogen Bonding in the Central Block

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4705
Author(s):  
Boer Liu ◽  
Xi Chen ◽  
Glenn A. Spiering ◽  
Robert B. Moore ◽  
Timothy E. Long
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Microphase Separation ◽  
Triblock Copolymers ◽  
Random Copolymer ◽  
Thermomechanical Properties ◽  
Structure Property ◽  
Scanning Calorimetry ◽  
Central Block ◽  
Quadruple Hydrogen Bonding

This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit contained cytosine acrylate (CyA) or post-functionalized ureido cytosine acrylate (UCyA) and the B unit consisted of n-butyl acrylate (nBA). Differential scanning calorimetry revealed two glass transition temperatures, suggesting microphase-separation in the A-AB-A triblock copolymers. Thermomechanical and morphological analysis revealed the effects of hydrogen bonding distribution and strength on the self-assembly and microphase-separated morphology. Dynamic mechanical analysis showed multiple tan delta (δ) transitions that correlated to chain relaxation and hydrogen bonding dissociation, further confirming the microphase-separated structure. In addition, UCyA triblock copolymers possessed an extended modulus plateau versus temperature compared to the CyA analogs due to the stronger association of quadruple hydrogen bonding. CyA triblock copolymers exhibited a cylindrical microphase-separated morphology according to small-angle X-ray scattering. In contrast, UCyA triblock copolymers lacked long-range ordering due to hydrogen bonding induced phase mixing. The incorporation of UCyA into the soft central block resulted in improved tensile strength, extensibility, and toughness compared to the AB random copolymer and A-B-A triblock copolymer comparisons. This study provides insight into the structure-property relationships of A-AB-A supramolecular triblock copolymers that result from tunable association strengths.

scholarly journals Effect of Multiple Reflows on the Interfacial Reactions and Mechanical Properties of an Sn-0.5Cu-Al(Si) Solder and a Cu Substrate

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2367
Author(s):  
Junhyuk Son ◽  
Dong-Yurl Yu ◽  
Yun-Chan Kim ◽  
Shin-Il Kim ◽  
Min-Su Kim ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Heat ◽  
Interfacial Reactions ◽  
Future Application ◽  
Scanning Calorimetry ◽  
Cross Sectional ◽  
Automotive Electronic ◽  
Transmission Electron ◽  
Si Content ◽  
Lead Free Solders

In this study, the interfacial reactions and mechanical properties of solder joints after multiple reflows were observed to evaluate the applicability of the developed materials for high-temperature soldering for automotive electronic components. The microstructural changes and mechanical properties of Sn-Cu solders regarding Al(Si) addition and the number of reflows were investigated to determine their reliability under high heat and strong vibrations. Using differential scanning calorimetry, the melting points were measured to be approximately 227, 230, and 231 °C for the SC07 solder, SC-0.01Al(Si), and SC-0.03Al(Si), respectively. The cross-sectional analysis results showed that the total intermetallic compounds (IMCs) of the SC-0.03Al(Si) solder grew the least after the as-reflow, as well as after 10 reflows. Electron probe microanalysis and transmission electron microscopy revealed that the Al-Cu and Cu-Al-Sn IMCs were present inside the solders, and their amounts increased with increasing Al(Si) content. In addition, the Cu6Sn5 IMCs inside the solder became more finely distributed with increasing Al(Si) content. The Sn-0.5Cu-0.03Al(Si) solder exhibited the highest shear strength at the beginning and after 10 reflows, and ductile fracturing was observed in all three solders. This study will facilitate the future application of lead-free solders, such as an Sn-Cu-Al(Si) solder, in automotive electrical components.

scholarly journals Combined thermal analysis of plant oils

2021 ◽  
Author(s):  
Kinga Tamási ◽  
Kálmán Marossy
Keyword(s):  
Thermal Analysis ◽  
Differential Scanning Calorimetry ◽  
Low Temperature ◽  
Glassy State ◽  
Mechanical Analysis ◽  
Plant Oils ◽  
Scanning Calorimetry ◽  
Natural Plant ◽  
The Moment ◽  
Current Reversal

AbstractThe paper deals with the study of seven selected natural plant oils. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermally stimulated discharge (TSD) methods were used. It has been found that most of the oils tested are in a glassy state at low temperature and have multiple transitions in the low temperature range. DSC shows complex melting-like processes or glass transition. For both DMA and TSD, the scaffold supportive method was used and found as a suitable one. DMA and TSD proved more sensitive than DSC and revealed at least two transitions between − 120 and − 40 °C. In the case of three oils (argan, avocado and sunflower), current reversal was observed by TSD; this symptom cannot be fully explained at the moment.

Application of the Continuous Rheoconversion Process (CRP) to Low Temperature HPDC-Part I: Microstructure

2006 ◽  
Vol 116-117 ◽  
pp. 402-405 ◽  
Author(s):  
Qin Yue Pan ◽  
Stuart Wiesner ◽  
Diran Apelian
Keyword(s):  
Low Temperature ◽  
Scale Up ◽  
Microstructural Characterization ◽  
Industrial Applications ◽  
Primary Phase ◽  
Heat Extraction ◽  
Initial Stage ◽  
Fraction Solid ◽  
Die Castings

The continuous rheoconversion process (CRP) is a novel slurry-on-demand process that was developed at MPI/WPI in 2002. The process is based on a passive liquid mixing technique in which the nucleation and growth of the primary phase are controlled using a specially designed “reactor”. The reactor provides heat extraction, copious nucleation, and forced convection during the initial stage of solidification, thus leading to the formation of globular structures. This paper presents our recent work on the scale-up of the CRP for industrial applications. Specifically, we demonstrate an important application of the CRP to low temperature (low fraction solid) HPDC. In Part I of this paper, we present salient results on microstructural characterization of CRP processed castings vs. conventional die castings.

scholarly journals Gold in Irish Coal: Palaeo-Concentration from Metalliferous Groundwaters

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 635
Author(s):  
Liam A. Bullock ◽  
John Parnell ◽  
Joseph G.T. Armstrong ◽  
Magali Perez ◽  
Sam Spinks
Keyword(s):  
Heat Flow ◽  
Low Temperature ◽  
Precious Metals ◽  
High Heat ◽  
Selenium Content ◽  
Foreland Basins ◽  
High Heat Flow ◽  
South Wales ◽  
First Time ◽  
Very High

Gold grains, up to 40 μm in size and containing variable percentages of admixed platinum, have been identified in coals from the Leinster Coalfield, Castlecomer, SE Ireland, for the first time. Gold mineralisation occurs in sideritic nodules in coals and in association with pyrite and anomalous selenium content. Mineralisation here may have reflected very high heat flow in foreland basins north of the emerging Variscan orogenic front, responsible for gold occurrence in the South Wales Coalfield. At Castlecomer, gold (–platinum) is attributed to precipitation with replacive pyrite and selenium from groundwaters at redox interfaces, such as siderite nodules. Pyrite in the cores of the nodules indicates fluid ingress. The underlying Caledonian basement bedrock is mineralised by gold, and thus likely provided a source for gold. The combination of the gold occurrences in coal in Castlecomer and in South Wales, proximal to the Variscan orogenic front, suggests that these coals along the front could comprise an exploration target for low-temperature concentrations of precious metals.

Effect of Welding Processes with High Heat Input on the Microstructure and Toughness of Coarse-Grained Heat-Affected Zone of a High-Strength High-Toughness Steel

2018 ◽  
Vol 937 ◽  
pp. 61-67
Author(s):  
Yu Jie Li ◽  
Jin Wei Lei ◽  
Xuan Wei Lei ◽  
Oleksandr Hress ◽  
Kai Ming Wu
Keyword(s):  
Low Temperature ◽  
Impact Toughness ◽  
Heat Affected Zone ◽  
Heat Input ◽  
High Strength ◽  
High Heat ◽  
Coarse Grained ◽  
Low Temperature Impact Toughness ◽  
The Impact ◽  
Welding Processes

Utilizing submerged arc welding under heat input 50 kJ/cm on 60 mm thick marine engineering structure plate F550, the effect of preheating and post welding heat treatment on the microstructure and impact toughness of coarse-grained heat-affected zone (CGHAZ) has been investigated. The original microstructure of the steel plate is tempered martensite. The yield and tensile strength is 610 and 660 MPa, respectively. The impact absorbed energy at low temperature (-60 °C) at transverse direction reaches about 230~270 J. Welding results show that the preheating at 100 °C did not have obvious influence on the microstructure and toughness; whereas the tempering at 600 °C for 2.5 h after welding could significantly reduce the amount of M-A components in the coarse-grained heat-affected zone and thus improved the low temperature impact toughness.

scholarly journals Formation of Pharmaceutical Salts and Cocrystals via Vapour-Assisted Tumbling (VAT) – A Solvent Efficient Process with Potential Industrial Applications

2021 ◽  
Author(s):  
Alexander J. Stirk ◽  
Fabio E. S. Souza ◽  
Jenny Gerster ◽  
Fatemeh M. Mir ◽  
Avedis Karadeolian ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Environmental Impact ◽  
Industrial Applications ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
New Techniques ◽  
X Ray ◽  
Industry Standard ◽  
Pharmaceutical Salts ◽  
Solid Form

Crystallisations on both the academic and industrial scale often use large volumes of solvent. In order decrease the environmental impact of such processes, new techniques must be discovered that increase the efficiency of the solvents used. Introduced here is a process that combines repurposed industry standard hardware and aspects of mechanochemistry to produce a technique we call “Vapour Assisted Tumbling” (VAT). Pharmaceutical and well-known cocrystals and salts were formed by tumbling the coformers in an atmosphere of vaporised solvent, in this study, methanol (MeOH). This was done inside a custom built analogue of an industrial rotary cone dryer (RCD). It was found that a desired solid form could be obtained as monitored by powder X-ray diffraction and differential scanning calorimetry. By repurposing industrial RCDs, it is feasible that solid forms can be crystallised with both minimal and reusable/recyclable solvent – drastically lowering the environmental impact of such transformations.

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