scholarly journals Age Discrimination of Chinese Baijiu Based on Midinfrared Spectroscopy and Chemometrics

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Shiqi Hu ◽  
Le Wang
Keyword(s):  
Storage Time ◽  
Principal Component ◽  
Age Discrimination ◽  
Gas Chromatography Mass Spectrometry ◽  
Support Vector ◽  
Accuracy Rate ◽  
Chinese Liquor ◽  
Mir Spectroscopy ◽  
Test Sets ◽  
Accuracy Rates

Baijiu is a traditional and popular Chinese liquor which is affected by the storage time. The longer the storage time of Baijiu is, the better its quality is. In this paper, the raw and mellow Baijiu samples from different storage time are discriminated accurately throughout midinfrared (MIR) spectroscopy and chemometrics. Firstly, changing regularities of the substances in Chinese Baijiu are discussed by gas chromatography-mass spectrometry (GC-MS) during the aging process. Then, infrared spectrums of Baijiu samples are processed by smoothing, multivariate baseline correction, and the first and second derivative processing, but no significant variation can be observed. Next, the spectral date pretreatment methods are constructively introduced, and principal component analysis (PCA) and discriminant analysis (DA) are developed for data analyses. The results show that the accuracy rates of samples by the DA method in calibration and validation sets are 91.7% and 100%, respectively. Consequently, an identification model based on support vector machine (SVM) and PCA is established combined with the grid search strategy and cross-validation methods to discriminate the age of Chinese Baijiu validly, where 100% classification accuracy rate is obtained in both training and test sets.

scholarly journals Discrimination of Volatiles of Shiitakes (Lentinula edodes) Produced during Drying Process by Electronic Nose

2020 ◽  
Vol 16 (1-2) ◽  
Author(s):  
Hui Zhang ◽  
Jing Peng ◽  
Yu-ren Zhang ◽  
Qiang Liu ◽  
Lei-qing Pan ◽  
...  
Keyword(s):  
Electronic Nose ◽  
Lentinula Edodes ◽  
Solid Phase ◽  
Principal Component ◽  
Gas Chromatography Mass Spectrometry ◽  
Support Vector ◽  
Drying Process ◽  
Drying Time ◽  
Discriminant Models ◽  
Accuracy Rates

AbstractThis study aimed to investigate the potential of electronic nose (E-nose) to differentiate volatiles of shiitakes produced at different drying stages. Shiitakes at different drying time slots were categorized into four groups (fresh, early, middle and late stage) by sensory evaluation. E-nose was used to analyze the volatiles and compared with headspace solid phase micro-extraction combined with gas chromatography-mass spectrometry (HS/GC-MS). The principal component analysis results showed that shiitakes at each stage could be successfully discriminated by E-nose and HS/GC-MS. The differences in volatile organic compounds produced at each stage were mainly caused by sulfurs and alcohols, leading to apparent changes of sensors sensitive to sulfurs, alcohols and aromatic compounds. The discriminant models were established by partial least squares discriminant analysis and support vector machine classification, with accuracy rates of 91.25 % and 95.83 %, respectively. The results demonstrated the potential use of E-nose in classifying and monitoring shiitakes during drying process.

scholarly journals Multivariate characterisation of Italian monovarietal red wines using MIR spectroscopy

OENO One ◽  
2019 ◽  
Vol 53 (4) ◽  
Author(s):  
Giuseppina P. Parpinello ◽  
Arianna Ricci ◽  
Panagiotis Arapitsas ◽  
Andrea Curioni ◽  
Luigi Moio ◽  
...  
Keyword(s):  
Principal Component ◽  
Rapid Screening ◽  
Support Vector ◽  
Red Wines ◽  
Grape Variety ◽  
Absorption Bands ◽  
Linear Discriminant ◽  
Mir Spectroscopy ◽  
Grape Varieties

Aim: The aim of this study was to investigate the application of mid-infrared (MIR) spectroscopy combined with multivariate analysis, to provide a rapid screening tool for discriminating among different Italian monovarietal red wines based on the relationship between grape variety and wine composition in particular phenolic compounds.Methods and results: The MIR spectra (from 4000 to 700 cm‒1) of 110 monovarietal Italian red wines, vintage 2016, were collected and evaluated by selected multivariate data analyses, including principal component analysis (PCA), linear discriminant analysis (DA), support vector machine (SVM), and soft intelligent modelling of class analogy (SIMCA). Samples were collected directly from companies across different regions of Italy and included 11 grape varieties: Sangiovese, Nebbiolo, Aglianico, Nerello Mascalese, Primitivo, Raboso, Cannonau, Teroldego, Sagrantino, Montepulciano and Corvina. PCA showed five wavelengths that mainly contributed to the PC1, including a much-closed peak at 1043 cm‒1, which correspond to the C–O stretch absorption bands that are important regions for glycerol, whereas the ethanol peaks at around 1085 cm‒1. The band at 877 cm‒1 are related to the C–C stretching vibration of organic molecules, whereas the asymmetric stretching for C–O in the aromatic –OH group of polyphenols is within spectral regions from 1050 to 1165 cm‒1. In particular, the (1175)–1100–1060 cm‒1 vibrational bands are combination bands, involving C–O stretching and O–H deformation of phenolic rings. The 1166–1168 cm‒1 peak is attributable to in-plane bending deformations of C–H and C–O groups of polyphenols, respectively, for which polymerisation may cause a slight peak shift due to the formation of H-bridges.The best result was obtained with the SVM, which achieved an overall correct classification for up to 72.2% of the training set, and 44.4% for the validation set of wines, respectively. The Sangiovese wines (n=19) were split into two sub-groups (Sang-Romagna, n=12 and Sang-Tuscany, n=7) considering the indeterminacy of its origins, which is disputed between Romagna and Tuscany. Although the classification of three grape varieties was problematic (Nerello Mascalese, Raboso and Primitivo), the remaining wines were almost correctly assigned to their actual classes.Conclusions: MIR spectroscopy coupled with chemometrics represents an interesting approach for the classification of monovarietal Italian red wines, which is important in quality control and authenticity monitoring.Significance and impact of the study: Authenticity is a main issue in winemaking in terms of quality evaluation and adulteration, in particular for origin certified/protected wines, for which the added marketing value is related to the link of grape variety with the area of origin. This study is part of the D-wine project “The diversity of tannins in Italian red wines”.

scholarly journals Evaluation of IoT-Enabled Monitoring and Electronic Nose Spoilage Detection for Salmon Freshness During Cold Storage

Foods ◽  
2020 ◽  
Vol 9 (11) ◽  
pp. 1579
Author(s):  
Huanhuan Feng ◽  
Mengjie Zhang ◽  
Pengfei Liu ◽  
Yiliu Liu ◽  
Xiaoshuan Zhang
Keyword(s):  
Cold Storage ◽  
Electronic Nose ◽  
Principal Component ◽  
Storage Condition ◽  
Quality Parameters ◽  
Training Dataset ◽  
Support Vector ◽  
Accuracy Rate ◽  
Specific Storage ◽  
Test Dataset

Salmon is a highly perishable food due to temperature, pH, odor, and texture changes during cold storage. Intelligent monitoring and spoilage rapid detection are effective approaches to improve freshness. The aim of this work was an evaluation of IoT-enabled monitoring system (IoTMS) and electronic nose spoilage detection for quality parameters changes and freshness under cold storage conditions. The salmon samples were analyzed and divided into three groups in an incubator set at 0 °C, 4 °C, and 6 °C. The quality parameters, i.e., texture, color, sensory, and pH changes, were measured and evaluated at different temperatures after 0, 3, 6, 9, 12, and 14 days of cold storage. The principal component analysis (PCA) algorithm can be used to cluster electronic nose information. Furthermore, a Convolutional Neural Networks and Support Vector Machine (CNN-SVM) based algorithm is used to cluster the freshness level of salmon samples stored in a specific storage condition. In the tested samples, the results show that the training dataset of freshness is about 95.6%, and the accuracy rate of the test dataset is 93.8%. For the training dataset of corruption, the accuracy rate is about 91.4%, and the accuracy rate of the test dataset is 90.5%. The overall accuracy rate is more than 90%. This work could help to reduce quality loss during salmon cold storage.

scholarly journals Diagnostic Method of Diabetes Based on Support Vector Machine and Tongue Images

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Jianfeng Zhang ◽  
Jiatuo Xu ◽  
Xiaojuan Hu ◽  
Qingguang Chen ◽  
Liping Tu ◽  
...  
Keyword(s):  
Support Vector Machine ◽  
Diagnostic Method ◽  
Predictive Accuracy ◽  
Principal Component ◽  
Support Vector ◽  
Diagnostic Model ◽  
Threshold Method ◽  
Accuracy Rate ◽  
Training Time ◽  
Input Variables

Objective. The purpose of this research is to develop a diagnostic method of diabetes based on standardized tongue image using support vector machine (SVM).Methods.Tongue images of 296 diabetic subjects and 531 nondiabetic subjects were collected by the TDA-1 digital tongue instrument. Tongue body and tongue coating were separated by the division-merging method and chrominance-threshold method. With extracted color and texture features of the tongue image as input variables, the diagnostic model of diabetes with SVM was trained. After optimizing the combination of SVM kernel parameters and input variables, the influences of the combinations on the model were analyzed.Results. After normalizing parameters of tongue images, the accuracy rate of diabetes predication was increased from 77.83% to 78.77%. The accuracy rate and area under curve (AUC) were not reduced after reducing the dimensions of tongue features with principal component analysis (PCA), while substantially saving the training time. During the training for selecting SVM parameters by genetic algorithm (GA), the accuracy rate of cross-validation was grown from 72% or so to 83.06%. Finally, we compare with several state-of-the-art algorithms, and experimental results show that our algorithm has the best predictive accuracy.Conclusions.The diagnostic method of diabetes on the basis of tongue images in Traditional Chinese Medicine (TCM) is of great value, indicating the feasibility of digitalized tongue diagnosis.

QSAR Study of PARP Inhibitors by GA-MLR, GA-SVM and GA-ANN Approaches

2020 ◽  
Vol 16 (8) ◽  
pp. 1088-1105
Author(s):  
Nafiseh Vahedi ◽  
Majid Mohammadhosseini ◽  
Mehdi Nekoei
Keyword(s):  
Present Report ◽  
Principal Component ◽  
Parp Inhibitors ◽  
Support Vector ◽  
Ann Model ◽  
Statistical Parameters ◽  
Qsar Study ◽  
Data Set ◽  
Test Set ◽  
Non Linear

Background: The poly(ADP-ribose) polymerases (PARP) is a nuclear enzyme superfamily present in eukaryotes. Methods: In the present report, some efficient linear and non-linear methods including multiple linear regression (MLR), support vector machine (SVM) and artificial neural networks (ANN) were successfully used to develop and establish quantitative structure-activity relationship (QSAR) models capable of predicting pEC50 values of tetrahydropyridopyridazinone derivatives as effective PARP inhibitors. Principal component analysis (PCA) was used to a rational division of the whole data set and selection of the training and test sets. A genetic algorithm (GA) variable selection method was employed to select the optimal subset of descriptors that have the most significant contributions to the overall inhibitory activity from the large pool of calculated descriptors. Results: The accuracy and predictability of the proposed models were further confirmed using crossvalidation, validation through an external test set and Y-randomization (chance correlations) approaches. Moreover, an exhaustive statistical comparison was performed on the outputs of the proposed models. The results revealed that non-linear modeling approaches, including SVM and ANN could provide much more prediction capabilities. Conclusion: Among the constructed models and in terms of root mean square error of predictions (RMSEP), cross-validation coefficients (Q2 LOO and Q2 LGO), as well as R2 and F-statistical value for the training set, the predictive power of the GA-SVM approach was better. However, compared with MLR and SVM, the statistical parameters for the test set were more proper using the GA-ANN model.

Application of Machine Learning in Animal Disease Analysis and Prediction

2020 ◽  
Vol 15 ◽  
Author(s):  
Shuwen Zhang ◽  
Qiang Su ◽  
Qin Chen
Keyword(s):  
Machine Learning ◽  
Unsupervised Learning ◽  
Supervised Learning ◽  
Clustering Algorithm ◽  
Principal Component ◽  
Support Vector ◽  
Animal Disease ◽  
Human Beings ◽  
Animal Diseases ◽  
Disease Analysis

Abstract: Major animal diseases pose a great threat to animal husbandry and human beings. With the deepening of globalization and the abundance of data resources, the prediction and analysis of animal diseases by using big data are becoming more and more important. The focus of machine learning is to make computers learn how to learn from data and use the learned experience to analyze and predict. Firstly, this paper introduces the animal epidemic situation and machine learning. Then it briefly introduces the application of machine learning in animal disease analysis and prediction. Machine learning is mainly divided into supervised learning and unsupervised learning. Supervised learning includes support vector machines, naive bayes, decision trees, random forests, logistic regression, artificial neural networks, deep learning, and AdaBoost. Unsupervised learning has maximum expectation algorithm, principal component analysis hierarchical clustering algorithm and maxent. Through the discussion of this paper, people have a clearer concept of machine learning and understand its application prospect in animal diseases.

scholarly journals Possibility of Human Gender Recognition Using Raman Spectra of Teeth

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3983
Author(s):  
Ozren Gamulin ◽  
Marko Škrabić ◽  
Kristina Serec ◽  
Matej Par ◽  
Marija Baković ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Principal Component ◽  
Support Vector ◽  
Gender Recognition ◽  
Proof Of Concept ◽  
Male And Female ◽  
Tooth Type ◽  
Tooth Apex ◽  
The Difference

Gender determination of the human remains can be very challenging, especially in the case of incomplete ones. Herein, we report a proof-of-concept experiment where the possibility of gender recognition using Raman spectroscopy of teeth is investigated. Raman spectra were recorded from male and female molars and premolars on two distinct sites, tooth apex and anatomical neck. Recorded spectra were sorted into suitable datasets and initially analyzed with principal component analysis, which showed a distinction between spectra of male and female teeth. Then, reduced datasets with scores of the first 20 principal components were formed and two classification algorithms, support vector machine and artificial neural networks, were applied to form classification models for gender recognition. The obtained results showed that gender recognition with Raman spectra of teeth is possible but strongly depends both on the tooth type and spectrum recording site. The difference in classification accuracy between different tooth types and recording sites are discussed in terms of the molecular structure difference caused by the influence of masticatory loading or gender-dependent life events.

scholarly journals Oestrus Analysis of Sows Based on Bionic Boars and Machine Vision Technology

Animals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1485
Author(s):  
Kaidong Lei ◽  
Chao Zong ◽  
Xiaodong Du ◽  
Guanghui Teng ◽  
Feiqi Feng
Keyword(s):  
Support Vector Machine ◽  
Machine Vision ◽  
Recognition Accuracy ◽  
Average Duration ◽  
Support Vector ◽  
Contact Duration ◽  
Innovative Design ◽  
Sparse Autoencoder ◽  
Accuracy Rates ◽  
Interactive Behaviour

This study proposes a method and device for the intelligent mobile monitoring of oestrus on a sow farm, applied in the field of sow production. A bionic boar model that imitates the sounds, smells, and touch of real boars was built to detect the oestrus of sows after weaning. Machine vision technology was used to identify the interactive behaviour between empty sows and bionic boars and to establish deep belief network (DBN), sparse autoencoder (SAE), and support vector machine (SVM) models, and the resulting recognition accuracy rates were 96.12%, 98.25%, and 90.00%, respectively. The interaction times and frequencies between the sow and the bionic boar and the static behaviours of both ears during heat were further analysed. The results show that there is a strong correlation between the duration of contact between the oestrus sow and the bionic boar and the static behaviours of both ears. The average contact duration between the sows in oestrus and the bionic boars was 29.7 s/3 min, and the average duration in which the ears of the oestrus sows remained static was 41.3 s/3 min. The interactions between the sow and the bionic boar were used as the basis for judging the sow’s oestrus states. In contrast with the methods of other studies, the proposed innovative design for recyclable bionic boars can be used to check emotions, and machine vision technology can be used to quickly identify oestrus behaviours. This approach can more accurately obtain the oestrus duration of a sow and provide a scientific reference for a sow’s conception time.

scholarly journals A Methodology Based on FT-IR Data Combined with Random Forest Model to Generate Spectralprints for the Characterization of High-Quality Vinegars

Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1411
Author(s):  
José Luis P. Calle ◽  
Marta Ferreiro-González ◽  
Ana Ruiz-Rodríguez ◽  
Gerardo F. Barbero ◽  
José Á. Álvarez ◽  
...  
Keyword(s):  
Random Forest ◽  
Raw Materials ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Raw Material ◽  
Support Vector ◽  
Protected Designation Of Origin ◽  
Ft Ir

Sherry wine vinegar is a Spanish gourmet product under Protected Designation of Origin (PDO). Before a vinegar can be labeled as Sherry vinegar, the product must meet certain requirements as established by its PDO, which, in this case, means that it has been produced following the traditional solera and criadera ageing system. The quality of the vinegar is determined by many factors such as the raw material, the acetification process or the aging system. For this reason, mainly producers, but also consumers, would benefit from the employment of effective analytical tools that allow precisely determining the origin and quality of vinegar. In the present study, a total of 48 Sherry vinegar samples manufactured from three different starting wines (Palomino Fino, Moscatel, and Pedro Ximénez wine) were analyzed by Fourier-transform infrared (FT-IR) spectroscopy. The spectroscopic data were combined with unsupervised exploratory techniques such as hierarchical cluster analysis (HCA) and principal component analysis (PCA), as well as other nonparametric supervised techniques, namely, support vector machine (SVM) and random forest (RF), for the characterization of the samples. The HCA and PCA results present a clear grouping trend of the vinegar samples according to their raw materials. SVM in combination with leave-one-out cross-validation (LOOCV) successfully classified 100% of the samples, according to the type of wine used for their production. The RF method allowed selecting the most important variables to develop the characteristic fingerprint (“spectralprint”) of the vinegar samples according to their starting wine. Furthermore, the RF model reached 100% accuracy for both LOOCV and out-of-bag (OOB) sets.

scholarly journals Identification of Pilots’ Fatigue Status Based on Electrocardiogram Signals

Sensors ◽  
2021 ◽  
Vol 21 (9) ◽  
pp. 3003
Author(s):  
Ting Pan ◽  
Haibo Wang ◽  
Haiqing Si ◽  
Yao Li ◽  
Lei Shang
Keyword(s):  
Back Propagation ◽  
Principal Component ◽  
Back Propagation Neural Network ◽  
Practical Significance ◽  
Support Vector ◽  
State Identification ◽  
Feature Parameter ◽  
The Time Domain ◽  
Pilot Fatigue ◽  
Identification Model

Fatigue is an important factor affecting modern flight safety. It can easily lead to a decline in pilots’ operational ability, misjudgments, and flight illusions. Moreover, it can even trigger serious flight accidents. In this paper, a wearable wireless physiological device was used to obtain pilots’ electrocardiogram (ECG) data in a simulated flight experiment, and 1440 effective samples were determined. The Friedman test was adopted to select the characteristic indexes that reflect the fatigue state of the pilot from the time domain, frequency domain, and non-linear characteristics of the effective samples. Furthermore, the variation rules of the characteristic indexes were analyzed. Principal component analysis (PCA) was utilized to extract the features of the selected feature indexes, and the feature parameter set representing the fatigue state of the pilot was established. For the study on pilots’ fatigue state identification, the feature parameter set was used as the input of the learning vector quantization (LVQ) algorithm to train the pilots’ fatigue state identification model. Results show that the recognition accuracy of the LVQ model reached 81.94%, which is 12.84% and 9.02% higher than that of traditional back propagation neural network (BPNN) and support vector machine (SVM) model, respectively. The identification model based on the LVQ established in this paper is suitable for identifying pilots’ fatigue states. This is of great practical significance to reduce flight accidents caused by pilot fatigue, thus providing a theoretical foundation for pilot fatigue risk management and the development of intelligent aircraft autopilot systems.

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