scholarly journals Expired Chicken Egg-White Extract’s Adsorption Behavior As a Corrosion Inhibitor for Carbon Steel in 1M HCl

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Esseddik Elqars ◽  
Mohamed Guennoun ◽  
Aicha Ouarhach ◽  
Noufissa Sqalli Houssini ◽  
Mohammed Elhafdi ◽  
...  

The inhibitory activity of the expired egg-white carbon steel (CS) extract in HCl solution was studied in this article. The extract was examined using FT-IR, and the surface was examined using a scanning electron microscope (SEM) and energy-dispersive X-ray analysis (EDX). Weight loss techniques at various temperatures were used to examine corrosion investigations (298, 308, 318, and 328 K), concentrations (100, 200, 400, and 800 mg. L−1) of extracts, and electrochemical measurements (potentiodynamic polarization (PDP) and impedance spectroscopy (EIS) at 25°C and different concentrations. Results. Results obtained through EIS demonstrated a maximal inhibition efficiency of 90% at an inhibitor concentration of 800 mg. L−1. Moreover, the findings of the potentiodynamic polarization indicated that egg-white extract was a mixed type of inhibitor and slowed down both cathodic and anodic reactions. For weight loss analysis, an inhibitory potency (89, 83, 77, and 71%) at various temperatures (298, 308, 318, and 328 K) was demonstrated, respectively. It indicates that the temperature rise contributes to a decrease in the resistance of the carbon steel. The adsorption of the expired egg-white extract was spontaneous with physisorption and chemisorption according to the Langmuir isotherm model, according to adsorption isotherm studies.

2021 ◽  
Author(s):  
P. R. Prabhu ◽  
Pavan Hiremath ◽  
Deepa Prabhu ◽  
M. C. Gowrishankar ◽  
B. M. Gurumurthy

AbstractThis paper presents the corrosion and inhibition behavior of heat-treated EN8 dual-phase steel with ferrite-martensite structure with pectin in 0.5 M sulphuric acid. The corrosion studies were performed using the weight loss method, electrochemical techniques such as potentiodynamic polarization measurements, and impedance spectroscopy. The study was done at different concentrations of pectin in the temperature range of 40 to 70 °C and immersion time of 1, 3, 5, and 7 h. The results showed that the inhibition performance of pectin has enhanced with an increase in pectin concentration and decreased with the temperature and time of exposure. From the weight loss study, highest inhibition efficiency of 76.43% was achieved at 5.0 g/L at 1 h of exposure at 40 °C. The maximum inhibition efficiency of 62% was obtained with 5.0 g/L of pectin at 40 °C by potentiodynamic polarization method. The energy, enthalpy, and entropy of activation and also thermodynamic parameters like free energy, enthalpy, and entropy of adsorption were assessed and discussed. Appropriate adsorption isotherm was fit to the obtained experimental outcomes and achieved Langmuir adsorption isotherm to be the best fit and obeyed physical adsorption. Surface analysis: scanning electron microscopy, X-ray diffraction techniques, atomic force microscopy, and energy dispersive X-ray were done with and without the addition of pectin. The metal surface appears to be uniform and smooth in the presence of pectin and adsorption was confirmed by surface analysis.


2018 ◽  
Vol 34 (5) ◽  
pp. 2471-2476 ◽  
Author(s):  
Hamida Edan Salman ◽  
Asim A. Balakit ◽  
Ali Ahmed Abdulridha

A new aromatic Schiff base with azo linkage (AS) has been synthesized and characterized by FT-IR, 1H NMR and 13C NMR spectroscopic techniques. The new compound (AS) has been evaluated as carbon steel corrosion inhibitor at different concentrations (0.005, 0.01, 0.02, 0.04 and 0.08 mM) and different temperatures (303 – 333 K). The corrosion inhibition efficiency was studied by potentiodynamic polarization and weight loss measurements. The effects of concentration and temperature on the inhibition efficiency were studied by potentiodynamic polarization studies, the results showed that increasing concentration of AS increases the inhibition efficiency while increasing the temperature decreases it, the highest corrosion inhibition efficiency, 93.9% was recorded with 0.08 mM of AS at 313 K in 1 M H2SO4. Weight loss measurements showed that the inhibition efficiency reached 97.1% in the presence of AS (0.08 mM) at 313 K. The adsorption process was found to obey Langmuir isotherm, and the adsorption thermodynamic parameters were studied. Scanning electron microscope (SEM) was used to confirm the results.


2014 ◽  
Vol 886 ◽  
pp. 12-15
Author(s):  
Bin Huang ◽  
Kang Quan Qiao ◽  
Yi Shun Cui

The influence of sodium hexametaPhosphate on the corrosion of carbon steel in 0.5 mol•L-1 KCl solution at 25 °C was investigated using weight loss measurements, potentiodynamic polarization curves and Scan electron microscope (SEM). The obtained results show that sodium hexametaPhosphate is an excellent inhibitor and the inhibition efficiencies exceed 87 %. The polarization measurements reveal that sodium hexametaPhosphate is an inhibitor mainly controlled by anodic process.


Author(s):  
A. H. EL-ASKALANY ◽  
S. I. MOSTAFA ◽  
A. M. EID

The inhibitive action of Saponinic extract of both Zygophylium album and Zygophylium Egyptian leaves which could serve as eco-friendly materials was investigated on the corrosion of N80 carbon steel in 1 M HCl solution. The techniques employed for the study were weight loss measurements. potentiodynamic polarization, electrochemical frequency modulation (EFM), and electrochemical impedance spectroscopy (EIS). The results obtained show that these extracts could serve as an effective inhibitor for N80 carbon steel. The percentage inhibition increases with increasing concentration of the inhibitor at 25 °C The percentage inhibitor efficiency above 90% was obtained at a concentration of 700 ppm for both extracts. The corrosion rates of steel and inhibitive efficiencies obtained from impedance and polarization measurements were in good agreement with those obtained from weight loss measurements. Potentiodynamic polarization studies clearly reveal that both extracts act as mixed-type inhibitors The study shows that the inhibition efficiency decreased with the temperature rise of the medium. Heat of adsorption and thermodynamic parameters and indicated that the adsorption process is mainly controlled by the physical adsorption process.


2014 ◽  
Vol 2014 ◽  
pp. 1-15 ◽  
Author(s):  
A. S. Fouda ◽  
A. A. Attia ◽  
A. A. Negm

Corrosion inhibitive performance of some thiophene derivatives during the acidic corrosion of carbon steel surface in 1 M HCl was investigated by chemical technique (weight loss) and electrochemical techniques (potentiodynamic polarization, electrochemical frequency modulation, and electrochemical impedance spectroscopy). The effect of temperature on the corrosion rate was investigated by the weight loss method, and some thermodynamic parameters for corrosion and adsorption processes were determined and discussed. The results show that the inhibition efficiency increased with the increase in inhibitor concentration and temperature. The adsorption of thiophene derivatives on the carbon steel surface obeys Langmuir adsorption isotherm. The obtained results indicated that the investigated compounds are chemically adsorbed on the steel surface. Potentiodynamic polarization studies showed that these compounds are mixed-type inhibitors and the results obtained from the techniques are in good agreement.


2011 ◽  
Vol 117-119 ◽  
pp. 999-1002
Author(s):  
Shu Qi Zheng ◽  
Chun Yu Li ◽  
Chang Feng Chen

The accelerated corrosion action of sulfur for carbon steel in wet H2S environment was studied by simulating the actual serviced environment. The weight-loss method, SEM, EDS and X-ray diffraction techniques are used to analyze the corrosion rate, the structure and the composition of the corrosion production formed in the environments. The results show that sulfur aggravated the corrosion sharply in wet H2S environment.


2016 ◽  
Vol 12 (12) ◽  
pp. 4593-4613
Author(s):  
Rekha. S ◽  
Kannan. K ◽  
Gnanavel. S

2-amino-6-nitrobenzothiazole(ANBT) was used as an inhibitor for the corrosion of mild steel in acid medium since the inhibition efficiency was low for that compound, 2,6-diaminobenzothiazole (DABT) and N-(6-aminobenzo [d] thiazol-2-y1) benzamide(ABTB) was synthesized,  and characterized by FT-IR, H1NMR, and C13NMR.The synthesized compound was tested as a corrosion inhibitor for mild steel in 1N HCl solution using weight loss, Potentiodynamic polarization, and AC impedance techniques. The inhibition efficiency was studied at the different time, temperature and acid concentration by weight loss method. The values of activation energy and free energy of adsorption of these compounds were also calculated, which reveals that the inhibitor was adsorbed on the mild steel by physisorption mechanism. Adsorption obeys Langmuir and Temkin adsorption isotherms. The results obtained by weight loss method revealed that the compound performed as a better inhibitor for mild steel in 1N HCl. Potentiodynamic polarization studies showed that the inhibitor acts as a mixed type inhibitor.AC impedance studies revealed that the corrosion process was controlled by charge transfer process. Surface analysis was studied using SEM and FT-IR.


2013 ◽  
Vol 2013 ◽  
pp. 1-22 ◽  
Author(s):  
Venkata Appa Rao Boyapati ◽  
Chaitanya Kumar Kanukula

The inhibiting effect of 1,2,3-benzotriazole (BTAH) against the corrosion of Cu-Ni (90/10) alloy in seawater and seawater polluted with inorganic sulphide was studied by electrochemical impedance studies (EISs), potentiodynamic polarization studies, and cyclic voltammetric (CV) and weight-loss studies. Surface examination studies were carried out by X-ray photo electron spectroscopy (XPS) and scanning electron microscopy (SEM)/energy dispersive X-ray analysis (EDX). EIS studies have been carried out in seawater and 10 ppm of inorganic sulphide containing seawater in the absence and presence of BTAH at different concentrations, different immersion periods, and at different temperatures. Appropriate equivalent circuit model was used to calculate the impedance parameters. The potentiodynamic polarization studies inferred that BTAH functions as a mixed inhibitor. The impedance, polarization, and weight-loss studies showed that the inhibition efficiency of BTAH is in the range between 99.97 and 99.30% under different conditions. Cyclic voltammeric studies show the stability of the protective BTAH film even at anodic potentials of +550 mV versus Ag/AgCl. All these studies infer that BTAH functions as an excellent inhibitor for Cu-Ni (90/10) alloy in seawater and sulphide-polluted seawater. XPS and SEM-EDX studies confirm the presence of protective BTAH film on the alloy surface.


2020 ◽  
Vol 21 (1) ◽  
pp. 86
Author(s):  
Ramlah Ramlah ◽  
Mohammad Wijaya ◽  
Diana Eka Pratiwi

ABSTRAK Penelitian ini merupakan penelitian eksperimen yang bertujuan untuk mengetahui pengaruh variasi konsentrasi inhibitor ekstrak daun beluntas (Pluchea indica Less.) terhadap laju korosi baja karbon dan karakteristik permukaan baja karbon sebelum dan sesudah direndam dalam media NaCl 3,5% tanpa dan dengan adanya inhibitor. Media korosif NaCl 3,5% direaksikan dengan ekstrak daun beluntas untuk memperlambat proses oksidasi Fe dengan variasi konsentrasi 0 ppm, 500 ppm, 1000 ppm, 1500 ppm dan 2000 ppm dan direndam selama 2, 4 dan 6 hari. Pengukuran laju korosi dilakukan dengan metode Weight loss dan polarisasi potensiodinamik. Karakterisasi baja karbon dilakukan menggunakan instrumen Fourier Transform Infra Red (FT-IR) dan Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS). Metode Weight loss dan polarisasi potensiodinamik menunjukkan nilai laju korosi terkecil pada perendaman selama 6 hari dengan konsentrasi inhibitor 2000 ppm yaitu masing-masing sebesar 1,5451 mmpy dan 1,5514 mmpy dengan efisiensi inhibisi sebesar 91%. Hasil penelitian menunjukkan bahwa semakin besar konsentrasi ekstrak dan semakin lama perendaman maka laju korosi semakin kecil dan efisiensi inhibisi semakin besar. Analisis FT-IR menunjukkan gugus fungsi yang teradsorpsi ke permukaan baja karbon yaitu O-H, C=C dan –CO-. Selain itu pada daerah sidik jari mengindikasikan ikatan Fe-O yang merupakan kompleks antara logam dengan senyawa ekstrak. Hasil analisis SEM-EDS menunjukkan bahwa pada permukaan baja karbon yang direndam dalam larutan NaCl 3,5% tanpa adanya inhibitor terbentuk retakan yang lebih banyak dibandingkan permukaan baja karbon yang direndam dalam larutan NaCl 3,5% dengan adanya ekstrak daun beluntas. Persentase Fe untuk baja karbon yang direndam tanpa adanya inhibitor sebesar 70,88% sedangkan untuk baja karbon yang direndam dengan adanya inhibitor sebesar 77,83%. Kata kunci: Laju Korosi, Baja Karbon, NaCl 3,5%, Inhibitor, Ekstrak Daun Beluntas ABSTRACT This research is an experiment research aimed to determine the effect of variations concentration of beluntas leaf extract on the corrosion rate of carbon steel and characteristics surface before and after immersed in 3,5% NaCl solution without and presence of inhibitors. Corrosive reacted with beluntas leaf extract to slow the process of oxidation Fe with various concentrations of 0 ppm, 500 ppm, 1000 ppm, 1500 ppm and 2000 ppm and immersion 2, 4 and 6 days. Measurement of corrotion rate by weight loss and potentiodynamic polarization method. Characterization of carbon steel used Fourier Transform Infra Red (FTIR) and Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS). Weight loss and potentiodynamic polarization methode showed that the smallest corrosion rate at 6 days immersion with an extract concentration of 2000 ppm, each of 1,5451 mmpy and 1,5514 mmpy with an efficiency of 91%. The results showed that the greater the extract concentration and the longer immersion the smaller the corrosion rate and the greater the eficciency. The fuctional groups adsorbed to the aurface of carbon steel are O-H, C=C and –CO-. Also in the fingerprint area indicate Fe-O bond is a complex between metal and extract compounds. The results of SEM-EDS analysis showed that on the carbon steel surface immersed in 3,5% NaCl solution without inhibitor formed more cracks than carbon steel surface immersed in 3,5% NaCl solution in the presence of beluntas leaf extract. Percentace of Fe for carbon steel immersed without an inhibitor is 70,88% while fore carbon steel immersed in the presence of an inhibitor of 77,83%. Keywords: Corrosion Rate, Carbon Steel, 3,5% NaCl, Inhibitor, Beluntas Leaf Extract


2019 ◽  
Vol 35 (2) ◽  
pp. 523-530
Author(s):  
Cleophas Akintoye Loto ◽  
Roland Tolulope Loto

Potassium gluconate inhibition effects of α-brass corrosion immersed in 1 M HNO3 were studied at room temperature (25°C). Gravimetric and potentiodynamic polarization measurement techniques were used separately for the experimental investigation. A Digi-Ivy potentiostat, connected to computer for data acquisition and analyses was used for the potentiodynamic polarization experiments. The observed potassium gluconate’s corrosion inhibition increased as the inhibitor concentration increased up to 3.5g/200ml HNO3 where a 0.7224g weight loss was recorded in comparison with the experiment without added inhibitor which had a 3.582g weight loss at 312 hours. The corresponding corrosion rate at 3.5g/200ml HNO3 concentration was 4.93 mm/yr while the uninhibited (control) experiment recorded a 20.33 mm/yr at 288 hrs. Corrosion inhibition efficiency values for the 1.5, 3, 3.5 and 4g/200ml HNO3 concentrations are respectively 16.99, 41.77, 79.86 and 64.53%. Other parameters recorded include: polarization resistance, Ω (3.20E+01); corrosion rate (19.15 mm/yr) and current density, 1.01E-03 Acm-2 for the 3.5g/200ml HNO3 concentration in HNO3 test medium were also achieved. A mixed type inhibitor was indicated with the recorded results of ba and bc. Adsorption isotherm showed that inhibitor protection mechanism followed both the Frumkin and the Freundlich models more than the Langmuir isotherm model.


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