scholarly journals Two-Step Facile Preparation of 2D MoS2/ZnO Nanocomposite p - n Junctions with Enhanced Photoelectric Performance

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Ali Aldalbahi ◽  
Zhen-Bo Wang ◽  
Tansir Ahamad ◽  
Saad M. Alshehri ◽  
Peter X. Feng
Keyword(s):  
Transport Properties ◽  
Response Times ◽  
Synergistic Effects ◽  
Spectral Response ◽  
Hole Transport ◽  
High Signal ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Band Shift ◽  
Photoelectric Properties

Both p - n and n - p heterojunctions of ZnO-MoS2 have been fabricated in order to understand the performance of electron and hole transport properties in solar cells and a self-powered photodetector system. Atomically thin 2-dimensional (2D) MoS2 was prepared by using a spin coating method with controlled process times, whereas ZnO nanowires were prepared by using a plasma sputtering deposition technique. The nanoscale morphologies, composites, and photoelectric properties of nanocomposites were examined using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and micro-Raman scattering spectroscopy, respectively. 2D heteronanostructures have exhibited an enhanced performance as compared to single-material-based prototypes. In photovoltaic mode, n - p heterojunction of the ZnO-MoS2-based prototype appears to have much better photoelectric conversion efficiency than that in the case with p - n junction, indicating highly effective hole transport properties of 2D MoS2 materials. Both band broadening and band shift were observed. Furthermore, the bias, annealing, and synergistic effects on the generated photocurrents and the response times were evaluated. The newly designed prototype exhibits exceptional properties: a broadband spectral response, a high signal-to-noise ratio, and excellent stability.

scholarly journals CuI/Spiro-OMeTAD Double-Layer Hole Transport Layer to Improve Photovoltaic Performance of Perovskite Solar Cells

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 978
Author(s):  
Chaoqun Lu ◽  
Weijia Zhang ◽  
Zhaoyi Jiang ◽  
Yulong Zhang ◽  
Cong Ni
Keyword(s):  
Solar Cells ◽  
Double Layer ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Perovskite Layer

The hole transport layer (HTL) is one of the main factors affecting the efficiency and stability of perovskite solar cells (PSCs). However, obtaining HTLs with the desired properties through current preparation techniques remains a challenge. In the present study, we propose a new method which can be used to achieve a double-layer HTL, by inserting a CuI layer between the perovskite layer and Spiro-OMeTAD layer via a solution spin coating process. The CuI layer deposited on the surface of the perovskite film directly covers the rough perovskite surface, covering the surface defects of the perovskite, while a layer of CuI film avoids the defects caused by Spiro-OMetad pinholes. The double-layer HTLs improve roughness and reduce charge recombination of the Spiro-OMeTAD layer, thereby resulting in superior hole extraction capabilities and faster hole mobility. The CuI/Spiro-OMeTAD double-layer HTLs-based devices were prepared in N2 gloveboxes and obtained an optimized PCE (photoelectric conversion efficiency) of 17.44%. Furthermore, their stability was improved due to the barrier effect of the inorganic CuI layer on the entry of air and moisture into the perovskite layer. The results demonstrate that another deposited CuI film is a promising method for realizing high-performance and air-stable PSCs.

Subwavelength Periodic Structures Design and its Role in Photon Control of Thin Film Solar Cells

NANO ◽  
2020 ◽  
Vol 15 (11) ◽  
pp. 2050139
Author(s):  
Zhiye Wang ◽  
Xiangqian Shen ◽  
Shuying Wang ◽  
Hua Zhou ◽  
Peihua Wangyang ◽  
...  
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Periodic Structures ◽  
Spectral Response ◽  
Incident Light ◽  
Optical Loss ◽  
Thin Film Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Optimized Design ◽  
Photoelectric Conversion

A subtle modification of the device surface is able to reduce optical loss and to further achieve high photoelectric conversion efficiency for thin film solar cells. This work shows the manipulation properties of subwavelength periodic structures on incident light at air/glass surface. In order to explore the mechanisms of optical loss, the spectral response and energy distribution of light are investigated by using rigorous coupled wave analysis and finite difference time domain methods. Calculation results show that the diffraction scattering and gradient refraction index play a significant role for better photon harvesting. With an optimized design of [Formula: see text][Formula: see text]nm, [Formula: see text], and hemispherical shape structure, obvious improvement in transmittance, external quantum efficiency and photo-generated current is achieved. The photoelectric conversion efficiencies of amorphous silicon thin film cells with an absorbing layer thickness of 400[Formula: see text]nm is 8.04%, improved by 5.9% compared with the flat cell of equivalent size.

Preparation and Optical Properties of TiO2 Film with a Nest-Like Structure by Three Times of Circulating Hydrothermal Method

NANO ◽  
2016 ◽  
Vol 11 (06) ◽  
pp. 1650066 ◽  
Author(s):  
Quangui He ◽  
Jia Zhuang ◽  
Qiuxiang Wen ◽  
Yang Deng ◽  
Jun Yu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Hydrothermal Method ◽  
Three Dimensional ◽  
Dye Adsorption ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Facile Hydrothermal Method ◽  
Conductive Glass ◽  
Photoelectric Properties ◽  
Adsorption Amount

An anatase TiO2 photoanode with a novel three-dimensional nest-like structure was prepared directly on a transparent conductive glass substrate through hydrothermal cycles by three times. First, an unidirectional banded structure film was prepared by a facile hydrothermal method. And then, with the time of hydrothermal cycle increased, part of nanobelts were ruptured into a lot of small polyhedrons, but they still maintained a trend of the previous connection, and some fine nanobelts were interweaved in small polyhedrons. Finally, we successfully prepared a film with a novel 3D nest-like structure, and it had all the characteristics of the hierarchitectures. It had better photoelectric properties than the film with fewer times of hydrothermal cycle. Its photoelectric conversion efficiency reached 3.81%, which is due to a large dye adsorption amount, rapid electronic transmission, and superior light scattering and more electrons transmission paths.

Nano-Efficient Photoelectric Conversion-Based Solar Photovoltaic System and Its Usage in Green Buildings

2021 ◽  
Vol 16 (2) ◽  
pp. 264-272
Author(s):  
Yibing Xue ◽  
Ziye Song
Keyword(s):  
Solar Cell ◽  
Solar Energy ◽  
Dye Sensitized Solar Cells ◽  
Control Unit ◽  
Green Buildings ◽  
Photovoltaic System ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Photovoltaic Solar Cell ◽  
Photoelectric Properties

Solar energy is a world-recognized green and pollution-free energy source. Photovoltaic technology based on solar energy has become the focus of new energy development. On this basis, how to improve the energy efficiency of solar energy has become a research hotspot. In this study, the solution method was used, acety-lacetonate was used as the precursor, and the mixture of dodecyl mercaptan (DDT) and oleylamine (OLA) was used as the solvent to obtain CuInS2 nanocrystals with wurtzite structure. Then, the dispersion of organic synthesized CuInS2 nanocrystals was retained, and the organic macromolecules affecting electron transport in the nanocrystals were eliminated. This material was used for the counter electrode of dye-sensitized solar cells. While analyzing the photoelectric characteristics of the nanoelectronic material, the hardware of the photovoltaic solar cell prepared based on the material should be designed, including the selection of the main control unit, the design of the peripheral circuit, the design of the charging and discharging circuit, so as to realize the management of the photovoltaic solar cell. In the test, OLA had an impact on the crystal structure, size, and dispersion of CuInS2 nanocrystals, thereby changing the photoelectric properties of the nanoelectronic materials, which were applied in photovoltaic panels for green buildings. The photoelectric conversion efficiency of CuInS2 nanocrystals after phase exchange in the green build-photovoltaic system was much higher than that of CuInS2 nanocrystals before phase exchange, and even higher than that of CuInS2 nanocrystals calcined at high temperature before phase exchange in the green build-photovoltaic system.

Study on Properties of Dye-Sensitized TiO2 Films

2012 ◽  
Vol 602-604 ◽  
pp. 1492-1496
Author(s):  
Wei Cong ◽  
Jiang Li ◽  
En Xiang Han
Keyword(s):  
Solar Cells ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Tetrabutyl Titanate ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Hydrothermal Temperature ◽  
Dye Sensitized ◽  
Photoelectric Properties ◽  
Titania Films

TiO2nanoporous thin films were fabricated by the hydrothermal method using tetrabutyl titanate as the precursor and used to assemble dye-sensitized solar cells. The properties which include the short-circuit photocurrent(ISC),open-circuit voltage(VOC) and the fill factor(FF)of the solar cells were tested. The microstructure of titania films were modulated by changing the hydrothermal reaction temperature and the amount of PEG and the influence on the properties of the solar cells by titania films weas studied. The results indicate that there are better photoelectric properties for TiO2films at the hydrothermal temperature fo 230°C and the additive amount of PEG being 5% of the mass of TiO2. ISC,VOCand FF was 12.42mA, 681mV, and 0.52 respectively, the photoelectric conversion efficiency(η)was 4.37%．

Furrowed hole-transport layer using argon plasma in an inverted perovskite solar cell

2019 ◽  
Vol 43 (36) ◽  
pp. 14625-14633 ◽  
Author(s):  
Xiao-Mei Li ◽  
Kai-li Wang ◽  
Yu-Rong Jiang ◽  
Ying-Guo Yang ◽  
Xing-Yu Gao ◽  
...  
Keyword(s):  
Solar Cell ◽  
Plasma Treatment ◽  
Conversion Efficiency ◽  
Argon Plasma ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion

In this study, a novel process was found to be effective using the argon-plasma treatment, in which the ion cluster was used to scour the PEDOT:PSS surface instead of the traditional bombardment method. The photoelectric conversion efficiency of the device reaches 14.8%.

Preparation and Photoelectric Properties of Spinel MCr2O4 (M = Cu, Ni) Nanopowders

2011 ◽  
Vol 415-417 ◽  
pp. 1594-1598
Author(s):  
Zhi Qiang Hu ◽  
Ying Qin ◽  
Xian Qing Liu ◽  
Shang Ru Zhai ◽  
Hong Gao
Keyword(s):  
Composite Film ◽  
Conversion Efficiency ◽  
Composite Electrode ◽  
Diffuse Reflectance Spectrum ◽  
Aqueous System ◽  
Photoelectric Conversion Efficiency ◽  
Film Electrode ◽  
Photoelectric Conversion ◽  
Photoelectric Properties ◽  
Co Precipitation

Spinel MCr2O4(M = Cu, Ni) nanopowders were synthesized by co-precipitation technique from alcohol-aqueous system and the performance of MCr2O4/TiO2 composite film electrodes was studied. The synthesized MCr2O4 nanopowders were characterized by X-ray diffraction (XRD) and UV-vis diffuse reflectance spectrum (UV-vis). The MCr2O4 nanopowders were doped into nanocrystalline semiconductor oxide film electrode of DSSCs and the influence of doping content was investigated. Compared with the pure TiO2 film electrode, the absorbance of different MCr2O4/TiO2 composite film electrode increased significantly. Furthermore, the light respondence of CuCr2O4/TiO2 composite electrode was better than NiCr2O4/TiO2 composite electrode. When the content of CuCr2O4 2%, the photoelectric conversion efficiency increased by 54%, and doping 1% NiCr2O4 nanopowders, the photoelectric conversion efficiency was improved 30%.

Investigation on Applying Compound Solvent in Liquid Electrolyte for Dye-Sensitized Solar Cells

2011 ◽  
Vol 347-353 ◽  
pp. 906-911
Author(s):  
Zhi Qiang Hu ◽  
De Feng Huang ◽  
Xian Qing Liu ◽  
Hong Gao ◽  
Hong Shun Hao
Keyword(s):  
Solar Cells ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Liquid Electrolyte ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Photoelectric Properties ◽  
Sensitized Solar Cells

Liquid electrolyte for dye-sensitized solar cells (DSSCs) was prepared by using the mixture of sulfolane and 3-methoxypropionitrile as a solvent, 4-tert-butylpyridine as an additive. The influences of sulfolane on electrolyte conductivity, photoelectric performances and the DSSCs stability were investigated. The results indicated that when the ratio of 3-methoxypropionitrile to sulfolane achieves 3:2, the cell showed the optimal photoelectric properties and stability, and the short-circuit current and photoelectric conversion efficiency achieved 7.58mA/cm2 and 2.79%, respectively.

Effect of Cu(Cr0.2Al0.8)2O4/TiO2 Composite Film Electrodes on DSSC Photoelectric Properties

2013 ◽  
Vol 275-277 ◽  
pp. 1683-1687
Author(s):  
Feng Xia Zhou ◽  
Yan Yan Jiang ◽  
Ji Wen Zhang ◽  
Jing Xiao Liu ◽  
Gui Shan Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Composite Film ◽  
Conversion Efficiency ◽  
Diffuse Reflectance Spectrum ◽  
Composite Films ◽  
Dye Sensitized Solar Cells ◽  
Nano Particles ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Photoelectric Properties

Cu(Cr0.2Al0.8)2O4/TiO2composite film electrodes were prepared on FTO glass substrate by screen printing method after Cu(Cr0.2Al0.8)2O4nano-particles were doped in TiO2powers. The characteristics were studied by the X-ray diffraction for the crystalline structure of composite films, UV-Vis diffuse reflectance spectrum instruction for absorption spectrum of composite films and dye sensitized solar cells tester for the performance of DSSC. The results show doping Cu(Cr0.2Al0.8)2O4powers could enhance UV-Vis spectral absorption strength and improve the photoelectric conversion efficiency of the solar cells when the doping content of Cu(Cr0.2Al0.8)2O4is 3％. Compared with pure TiO2film electrodes, the photoelectric conversion efficiency of the solar cells reaches to 3.59％.

scholarly journals Computational Prediction of Electronic and Photovoltaic Properties of Anthracene-Based Organic Dyes for Dye-Sensitized Solar Cells

2018 ◽  
Vol 2018 ◽  
pp. 1-17 ◽  
Author(s):  
Hongbo Wang ◽  
Qian Liu ◽  
Dejiang Liu ◽  
Runzhou Su ◽  
Jinglin Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Density Functional ◽  
Organic Dyes ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Dye Sensitized ◽  
Photoelectric Properties ◽  
Sensitized Solar Cells

Three kinds of anthracene-based organic dyes for dye-sensitized solar cells (DSSCs) were studied, and their structures are based on a push–pull framework with anthracenyl diphenylamine as the donor connected to a carboxyphenyl or carboxyphenyl-bromothiazole (BTZ) as the acceptor via an acetylene bridge. The photoelectric properties of the three dyes were investigated using density functional theory (DFT). The simulations indicate that the improvement of anthracene-based dyes (the addition of BTZ and the change of alkyl groups to alkoxy chains) can reduce the energy gap and produce a red shift. This structural modification also improves the light capturing and the electron injection capability, making it excellent in photoelectric conversion efficiency (PCE). In addition, twelve molecules have been designed to regulate photovoltaic performance.

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