scholarly journals Shape Memory Corrosion-Resistant Polymeric Materials

2021 ◽  
Vol 2021 ◽  
pp. 1-18
Author(s):  
Nathan D. Jacobson ◽  
Jude Iroh
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Corrosion Inhibition ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Polymeric Materials ◽  
Initial Position ◽  
Self Healing ◽  
Future Prospects ◽  
Corrosion Resistant

Shape memory alloys, materials capable of being deformed and maintaining the deformation and additionally capable of returning to the initial position, are valued for a range of applications from actuators to flexible microdevices. Maintaining the properties that make them useful, their ability to deform and reform, requires that shape memory alloys must be protected against corrosion, in which the integration of shape memory polymers can act as a means of protection. Thus, this review is to highlight the utility of self-healing shape memory polymers as a means of corrosion inhibition. Therefore, this review discusses the benefits of utilizing self-healing shape memory polymers for the protection of shape memory, several types of self-healing polymers that could be used, means of improving or tailoring the polymers towards specific usages, and future prospects in designing a shape memory polymer for use in corrosion inhibition.

scholarly journals Harnessing reversible dry adhesion using shape memory polymer microparticles

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Memory Effects ◽  
Reversible Adhesion ◽  
Dry Adhesion ◽  
Bonding Property ◽  
Shape Memory Effects ◽  
Polymer Microparticles

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.

scholarly journals In Situ Generation of Green Hybrid Nanofibrillar Polymer-Polymer Composites—A Novel Approach to the Triple Shape Memory Polymer Formation

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1900
Author(s):  
Ramin Hosseinnezhad ◽  
Iurii Vozniak ◽  
Fahmi Zaïri
Keyword(s):  
Polymer Blends ◽  
Shape Memory ◽  
Shape Memory Polymer ◽  
Cellulose Nanofibers ◽  
Polymeric Materials ◽  
Novel Approach ◽  
Phase Transition Temperatures ◽  
Triple Shape Memory

The paper discusses the possibility of using in situ generated hybrid polymer-polymer nanocomposites as polymeric materials with triple shape memory, which, unlike conventional polymer blends with triple shape memory, are characterized by fully separated phase transition temperatures and strongest bonding between the polymer blends phase interfaces which are critical to the shape fixing and recovery. This was demonstrated using the three-component system polylactide/polybutylene adipateterephthalate/cellulose nanofibers (PLA/PBAT/CNFs). The role of in situ generated PBAT nanofibers and CNFs in the formation of efficient physical crosslinks at PLA-PBAT, PLA-CNF and PBAT-CNF interfaces and the effect of CNFs on the PBAT fibrillation and crystallization processes were elucidated. The in situ generated composites showed drastically higher values of strain recovery ratios, strain fixity ratios, faster recovery rate and better mechanical properties compared to the blend.

scholarly journals Structural multi-colour invisible inks with submicron 4D printing of shape memory polymers

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wang Zhang ◽  
Hao Wang ◽  
Hongtao Wang ◽  
John You En Chan ◽  
Hailong Liu ◽  
...  
Keyword(s):  
Shape Memory ◽  
Information Hiding ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Photonic Devices ◽  
Temperature Sensitive ◽  
4D Printing ◽  
Two Photon ◽  
Shape Memory Effects ◽  
Nanoscale Structure

AbstractFour-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D printing of a SMP in the submicron length scale, extending its applications to nanophononics. We report a new SMP photoresist based on Vero Clear achieving print features at a resolution of ~300 nm half pitch using two-photon polymerization lithography (TPL). Prints consisting of grids with size-tunable multi-colours enabled the study of shape memory effects to achieve large visual shifts through nanoscale structure deformation. As the nanostructures are flattened, the colours and printed information become invisible. Remarkably, the shape memory effect recovers the original surface morphology of the nanostructures along with its structural colour within seconds of heating above its glass transition temperature. The high-resolution printing and excellent reversibility in both microtopography and optical properties promises a platform for temperature-sensitive labels, information hiding for anti-counterfeiting, and tunable photonic devices.

Structural tuning of polycaprolactone based thermadapt shape memory polymer

2020 ◽  
Vol 11 (7) ◽  
pp. 1369-1374 ◽  
Author(s):  
Wusha Miao ◽  
Weike Zou ◽  
Yingwu Luo ◽  
Ning Zheng ◽  
Qiao Zhao ◽  
...  
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Controlled Structures

Polycaprolactone based thermadapt shape memory polymers with precisely controlled structures allow tunable shape reconfigurability.

Novel Behavior in Smart Polymeric Materials: Stress Memory and its Potential Applications

2016 ◽  
Vol 97 ◽  
pp. 93-99
Author(s):  
Jin Lian Hu ◽  
Harishkumar Narayana
Keyword(s):  
Magnetic Field ◽  
Shape Memory ◽  
Smart Materials ◽  
Shape Memory Polymers ◽  
Polymeric Materials ◽  
External Stimulus ◽  
Artificial Muscles ◽  
Recovery Stress ◽  
Stress Memory ◽  
Potential Applications

Materials, structures and systems, responsive to an external stimulus are smart and adaptive to our human demands. Among smart materials, polymers with shape memory effect are at the forefront of research leading to comprehensive publications and wide applications. In this paper, we extend the concept of shape memory polymers to stress memory ones, which have been discovered recently. Like shape memory, stress memory represents a phenomenon where the stress in a polymer can be programmed, stored and retrieved reversibly with an external stimulus such as temperature and magnetic field. Stress memory may be mistaken as the recovery stress which was studied quite broadly. Our further investigation also reveals that stress memory is quite different from recovery stress containing multi-components including elastic and viscoelastic forces in addition to possible memory stress. Stress memory could be used into applications such as sensors, pressure garments, massage devices, electronic skins and artificial muscles. The current revelation of stress memory potentials is emanated from an authentic application of memory fibres, films, and foams in the smart compression devices for the management of chronic and therapeutic disorders.

Mechanics of nickel–titanium shape memory alloys undergoing partially constrained recovery for self-healing materials

2018 ◽  
Vol 29 (15) ◽  
pp. 3025-3036 ◽  
Author(s):  
Nathan Salowitz ◽  
Ameralys Correa ◽  
Trishika Santebennur ◽  
Afsaneh Dorri Moghadam ◽  
Xiaojun Yan ◽  
...  
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Nickel Titanium ◽  
Self Healing ◽  
Bonding Agents ◽  
Compressive Loads ◽  
Martensitic State ◽  
Geometric Changes ◽  
Shape Memory Fibers

Engineered self-healing materials seek to create an innate ability for materials to restore mechanical strength after incurring damage, much like biological organisms. This technology will enable the design of structures that can withstand their everyday use without damage but also recover from damage due to an overload incident. One of the primary mechanisms for self-healing is the incorporation of shape memory fibers in a composite type structure. Upon activation, these shape memory fibers can restore geometric changes caused by damage and close fractures. To date, shape memory–based self-healing, without bonding agents, has been limited to geometric restoration without creating a capability to withstand externally applied tensile loads due to the way the shape memory material has been integrated into the composite. Some form of bonding has been necessary for self-healing materials to resist an externally applied load after healing. This article presents results of new study into using a form of constrained recovery of nickel–titanium shape memory alloys in self-healing materials to create residual compressive loads across fractures in the low temperature martensitic state. Analysis is presented relating internal loads in self-healing materials, potentially generated by shape memory alloys, to the capability to resist externally applied loads. Supporting properties were experimentally characterized in nickel–titanium shape memory alloy wires. Finally, self-healing samples were synthesized and tested demonstrating the ability to resist externally applies loads without bonding. This study provides a new useful characterization of nickel–titanium applicable to self-healing structures and opens the door to new forms of healing like incorporation of pressure-based bonding.

Research on PA Heat-Melt Adhesive Being Used as Self-Healing Agent in Cementitious Materials

2011 ◽  
Vol 374-377 ◽  
pp. 1899-1903
Author(s):  
Xiong Zhou Yuan ◽  
Wei Sun ◽  
Xiao Bao Zuo
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Chemical Stability ◽  
Bonding Strength ◽  
Research Team ◽  
Cementitious Materials ◽  
Experimental Results ◽  
Self Healing ◽  
Detailed Consideration ◽  
Healing Agent

Based on detailed consideration of the autonomic healing concept of microencapsulated healing agent, micro- bacteria induced calcite and shape memory alloys, our research team proposed a new self-healing technique coupled with of SMA and heat-melt adhesive. In this article, chemical stability and bonding strength with cementitious materials of PA heat-melt adhesive were tested. Experimental results show that PA heat-melt adhesive may contain the ability being used in self-healing techniques coupled with SMA.

Deployable Process Analysis of Packaged SMP Sandwich Beam

2010 ◽  
Vol 123-125 ◽  
pp. 943-946 ◽  
Author(s):  
Zheng Fa Li ◽  
Zheng Dao Wang
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Sandwich Structure ◽  
Shape Recovery ◽  
Process Analysis ◽  
Sandwich Beam ◽  
Shape Memory Polymers ◽  
Recovery Stress ◽  
Recovery Response

Shape memory polymers own many advantages compared with traditional shape memory alloys or ceramics. In order to improve their shape recovery stress and realize a stable recovery response during the deployable process, the structure of SMP sandwich beam composed of two metallic skin and one SMP core is considered. The recovery behaviors of pure SMP and SMP beams reinforced by one-layer metallic skin are also discussed for comparison. The results confirm that the deployable properties of SMP matrix can be significantly improved by using sandwich structure.

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