scholarly journals Fabrication and Response Surface Methodology for the Adsorption of Nickel Ferrite-Graphene Oxide Nanocomposite for the Removal of Methylene Blue from Water

2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Lu Thi Mong Thy ◽  
Nguyen Thi Chi Linh ◽  
Nguyen Thi Tuyet Tram ◽  
Tran Hoang Tu ◽  
Le Tan Tai ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Response Surface Methodology ◽  
Graphene Oxide ◽  
Response Surface ◽  
Photoelectron Spectroscopy ◽  
Nickel Ferrite ◽  
Interactive Effects ◽  
Isotherm Models ◽  
Order Kinetic ◽  
X Ray

This study is aimed at studying the adsorption of methylene blue (MB) from aqueous solutions by nickel ferrite/graphene oxide (NGO) nanocomposite. The nanocomposite was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, energy dispersive X-ray, Brunauer-Emmett-Teller-specific surface area, and vibrating sample magnetometer analyses. The interactive effects of critical variables including pH, initial concentration, and contact time on the adsorption capacity of NGO for MB were studied using response surface methodology (RSM) according to composite central design. In RSM models, the predicted values agreed well with verification experiments, with a high correlation coefficient of 0.9887. The adsorption process followed the pseudo-second-order kinetic and Langmuir isotherm models. The maximum capacity for adsorption of MB onto NGO was found to be 476.19 mg/g. Based on these results, NGO has the potential as an efficient adsorbent for the removal of MB from water.

scholarly journals Efficient Removal of Levofloxacin by Activated Persulfate with Magnetic CuFe2O4/MMT-k10 Nanocomposite: Characterization, Response Surface Methodology, and Degradation Mechanism

Water ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3583
Author(s):  
Junying Yang ◽  
Minye Huang ◽  
Shengsen Wang ◽  
Xiaoyun Mao ◽  
Yueming Hu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Response Surface Methodology ◽  
Response Surface ◽  
Photoelectron Spectroscopy ◽  
Degradation Mechanism ◽  
Sol Gel ◽  
Combustion Method ◽  
Copper Ferrite ◽  
X Ray ◽  
Rsm Model

In this study, a magnetic copper ferrite/montmorillonite-k10 nanocomposite (CuFe2O4/MMT-k10) was successfully fabricated by a simple sol-gel combustion method and was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), the Brunner–Emmett–Teller (BET) method, vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS). For levofloxacin (LVF) degradation, CuFe2O4/MMT-k10 was utilized to activate persulfate (PS). Due to the relative high adsorption capacity of CuFe2O4/MMT-k10, the adsorption feature was considered an enhancement of LVF degradation. In addition, the response surface methodology (RSM) model was established with the parameters of pH, temperature, PS dosage, and CuFe2O4/MMT-k10 dosage as the independent variables to obtain the optimal response for LVF degradation. In cycle experiments, we identified the good stability and reusability of CuFe2O4/MMT-k10. We proposed a potential mechanism of CuFe2O4/MMT-k10 activating PS through free radical quenching tests and XPS analysis. These results reveal that CuFe2O4/MMT-k10 nanocomposite could activate the persulfate, which is an efficient technique for LVF degradation in water.

scholarly journals Highly Efficient Adsorption of Aqueous Pb(II) with Mesoporous Metal-Organic Framework-5: An Equilibrium and Kinetic Study

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
José María Rivera ◽  
Susana Rincón ◽  
Cherif Ben Youssef ◽  
Alejandro Zepeda
Keyword(s):  
Kinetic Study ◽  
Photoelectron Spectroscopy ◽  
Metal Organic Framework ◽  
Isotherm Models ◽  
Ionic Exchange ◽  
Order Kinetic ◽  
X Ray ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
Organic Framework

Mesoporous metal-organic framework-5 (MOF-5), with the composition Zn4O(BDC)3, showed a high capacity for the adsorptive removal of Pb(II) from 100% aqueous media. After the adsorption process, changes in both morphology and composition were detected using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) system, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analysis. The experimental evidence showed that Zn(II) liberation from MOF-5 structure was provoked by the water effect demonstrating that Pb(II) removal is not due to ionic exchange with Zn. A kinetic study showed that Pb(II) removal was carried out in 30 min with a behavior of pseudo-second-order kinetic model. The experimental data on Pb(II) adsorption were adequately fit by both the Langmuir and BET isotherm models with maximum adsorption capacities of 658.5 and 412.7 mg/g, respectively, at pH 5 and 45°C. The results of this work demonstrate that the use of MOF-5 has great potential for applications in environmental protection, especially regarding the removal of the lead present in industrial wastewaters and tap waters.

scholarly journals Removal of Chromium(VI) by Chitosan Beads Modified with Sodium Dodecyl Sulfate (SDS)

2020 ◽  
Vol 10 (14) ◽  
pp. 4745
Author(s):  
Xiaoyu Du ◽  
Chihiro Kishima ◽  
Haixin Zhang ◽  
Naoto Miyamoto ◽  
Naoki Kano
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Adsorption Capacity ◽  
Photoelectron Spectroscopy ◽  
Sodium Dodecyl ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Chitosan Beads ◽  
X Ray ◽  
Chromium Vi ◽  
Dodecyl Sulfate

In this study, chitosan beads modified with sodium dodecyl sulfate (SDS) were successfully synthesized and employed for the removal of chromium(VI) (Cr(VI)). The adsorption performance of the adsorbent (SDS-chitosan beads) was examined by batch experiments. The partition coefficient (PC) as well as the adsorption capacity were evaluated to assess the true performance of the adsorbent in this work. The adsorbent (SDS-chitosan beads) showed a maximum Cr(VI) adsorption capacity of 3.23 mg·g−1 and PC of 9.5 mg·g−1·mM−1 for Cr(VI). The prepared adsorbent was characterized by different techniques such as scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), X-ray photoelectron spectroscopy (XPS) and Fourier transform-infrared spectroscopy (FT-IR). We used inductively coupled plasma mass spectrometry (ICP-MS) for the determination of Cr(VI) in solution. The experimental data could be well-fitted by pseudo-second-order kinetic and Langmuir isotherm models. The thermodynamic studies indicated that the adsorption process was favorable under the higher temperature condition. The SDS-modified chitosan beads synthesized in this work represent a promising adsorbent for removing Cr(VI).

scholarly journals Isotherm and Kinetic Modeling of Strontium Adsorption on Graphene Oxide

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2780
Author(s):  
Abdulrahman Abu-Nada ◽  
Ahmed Abdala ◽  
Gordon McKay
Keyword(s):  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Functional Groups ◽  
Photoelectron Spectroscopy ◽  
Active Sites ◽  
Nitrogen Adsorption ◽  
Order Kinetic ◽  
X Ray ◽  
Oxygen Functional Groups ◽  
Bet Analysis

In this study, graphene oxide (GO) was synthesized using Hummers method. The synthesized GO was characterized using field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transformed infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Brunauer–Emmett–Teller (BET) nitrogen adsorption. The analyses confirmed the presence of oxygen functional groups (C=O and C-O-C) on the GO surface. These oxygen functional groups act as active sites in the adsorption Sr (II). The BET analysis revealed the surface area of GO of 232 m2/g with a pore volume of 0.40 cm3/g. The synthesized GO was used as an adsorbent for removing Sr (II) from aqueous solutions. The adsorption equilibrium and kinetic results were consistent with the Langmuir isotherm model and the pseudo-second-order kinetic model. A maximum strontium adsorption capacity of 131.4 mg/g was achieved. The results show that the GO has an excellent adsorption capability for removing Sr (II) from aqueous solutions and potential use in wastewater treatment applications.

scholarly journals Removal of Nickel Ions from Aqueous Solutions by 2-Hydroxyethyl Acrylate/Itaconic Acid Hydrogels Optimized with Response Surface Methodology

Gels ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 225
Author(s):  
Katarina Antić ◽  
Antonije Onjia ◽  
Dana Vasiljević-Radović ◽  
Zlate Veličković ◽  
Simonida Lj. Tomić
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Itaconic Acid ◽  
Water Solution ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Solution Ph ◽  
Nickel Ions ◽  
Adsorption Time ◽  
Before And After

The adsorption of Ni2+ ions from water solutions by using hydrogels based on 2-hydroxyethyl acrylate (HEA) and itaconic acid (IA) was studied. Hydrogel synthesis was optimized with response surface methodology (RSM). The hydrogel with the best adsorption capacity towards Ni2+ ions was chosen for further experiments. The hydrogel was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and atomic force microscopy (AFM) analysis before and after the adsorption of Ni2+ ions. Batch equilibrium experiments were conducted to investigate the influence of solution pH, hydrogel weight, ionic strength, adsorption time, temperature and initial concentration of nickel ions on the adsorption. Time-dependent adsorption fitted the best to the pseudo-second-order kinetic model. A thermodynamic study revealed that the adsorption was an exothermic and non-spontaneous process. Five isotherm models were studied, and the best fit was obtained with the Redlich–Peterson model. Consecutive adsorption/desorption studies indicated that the HEA/IA hydrogel can be efficiently used as a sorbent for the removal of Ni2+ ions from the water solution. This study develops a potential adsorbent for the effective removal of trace nickel ions.

scholarly journals Fabrication of Amino Functionalized Magnetic Expanded Graphite Nanohybrids for Application in Removal of Ag(I) from Aqueous Solution

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Ying-Xia Ma ◽  
Yong-Xin Ruan ◽  
Dan Xing ◽  
Xue-Yan Du ◽  
Pei-Qing La
Keyword(s):  
Experimental Data ◽  
Aqueous Solution ◽  
Photoelectron Spectroscopy ◽  
Expanded Graphite ◽  
Second Order ◽  
Isotherm Models ◽  
Order Kinetic ◽  
One Pot ◽  
X Ray ◽  
Pseudo Second Order

Ethylenediamine functionalized magnetic expanded graphite decorated with Fe3O4 nanoparticles (MEG-NH2) was fabricated by one-pot solvothermal method. The as-prepared MEG-NH2 nanohybrids were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and Zeta potential analyzer. The effects of Fe3O4 content in MEG-NH2 nanohybrids, pH, initial concentration, contact time, and dosage on adsorption properties of the MEG-NH2 nanohybrids for Ag(I) from aqueous solution were investigated by batch experiments. The pseudo-first-order and the pseudo-second-order kinetic models were utilized to study adsorption kinetics. The experimental data was also analyzed with Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherm models. The results show that Ag(I) was reduced to silver in the process of the adsorption by MEG-NH2 nanohybrids; the experimental data was better fitted to pseudo-second-order model and Langmuir isotherm model which revealed that the adsorption process was a chemical adsorption by the formation of silver on the surface of MEG-NH2 nanohybrids.

scholarly journals Graphene oxide edge grafting of polyaniline nanocomposite: an efficient adsorbent for methylene blue and methyl orange

2018 ◽  
Vol 77 (12) ◽  
pp. 2751-2760 ◽  
Author(s):  
Hefang Wang ◽  
Mengmeng Duan ◽  
Yong Guo ◽  
Cunyue Wang ◽  
Zetao Shi ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Graphene Oxide ◽  
Methyl Orange ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Chemical Oxidation ◽  
Significant Loss ◽  
X Ray ◽  
In Situ Chemical Oxidation ◽  
Pani Composite

Abstract Polyaniline (PANI) chains were grafted at the edge of graphene oxide (GO) sheets by in-situ chemical oxidation polymerization. The obtained GO-PANI composite was used for the adsorption of cationic methylene blue (MB) and anionic methyl orange (MO) dyes from aqueous solutions. The structure of the GO-PANI composite was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electronic micrograph (SEM), X-ray photoelectron spectroscopy (XPS) and zeta potentials. GO-PANI exhibited a high adsorption capacity for MB (962 mg/g) and MO (885 mg/g) compared with other reported absorbents, which was due to adsorption through strong π-π stacking and anion–cation interactions. The nanocomposite could be recycled five times without significant loss in removal abilities for MB (87.8%) and MO (75.0%), respectively. GO-PANI composite is a promising adsorbent for the adsorption of anionic and cationic dyes from aqueous solutions.

scholarly journals Modeling the removal of methylene blue dye using a graphene oxide/TiO2/SiO2 nanocomposite under sunlight irradiation by intelligent system

2021 ◽  
Vol 19 (1) ◽  
pp. 157-173
Author(s):  
Hanan Haj Ahmad ◽  
Waed Alahmad
Keyword(s):  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Kinetics ◽  
Photoelectron Spectroscopy ◽  
Intelligent System ◽  
Fractional Factorial ◽  
Blue Dye ◽  
Sunlight Irradiation ◽  
X Ray ◽  
Percentage Removal

Abstract In this study, a model to improve the degradability of methylene blue (MB) dye using graphene oxide/TiO2/SiO2 nanocomposite under sunlight irradiation is investigated. The effect of operative parameters comprising catalyst concentration, initial dye concentration, and pH on the photocatalytic batch during removal of MB is studied. Fractional factorial design (FFD) and response surface methodology (RSM) are used to design the experiment layout. Graphene oxide (GO)/TiO2/SiO2 nanoparticles are synthesized through sonication and sol–gel methodologies. In the experiments, three levels of catalyst varied in the percentage of TiO2 pointed as (I) TiO2:GO (100%), (II) TiO2:GO:SiO2 (50%), and (III) TiO2:GO:SiO2 (25%) are used. The irradiation interval was 7 h at solar radiation energy 6.35–5.00 kW h/m2/day. In the experiments, three levels of catalyst varied in the percentage of TiO2 pointed as (I) TiO2:GO (100%), (II) TiO2:GO:SiO2 (50%), and (III) TiO2:GO:SiO2 (25%) are used. The synthesized catalysts are characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscope, and X-ray photoelectron spectroscopy. ANOVA under 23 FFD is conducted to evaluate the effect of independent factors depending on the value of F as pH of solution, weight of catalyst, and concentration of MB. The adsorption kinetics, experimental design with FFD, and RSM are investigated in this study. The Surface Adsorption kinetics were statistically analyzed, the model that best described the results of each experiment was determined out of the two evaluated kinetics (pseudo-first order, pseudo-second order), for the three photocatalyst composites I, II, and III with the parameters; weight of the catalyst, pH, and initial MB concentration, also percentage degradation is evaluated. RSM results are consistent with the kinetic model; first, the pH is considered as the most significant parameter affecting the removal of the organic pollutant, and second, catalyst II gives the highest percentage removal efficiency of MB. FFD results are consistent with both models where the effect of the independent factor depending on the value of F was pH of solution > weight of catalyst > initial concentration of MB. The percentage removal was in the range from 30 to 99%.

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