scholarly journals Barium Sulfate Scale Removal at Low-Temperature

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Hany Gamal ◽  
Saad Al-Afnan ◽  
Salaheldin Elkatatny ◽  
Mohamed Bahgat

Precipitation of the scale in the oil and gas reservoirs, surface and subsurface equipment, and processing and production facilities is a big problem as it affects petroleum production. The scale precipitations decrease the oil and gas production and cause economical loss. Solving this issue requires an engineering investigation to provide a safe, efficient, and economic solution. Consequently, this study proposed a developed dissolver for barium sulfate scales, where two field-scale samples were collected from different locations. The compositional analysis for scale samples showed that sample 1 is 100% barium sulfate where sample 2 has 97.75% barium sulfate and 2.25% of quartz. The composition of the developed dissolver has diethylenetriamine pentaacetic acid (DTPA) as a chelating agent, oxalic acid, and tannic acids as an activator, nonionic surfactant, and water as the base fluid. The new dissolver was investigated with extensive lab tests to determine the dissolution efficiency, precipitation tendency for the dissolved scale solids, corrosion rate, and fluid-rock interaction. The obtained successful results indicated that the developed dissolver had a dissolution efficiency for two real barium scale samples as the results showed 76.9 and 71.2% at 35°C and 91.3 and 78.4% at 90°C for samples 1 and 2, respectively. The new solution has a great performance compared with common scale dissolvers in the oil field as hydrochloric acid, ethylenediaminetetraacetic acid, and diethylenetriamine pentaacetic acid. The developed dissolver showed a very low precipitation tendency for the scale dissolved solids (1.9 and 3.2% for samples 1 and 2, respectively) under 35°C for 24 hours. Without any additives of corrosion inhibitors, the corrosion rate was 0.001835 g/cm2 at 6.9 MPa and 100°C for 6 hours. Injecting the developed dissolver for damaged sandstone core sample with barite mud by flooding test showed a return permeability of 115%.

2020 ◽  
Vol 12 (6) ◽  
pp. 2455
Author(s):  
Hany Gamal ◽  
Salaheldin Elkatatny ◽  
Dhafer Al Shehri ◽  
Mohamed Bahgat

The oil and gas production operations suffer from scale depositions. The scale precipitations have a damaging impact on the reservoir pores, perforations, downhole and completion equipment, pipeline network, wellhead chokes, and surface facilities. Hydrocarbon production possibly decreased because of the scale accumulation in the well tubular, leading to a well plugging, this requires wells to be shut-in in severe cases to perform a clean-out job. Therefore, scale deposition is badly affecting petroleum economics. This research aims to design a scale dissolver with low cost, non-damaging for the well equipment and has a high performance at the field operating conditions. This paper presents a novel non-corrosive dissolver for sulfate and sulfide composite scale in alkaline pH and works at low-temperature conditions. The scale samples were collected from a production platform from different locations. A complete description of the scale samples was performed as X-ray diffraction (XRD) and X-ray fluorescence (XRF). The new scale dissolver was prepared in different concentrations to examine its dissolution efficiency for the scale with time at low temperatures. The experimental design studied the solid to fluid ratio, temperature, solubility time, and dissolution efficiency in order to achieve the optimum and most economic performance of solubility in terms of high dissolution efficiency with the smallest possible amount of scale dissolver. A solubility comparison was performed with other commercial-scale-dissolvers and the corrosion rate was tested. The experimental work results demonstrated the superior performance of the new scale dissolver. The new scale dissolver showed a solubility efficiency of 91.8% at a low temperature of 45 °C and 79% at 35 °C. The new scale dissolver showed a higher solubility ratio for the scale sample than the ethylenediaminetetraacetic acid (EDTA) (20 wt. %), diethylenetriamine pentaacetic acid (DTPA) (20 wt. %), and HCl (10 wt. %). The corrosion rate for the new non-corrosive dissolver was 0.01357 kg/m2 (0.00278 lb./ft²) which was considered a very low rate and non-damaging for the equipment. The low corrosive effect of the new dissolver will save the extra cost of adding the corrosion inhibitors and save the equipment from the damaging effect of the corrosive acids.


2020 ◽  
Vol 58 (3) ◽  
pp. 397-424
Author(s):  
Jesse Salah Ovadia ◽  
Jasper Abembia Ayelazuno ◽  
James Van Alstine

ABSTRACTWith much fanfare, Ghana's Jubilee Oil Field was discovered in 2007 and began producing oil in 2010. In the six coastal districts nearest the offshore fields, expectations of oil-backed development have been raised. However, there is growing concern over what locals perceive to be negative impacts of oil and gas production. Based on field research conducted in 2010 and 2015 in the same communities in each district, this paper presents a longitudinal study of the impacts (real and perceived) of oil and gas production in Ghana. With few identifiable benefits beyond corporate social responsibility projects often disconnected from local development priorities, communities are growing angrier at their loss of livelihoods, increased social ills and dispossession from land and ocean. Assuming that others must be benefiting from the petroleum resources being extracted near their communities, there is growing frustration. High expectations, real and perceived grievances, and increasing social fragmentation threaten to lead to conflict and underdevelopment.


The formation/deposition of hydrate and scale in gas production and transportation pipeline has continue to be a major challenge in the oil and gas industry. Pipeline transport is one of the most efficient, reliable and safer means of transporting petroleum products from the well sites to either the refineries or to the final destinations. Acetic acid (HAc), is formed in the formation water which also present in oil and gas production and transportation processes. Acetic acid aids corrosion in pipelines and in turn aids the formation and deposition of scales which may eventually choke off flow. Most times, Monethylene Glycol (MEG) is added into the pipeline as an antifreeze and anticorrosion agent. Some laboratory experiments have shown that the MEG needs to be separated from unwanted substance such as HAc that are present in the formation water to avoid critical conditions in the pipeline. Internal pipeline corrosion slows and decreases the production of oil and gas when associated with free water and reacts with CO2 and organic acid by lowering the integrity of the pipe. In this study, the effect of Mono-Ethylene Glycol (MEG) and Acetic acid (HAc) on the corrosion rate of X-80 grade carbon steel in CO2 saturated brine were evaluated at 25oC and 80oC using 3.5% NaCl solution in a semi-circulation flow loop set up. Weight loss and electrochemical measurements using the linear polarization resistance (LPR) and electrochemical impedance spectroscope (EIS) were used in measuring the corrosion rate as a function of HAc and MEG concentrations. The results obtained so far shows an average corrosion rate increases from 0.5 to 1.8 mm/yr at 25oC, and from 1.2 to 3.5 mm/yr at 80oC in the presence of HAc. However, there are decrease in corrosion rate from 1.8 to 0.95 mm/yr and from 3.5 to 1.6mm/yr respectively at 25oC and 80oC on addition of 20% and 80% MEG concentrations to the solution. It is also noted that the charge transfer with the electrochemical measurements (EIS) results is the main corrosion controlling mechanism under the test conditions. The higher temperature led to faster film dissolution and higher corrosion rate in the presence of HAc. The EIS results also indicate that the charge transfer controlled behaviour was as a result of iron carbonate layer accelerated by the addition of different concentrations of MEG to the system. Key words: CO2 corrosion, Carbon steel, MEG, HAc, Inhibition, Environment.


2012 ◽  
Author(s):  
Amer Badr Merdhah ◽  
Abu Azam Mohd Yassin

Kerak pemendapan merupakan satu daripada masalah paling penting dan serius dalam sistem suntikan air. Kerak kadangkala mengehadkan atau menghalang penghasilan gas dan minyak melalui penyumbatan matrik atau perpecahan pembentukan minyak dan jeda yang berlubang. Makalah ini mengetengahkan kesimpulan pengukuran makmal bagi kerak terbentuk di dalam keterlarutan medan minyak biasa dalam sintetik air masin (pembentukan air dan air laut) bagi pembentukan air yang mengandungi barium dan kandungan garam yang tinggi pada suhu 40 hingga 90°C pada tekanan atmosfera. Keputusan uji kaji mengesahkan pola kebergantungan keterlarutan bagi kerak medan minyak biasa pada keadaan ini. Pada suhu yang lebih tinggi, kerak bagi CaCO3, CaSO4, dan SrSO4 meningkat manakala kerak BaSO4 menurun disebabkan oleh keterlarutan CaCO3, CaSO4, dan SrSO4 menurun dan keterlarutan BaSO4 meningkat dengan kenaikan suhu. Kata kunci: Masalah pengskalaan; skala keterlarutan; paras kandungan garam tinggi; logam barium tinggi Scale deposition is one of the most important and serious problems which water injection systems are generally engaged in. Scale sometimes limits or blocks oil and gas production by plugging the oil–producing formation matrix or fractures and the perforated intervals. This paper presents a summary of the laboratory measurements of the solubility of common oil field scales in synthetic brines (formation water and sea water) of high–barium and high–salinity formation waters at 40 to 90°C and atmospheric pressure. The experimental results confirm the general trend in solubility dependencies for common oil field scales at these conditions. At higher temperatures the deposition of CaCO3, CaSO4 and SrSO4 scale increases and the deposition of BaSO4 scale decreases since the solubilities of CaCO3, CaSO4 and SrSO4 scales decreases and the solubility of BaSO4 increases with increasing temperature. Key words: Scaling problems; solubility of scale; high salinity; high barium


2012 ◽  
Vol 155-156 ◽  
pp. 722-725
Author(s):  
Wen Bin Cai ◽  
Guo Wei Qin ◽  
Yan He

In the oil and gas production process, serious sand production causes reservoir and pipe blocked, which makes productivity declined, even stopped. It's the efficient means of sand washing and plug removal by using high-pressure foam fluid jet. The structure and performance of sand washing device determines the efficiency of sand washing and plug removal. The device's nozzle consists of anti-blocking valves, three kinds of nozzles with self-drive, rotation characteristics during the operation. The nozzles include sand washing nozzle, couple nozzle and power nozzle. This device can be used in horizontal wells with complex well bore situation to carry out sand and plug removal. The device has a good effect on sand washing and plug removal in the oil field.


2012 ◽  
Vol 241-244 ◽  
pp. 1396-1399
Author(s):  
Gui Min Nie ◽  
Dan Guo ◽  
Yan Wang ◽  
Xiao Wei Cheng

With the depletion of shallow-layer oil and gas pools inLiaohe oilfield, buried hill stratigraphic reservoirs in Liaohe oil field are becoming main objectives for exploration in recent years, especially in high-risk areas of Xinglongtai deep the Hing ancient buried hill resources are particularly rich. Since 2007, Liaohe oilfield increased investment for Buried Hill reservoirs with deep horizontal drilling developt the buried hill reservoir. Liaohe has completed 36 deep horizontal, with a total footage of 183920m, the average depth of 5109m. Improving drilling speed of "buried hill deep horizontal and branch horizontal wells”, and reducing drilling costs are of great urgency. “Hing buried hill deep horizontal, horizontal wells,” with composite drilling technology, supporting the optimization of PDC bits, the high-pressure jet drilling, the MWD borehole trajectory control and optimization of drilling parameters, the new drilling fluid technology and so on. With a large number of horizontal wells put into Buried Hill stratigraphic reservoirs, oil and gas production of average deep horizontal well increase of 2-5 times. Besides, the previous recovery and production of oil and gas reservoirs significantly improved to create an objective economic and social benefits.


Author(s):  
Yaroslav Adamenko ◽  
◽  
Mirela Coman ◽  
Oleh Adamenko ◽  

Environmentally safe oil and gas production demands permanent control for the development of ecological situation which should be managed on the basis of existing nature protection requirements and corresponding instruction documents. Purpose of the research and formulation of the problem is to select landscape complexes at the hierarchical levels of locations and facies in the Bykiv oil and gas field to make landscape map with morphological genetic and age features of landscape structure as the basis of environmental assessment of oil and gas field impact on the natural geosystems. Presentation of the main research material with full justification of the received scientific results. Landscape analysis of the investigated area allowed to select, ground and make mapping the following landscape complexes: landscape localities, foothill landscape complexes. Characteristic feature of the Bytkiv oil and gas field and neighborhoods is their high-altitude stratification from middle and lowmountainous to foothills and lowlands. The genesis or origin of the area under study is various - from denudation relics of the top peneplenization surface of leveling much younger pedyplenization surface pediments on the transition from mountainous to foothill relief, to deeply portioned erosionally active steep slopes and stairstepping of the river terraces. Age boundaries of the created landscape structures were determined on the availability of adjoint sedimentary formations from the producents of bedrock destruction, resedimented eolivan, deluvial, proluvial and alluvial processes.


Author(s):  
Mi-feng Zhao ◽  
Juantao Zhang ◽  
Fangting Hu ◽  
Anqing Fu ◽  
Kelin Wang ◽  
...  

Abstract Acid fracturing is an effective technology for increasing oil and gas production. However, acid will cause serious corrosion to the tubing. In this paper, the inhibition performance of TG202 inhibitor for acidizing of high temperature and high pressure gas wells on N80 carbon steel and 13Cr martensitic stainless steel tubing in 15% hydrochloric acid was studied by electrochemical noise technology. The results showed that with the increase of TG202 inhibitor content, the noise resistance increased and the corrosion rate of tubing steel decreased. Under the same condition, the order of corrosion rate of tubing steels: 13Cr > HP-13Cr > N80 > P110. The pitting corrosion of HP-13Cr and 13Cr is significant. The research showed that TG202 inhibitor had a protective effect on tubing during acidizing. The inhibition mechanism of TG202 inhibitor was discussed.


2021 ◽  
Vol 73 (10) ◽  
pp. 17-22
Author(s):  
Pat Davis Szymczak

It wasn’t too long ago that Arctic oil and gas exploration enjoyed celebrity status as the industry’s last frontier, chock full of gigantic unexplored hydrocarbon deposits just waiting to be developed. Fast forward and less than a decade later, the same climate change that made Arctic oil and gas more accessible has caused an about-face as governments and the world’s supranational energy companies rebrand and target control of greenhouse gases (GHG) to achieve carbon neutrality by 2050. Among countries with Arctic coastlines, Canada has focused its hydrocarbon production on its oil sands which sit well below the Arctic Circle; Greenland has decided to not issue any new offshore exploration licenses (https://jpt.spe.org/greenland-says-no-to-oil-but-yes-to-mining-metals-for-evs), and while Norway is offering licenses in its “High North,” the country can’t find many takers. The Norwegian Petroleum Directorate (NPD) reported that while 26 companies applied for licenses in 2013, this year’s bid round attracted only seven participants. Norway is Europe’s largest oil producer after Russia with half of its recoverable resources still undeveloped and most of that found in the Barents Sea where the NPD says only one oil field and one gas field are producing. That leaves Russia and the US—geopolitical rivals which are each blessed with large Arctic reserves and the infrastructure to develop those riches—but whose oil and gas industries play different roles in each nation’s economy and domestic political intrigues. Russia sees its Arctic reserves, particularly gas reserves, as vital to its national security, considering that oil and gas accounts for 60% of Russian exports and from 15 to 20% of the country’s gross domestic product (GDP), according to Russia’s Skolkovo Energy Centre. With navigation now possible year­round along the Northern Sea Route, Russia’s LNG champion and its largest independent gas producer, Novatek, is moving forward with exploration to expand its resource base and build infrastructure to ship product east to Asia and west to Europe. https://jpt.spe.org/russian­lng­aims­high­leveraging­big­reserves­and­logistical­advantages As a result, Russia’s state­owned majors—Rosneft, Gazprom, and Gazprom Neft—are lining up behind their IOC colleague as new investment in Arctic exploration and development is encouraged and rewarded by the Kremlin. In contrast, the American Petroleum Institute reports that the US oil and gas industry contributes 8% to US GDP, a statistic that enables the US to have a more diverse discussion than Russia about the role that oil and gas may play in any future energy mix. That is unless you happen to be from the state of Alaska where US Arctic oil and gas is synonymous with Alaskan oil and gas, and where the US Geological Survey estimates 27% of global unex­plored oil reserves may lie. Though Alaska is responsible for only 4% of US oil and gas production, those revenues covered two-thirds of Alaska’s state budget in 2020 despite the state’s decline in crude production in 28 of the past 32 years since it peaked at 2 million B/D in 1988, according to the US Energy Information Administration (EIA).


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