scholarly journals Slope Belts of Paleouplifts Control the Pore Structure of Organic Matter of Marine Shale: A Comparative Study of Lower Cambrian Rocks in the Sichuan Basin

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-18
Author(s):  
Pengfei Wang ◽  
Chen Zhang ◽  
Aorao Liu ◽  
Pengfei Zhang ◽  
Yibo Qiu ◽  
...  

Extensive exploration of the marine shale of the Niutitang Formation in south China has been conducted. However, exploration and development results have varied considerably in different areas. For example, the Niutitang shale in Jingyan City (Southwestern Sichuan Basin) produces a large amount of gas with a long period of stable production. In contrast, most development wells in the Niutitang shale in Chongqing City do not produce gas. Scanning electron microscopy images showed that the organic matter (OM) pore development in the Niutitang shale in Jingyan is abundant, large in size, and are well connected. In contrast, OM pores in the Niutitang shale in Chongqing are rarely observed. OM pore development of the Jingyan and Chongqing shales is mainly controlled by thermal maturity as shown by equivalent vitrine reflectance determinations. The moderate thermal maturity has resulted in the development of a large number of OM pores in the Niutitang shale in Jingyan, whereas the high thermal maturity of the Niutitang shale in Chongqing has led to the destruction of most of the OM pores. Due to the existence of ancient uplift, the shale was buried shallowly in the process of hydrocarbon generation evolution, and the shale avoided excessive thermal evolution and retained appropriate thermal maturity. In the Jingyan area, due to its location near the central uplift in the Sichuan Basin, the Niutitang shale deposited nearby avoided excessive evolution, and a large number of OM pores were retained in the reservoir.

2020 ◽  
Vol 12 (1) ◽  
pp. 1617-1629
Author(s):  
Kun Zhang ◽  
Jun Peng ◽  
Xin Wang ◽  
Zhenxue Jiang ◽  
Yan Song ◽  
...  

AbstractThe marine shale in southern China has undergone complex tectonic evolution with a high thermal evolution degree. Excessive thermal evolution brings certain risks to shale gas exploration and development. With the advancement of experimental methods, the evolution process of shale reservoirs can be better understood from the micro-nanoscale. This work takes the Ordovician-Silurian Wufeng and the first member of Longmaxi Formation in the Sichuan Basin and Lower Cambrian Niutitang Formation in Outer Margin of the Sichuan Basin to study the impact of maturity upon the genesis of shale gas and development features of the reservoir. A series of geochemical research methods, including TOC, gas component and gas isotope, were adopted to study the impact of different thermal evolution stages of organic matter upon the genesis of shale gas. The nanoscale micro-imaging technique, such as FIB-SEM and FIB-HIM, was used to analyze the development of OM-hosted pores. As shown from the results, when Ro = 1.2–3.5%, the marine shale gas is dominated by methane and other hydrocarbon gases, since the mixture of cracking gas from liquid hydrocarbons and kerogen-cracking gas cause the carbon isotope reversal. Besides, the pyrobitumen pores characterized by the strong connectivity and storage capacity were primarily developed. When Ro > 3.5%, the organic matter is at the graphitization stage. The shale gas is mainly composed of nitrogen at this stage. The nitrogen is originated from the atmosphere and the thermal evolution process, and the OM-hosted pores (pyrobitumen and kerogen pores) characterized by the bad connectivity and storage capacity are developed. Finally, the main component of shale gas, the genesis of shale gas and the pattern of OM-hosted pores under different thermal evolution stages of organic matter are summarized, which provide technical support for the exploration and development of shale gas.


2021 ◽  
pp. SP514-2021-2
Author(s):  
Weimu Xu ◽  
Johan W. H. Weijers ◽  
Micha Ruhl ◽  
Erdem F. Idiz ◽  
Hugh C. Jenkyns ◽  
...  

AbstractThe organic-rich upper Lower Jurassic Da'anzhai Member (Ziliujing Formation) of the Sichuan Basin, China is the first stratigraphically well-constrained lacustrine succession associated with the Toarcian Oceanic Anoxic Event (T-OAE; ∼183 Ma). The formation and/or expansion of the Sichuan mega-lake, likely one of the most extensive fresh-water systems to have existed on the planet, is marked by large-scale lacustrine organic productivity and carbon burial during the T-OAE, possibly due to intensified hydrological cycling and nutrient supply. New molecular biomarker and organic petrographical analyses, combined with bulk organic and inorganic geochemical and palynological data, are presented here, providing insight into aquatic productivity, land-plant biodiversity, and terrestrial ecosystem evolution in continental interiors during the T-OAE. We show that lacustrine algal growth during the T-OAE accounted for a significant organic-matter flux to the lakebed in the palaeo-Sichuan mega-lake. Lacustrine water-column stratification during the T-OAE facilitated the formation of dysoxic-anoxic conditions at the lake bottom, favouring organic-matter preservation and carbon sequestration into organic-rich black shales in the Sichuan Basin. We attribute the palaeo-Sichuan mega-lake expansion to enhanced hydrological cycling in a more vigorous monsoonal climate in the hinterland during the T-OAE greenhouse.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5433544


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