scholarly journals Corrigendum to “A New Density Model of Quartz Solubility in H2O-CO2-NaCl Ternary Systems up to High Temperatures and High Pressures”

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-1
Author(s):  
Weiping Deng ◽  
Qing Wei ◽  
Xuan Liu

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-23
Author(s):  
Weiping Deng ◽  
Qing Wei ◽  
Xuan Liu

A novel density model for computing quartz solubility in H2O-CO2-NaCl hydrothermal fluids applicable to wide ranges of temperature and pressure is proposed. Based on the models of Akinfiev and Diamond (2009) and Wei et al. (2012), the effective partial molar volume of water ( V H 2 O ∗ ) is replaced by the partial molar volume of water ( V ¯ H 2 O ) by implementing an empirical correction, and water molar fraction ( x H 2 O ) is modified with water activity ( a H 2 O ), in addition to a series of changes to the model coefficient forms. The absolute values of averaged relative deviation of this model compared to the experimental data sets in pure water, H2O-CO2, and H2O-NaCl solutions are 5.74%, 6.69%, and 7.09%, respectively, which are better than existing models in the literature. The model can be reliably used for computing quartz solubilities in pure water from 0°C to 1000°C, from 0 bar to 20,000 bar, and in CO2- and/or NaCl-bearing solutions from 0°C to 1000°C, from 0 bar to 10,000 bar (with slightly lower accuracy at 5000-10,000 bar in H2O-NaCl systems) in the single liquid region. Moreover, the trends and overall ranges of this model may probably be more accurate in the H2O-CO2-NaCl fluid mixtures compared to the limited experimental data. In addition, a bisection algorithm for deriving the isopleths of quartz solubilities based on this new model is first proposed, and application perspectives are discussed for various geologic settings including subduction zone, lower crust-upper mantle, migmatite, pegmatite, porphyry, and orogenic deposits.


2010 ◽  
Vol 133 (4) ◽  
pp. 044503 ◽  
Author(s):  
Min Li ◽  
Fangfei Li ◽  
Wei Gao ◽  
Chunli Ma ◽  
Liyin Huang ◽  
...  

During the researches upon high-pressure explosions of carbonic oxide-air, hydrogen-air, etc., mixtures, which have been described in the previous papers of this series, a mass of data has been accumulated relating to the influence of density and temperature upon the internal energy of gases and the dissociation of steam and carbon dioxide. Some time ago, at Prof. Bone’s request, the author undertook a systematic survey of the data in question, and the present paper summarises some of the principal results thereof, which it is hoped will throw light upon problems interesting alike to chemists, physicists and internal-combustion engineers. The explosion method affords the only means known at present of determining the internal energies of gases at very high temperatures, and it has been used for this purpose for upwards of 50 years. Although by no means without difficulties, arising from uncertainties of some of the assumptions upon which it is based, yet, for want of a better, its results have been generally accepted as being at least provisionally valuable. Amongst the more recent investigations which have attracted attention in this connection should be mentioned those of Pier, Bjerrum, Siegel and Fenning, all of whom worked at low or medium pressures.


2017 ◽  
Vol 58 (6) ◽  
pp. 886-891 ◽  
Author(s):  
Kenichi Koide ◽  
Toshirou Anraku ◽  
Akihiro Iwase ◽  
Hiroyuki Inoue

1996 ◽  
Vol 11 (9) ◽  
pp. 2186-2197 ◽  
Author(s):  
H. Z. Xiao ◽  
I. M. Robertson ◽  
H. K. Birnbaum

The microstructural and microchemical changes produced in a Ti–25Al–10Nb–3V–1Mo alloy (at. %) by charging at high temperatures in high pressures of hydrogen gas have been studied using transmission electron microscopy (TEM) and x-ray methods. Hydrides incorporating all of the substitutional solutes that formed during charging have a face-centered cubic (fcc) structure and exhibit either a plate or fine-grained morphology. With increasing hydrogen content, the size of the hydrides decreases and their microchemistry changes as they approach the stable binary hydride, TiH2. Rejection of substitutional solute elements from the hydride produces changes in the microchemistry, and consequently in the crystal structure, of the surrounding matrix. In alloys containing 50 at. % H, this solute redistribution results in the formation of an orthohombic substitutional solid solution phase containing increased levels of Nb. The driving force of this redistribution of solutes is the reduction in the chemical potential of the system as the amount of the most stable hydride, TiH2, forms. The hydrides reverted to a solid solution on annealing in vacuum at 1073 K, and the original microchemistry of the alloy was restored. Reversion from the hydride structure to the original α2 ordered DO19 structure proceeds via a disordered HCP phase.


2015 ◽  
Vol 86 (7) ◽  
pp. 072207 ◽  
Author(s):  
Yoshio Kono ◽  
Curtis Kenney-Benson ◽  
Yuki Shibazaki ◽  
Changyong Park ◽  
Yanbin Wang ◽  
...  

Author(s):  
Simon MacLeod ◽  
Daniel Errandonea ◽  
Geoffrey Adam Cox ◽  
Hyunchae Cynn ◽  
Dominik Daisenberger ◽  
...  

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