scholarly journals The Influence of Heat Treatment on the Static and Dynamic Sorptive Behavior of Moso Bamboo (Phyllostachys pubescens)

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Yuxiang Huang ◽  
Ru Liu ◽  
Fandan Meng ◽  
Yanglun Yu ◽  
Wenji Yu

The influence of heat treatment on moisture sorption behavior of moso bamboo (Phyllostachys pubescens), especially under dynamic sorption conditions, was investigated. Moso bamboo was heated to 180 and 200°C for 8 h to investigate the chemical components and sorptive behavior at sinusoidal relative humidity (RH) and constant humidity. The results of chemical components revealed that the content of holocellulose,α-cellulose, and hemicellulose decreased while that of lignin increased slightly with increasing treatment temperatures. The results of static adsorption at constant RH showed that 200°C treated bamboo exhibited the lowest moisture content and moisture sorption coefficient. The results of dynamic sorptive behavior indicated that the moisture content changed sinusoidally but lagged behind the triggering sinusoidal RH changes. Heat-treated bamboo presented greater phase lag and smaller amplitudes of moisture content and sorption hysteresis due to the hemicellulose removal.

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1264
Author(s):  
Teng-Chun Yang ◽  
Tung-Lin Wu ◽  
Chin-Hao Yeh

The influence of heat treatment on the physico-mechanical properties, water resistance, and creep behavior of moso bamboo (Phyllostachys pubescens) was determined in this study. The results revealed that the density, moisture content, and flexural properties showed negative relationships with the heat treatment temperature, while an improvement in the dimensional stability (anti-swelling efficiency and anti-water absorption efficiency) of heat-treated samples was observed during water absorption tests. Additionally, the creep master curves of the untreated and heat-treated samples were successfully constructed using the stepped isostress method (SSM) at a series of elevated stresses. Furthermore, the SSM-predicted creep compliance curves fit well with the 90-day full-scale experimental data. When the heat treatment temperature increased to 180 °C, the degradation ratio of the creep resistance (rd) significantly increased over all periods. However, the rd of the tested bamboo decreased as the heat treatment temperature increased up to 220 °C.


2012 ◽  
Vol 468-471 ◽  
pp. 1118-1122
Author(s):  
Yan Jun Li ◽  
Lan Xing Du ◽  
Gou Ying Hu ◽  
Xing Xia Ma

To enhance decay resistance, the effect of heat treatment and the variation of chemical composition on Chinese Fir and Pine were investigated in this study — heat treatment temperature was 170°C, 190°C and 210°C, respectively, heat treatment time was 2, 3 and 4hours, respectively. Both of them were subsequently exposed to white-rot fungus and brown-rot fungus. The results showed that:(1) With the increasing of the heat treatment, decay resistance of Chinese Fir and Pine were improved, anti-corrosion of Pine after being heat treated at 190°C which were exposed to write-rot fungus can reach I, anti-corrosion of Chinese Fir after being heat treated at 170°C treated which were exposed to brown-rot fungus could reach I yet, After being heat treated at 210°C for 3 hours , the Chinese fir samples had no measurable weight loss when exposed to the write-rot fungus.(2) There was no remarkable influence on both Chinese Fir and Pine by heat treatment time.(3) The moisture content of Chinese Fir and Pine were lower than the moisture content that the rot fungus need, macromolecule chains such as cellulose and hemicellulose broke down, their contents decreased, and the hemicellulose decomposed into acetic acid, they prevented the growth of rot fungus.


Author(s):  
Neda Maftoonazad ◽  
Hosahalli S. Ramaswamy ◽  
Michele Marcotte

The moisture sorption behavior of pectin films formulated with different sorbitol content was evaluated and films with different equilibrium moisture contents were obtained. Different models were used to describe the moisture sorption isotherms (MSI) of pectin films, sorbitol and pectin powder. Based on changes observed in MSI, sorbitol was found to strongly interact with pectin polymers. Incorporation of sorbitol in pectin films resulted in lower equilibrium moisture contents at low to intermediate water activities (aw), but much higher moisture contents at aw > 0.53. Estimates of monolayer moisture values (1.53 – 3.81 g H2O kg-1 solids) were obtained by the application of Guggenheim-Anderson-DeBoer (GAB) model. A differential mechanical analyzer (DMA) was used for mechanical properties of formulated films while a differential scanning calorimeter (DSC) was used for thermal properties and glass transition temperature (Tg). With both DMA and DSC tests, the strong plasticizing action of water and sorbitol was evident. Tg vs. moisture content data were successfully fitted to the Fox empirical model. Multi-frequency DMA measurements provided estimates for the apparent activation energy (Ea) of the second glass transition in the range of 131-184 kJ/mol; the values for Ea decreased with increasing sorbitol concentration. Water vapor permeability (WVP) and mechanical properties of the films were also analyzed under varying sorbitol and moisture contents. Increasing moisture or addition of sorbitol to pectin films increased the elongation at break, but decreased the tensile strength, modulus of elasticity and Tg, and increased WVP of the films.


Holzforschung ◽  
2014 ◽  
Vol 68 (2) ◽  
pp. 185-193 ◽  
Author(s):  
Christian Brischke ◽  
Kathrin A. Sachse ◽  
Christian R. Welzbacher

Abstract A model has been developed aiming at the description of the effect of thermal modification on the electrical conductivity of wood. The intention was to calculate the moisture content (MC) of thermally modified timber (TMT) through the parameters electrical resistance R, wood temperature T, and CIE L*a*b* color data, which are known to correlate well with the intensity of a heat treatment. Samples of Norway spruce (Picea abies Karst.) and beech (Fagus sylvatica L.) samples were thermally modified in laboratory scale at 11 different heat treatment intensities and the resistance characteristics of the samples were determined. Within the hygroscopic range, a linear relationship between the resistance characteristics and the mass loss (ML) through the heat treatment was established. Based on this, a model was developed to calculate MC from R, T, and ML. To validate this model, color values of 15 different TMTs from industrial production were determined for estimation of their ML and fed into the model. MC of the 15 arbitrarily heat-treated TMTs was calculated with an accuracy of ±3.5% within the hygroscopic range. The material-specific resistance characteristics based on experimental data led to an accuracy of ±2.5%.


FLORESTA ◽  
2010 ◽  
Vol 40 (1) ◽  
Author(s):  
Rodrigo Strzelecki Berndsen ◽  
Ricardo Jorge Klitzke ◽  
Djeison Cesar Batista ◽  
Eduardo Mauro do Nascimento ◽  
Fabiano Ostapiv

As buscas por materiais renováveis de baixo impacto ambiental apontam o bambu como um material que promove o desenvolvimento sustentável devido ao seu rápido crescimento e por não precisar ser replantado após seu corte. O principal objetivo deste estudo foi determinar as seguintes propriedades físicas do bambu-mossô (Phyllostachys pubescens Mazel ex H. de Lehaie): teor de umidade, densidade básica e retratibilidade. Procurou-se investigar as diferenças entre as propriedades físicas em diferentes posições de colmos (base, meio, topo) de diferentes idades (1, 3 e 5 anos), visando a melhor utilização dessa matéria-prima. Os resultados mostraram que não houve interação significativa entre os fatores “idade” e “posição” para as propriedades teor de umidade e densidade básica, de acordo com a ANOVA em arranjo fatorial (95% de probabilidade). O teor de umidade diminuiu com o aumento da idade e da base para o topo, enquanto que a densidade básica aumentou com a idade e da base para o topo. A interação significativa entre os fatores “idade” e “posição” somente foi observada para a retratibilidade. A porção menos estável foi o topo dos bambus com cinco anos de idade, onde se encontraram maiores valores para a contração radial, tangencial e volumétrica. A porção basal na idade de três anos revelou-se a mais estável em contração volumétrica e tangencial. As porções base e topo na idade de um ano foram as mais estáveis quanto à contração radial. Palavras-chave: Phyllostachys pubescens; bambu-mossô; propriedades físicas.   Abstract Physical properties of moso bamboo (Phyllostachys pubescens Mazel ex H. de Lehaie) at different ages and culm positions. The searching for renewable material with low environment impact put bamboo forward as a material that promotes the sustainable development due to its fast growing and that is not necessary to replant after harvesting. The aim of this study was to evaluate the following physical properties at different culm positions (base, middle and top) and ages (1, 3 and 5 years old) of moso bamboo (Phyllostachys pubescen Mazel ex H. de Lehaie): moisture content, basic density and shrinkage. The results showed that there was no significant interaction between the factors “age” and “position” for moisture content and basic density according to ANOVA in factorial arrange (95% of probability). Moisture content decreased with the increase of age and from base to top, while basic density increased with age and from base to top. Significant interaction between the factors “age” and “position” was only observed for shrinkage test according to ANOVA in factorial arrange. The portion less stable was the top of bamboo with five years old, which presented the highest radial, tangential and volumetric shrinkages. The basal portion of three years old was the most stable in volumetric and tangential shrinkage. The portions of base and top of one year old were the most stable in radial shrinkage.Keywords: Phyllostachys pubescens; moso bamboo; physical properties.


Forests ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 1081
Author(s):  
Vlastimil Borůvka ◽  
Přemysl Šedivka ◽  
David Novák ◽  
Tomáš Holeček ◽  
Jiří Turek

This paper deals with the effect of heat treatment on the selected physical properties of birch wood. Five stages of heat treatment were used, ranging from 160 °C to 200 °C, in 10 °C increments, having a peak treatment duration of 3 h for each level. Primarily, changes in thermal characteristics, namely conductivity, diffusivity, effusivity, volume heat capacity, changes in colour and gloss parameters, mass loss due to modification and different moisture content in wood under given equilibrium climatic conditions, were monitored. The ISOMET 2114 analyser was used to measure the thermal characteristics. The measurement principle of this analyser is based on the analysis of the thermal response of the analysed material to pulses of heat flow. Measurements of colour, gloss, density and moisture content were carried out according to harmonised EN standards. The aim was to experimentally verify the more or less generally known more positive perception of heat-treated wood, both by touch and sight, i.e., the warmer perception of darker brown shades of wood. In terms of thermal characteristics, the most interesting result is that they gradually decrease with increasing treatment temperature. For example, at the highest treatment temperature of 200 °C, there is a decrease in thermal conductivity by 20.2%, a decrease in volume heat capacity by 15.0%, and a decrease in effusivity by 17.7%. The decrease in thermal conductivity is nearly constant at all treatment levels, specifically at this treatment temperature, by 6.0%. The fact mentioned above is positive in terms of the tactile perception of such treated wood, which can have a positive effect, for example, in furniture with surface application of heat-treated veneers, which are perceived positively by the majority of the human population visually or as a cladding material in saunas. In this context, it has been found that the thermal modification at the above-mentioned treatment temperature of 200 °C results in a decrease in brightness by 44.0%, a decrease in total colour difference by 38.4%, and a decrease in gloss (at an angle of 60°) by 18.2%. The decrease in gloss is only one essential negative aspect that can be addressed by subsequent surface treatment. During the heat treatment, there is also a loss of mass in volume, e.g., at a treatment temperature of 200 °C and subsequent conditioning to an equilibrium moisture content in a conditioning chamber with an air temperature of 20 ± 2 °C and relative humidity of 65 % ± 5%, there was a decrease by 7.9%. In conclusion, the experiments clearly confirmed the hypothesis of a positive perception of heat-treated wood in terms of haptics and aesthetics.


2011 ◽  
Vol 183-185 ◽  
pp. 1896-1900
Author(s):  
Rong Jun Zhao ◽  
Xian Bao Cheng ◽  
Wei Wei Shuangguan ◽  
Juan Sun ◽  
Ben Hua Fei

In this paper, the zero-span tensile strengths of tracheids of Chinese fir and Masson pine were investigated, and the effect of the moisture on the tracheid strength was also discussed. Furthermore, the influence of thermal treatment on the zero-span tensile strengths of tracheids were analysed, and research of relationship of zero-span tensile strengths, chemical components and cellulose crystallinity were also conducted. This study tried to explore the inherent mechanism of heat treatment on the cell level.


1930 ◽  
Vol 2 (1) ◽  
pp. 65-90 ◽  
Author(s):  
W. F. Geddes

Studies were conducted on heat-treated samples of unbleached straight-grade flour milled from Western Canadian hard red spring wheat with the purpose of determining the influence of time and temperature of heating flour with normal moisture content on certain biochemical properties related to "strength". Samples were selected which showed a progressive range in baking quality including some which revealed improvement as a result of heat treatment, when baked by the basic procedure. Gluten quality was impaired in all heat-treated samples, as evidenced by decreased viscosity of leached, acidulated flour suspensions, a decreased rate and extent of imbibition of the washed out gluten, and decreased gas retention of the dough. High positive correlations between viscosity, gas retention, and loaf volume were obtained. The somewhat higher correlations between these measures of gluten quality and loaf volume when determined with potassium bromate added to the formula suggest that the bromate method gives a better measure of gluten quality than the basic procedure. Decrease in viscosity was approximately a linear function of the temperature, for constant time of heating. Ease of peptization of the flour proteins by N. magnesium sulphate, N. potassium iodide, and 5% potassium sulphate solutions showed a marked and progressive decrease with increasing severity of heat treatment. The high positive correlations between the percentage of protein extractable by these salts indicate that the magnitude of these fractions is influenced by the same inherent qualities of the flour proteins. The high positive correlations between the percentage of protein peptized by these salts and viscosity, suggest that these "qualities" are the colloidal properties of the flour proteins. High positive correlations were obtained between loaf volume and percentage of protein peptized. Increasing the moisture content of the flour, with fixed time and temperature of heating, resulted in decreased peptization indicating more extensive heat denaturation of the gluten proteins. Fractionation of the flour proteins showed that the decrease in the potassium sulphate fraction with increasing severity of heat treatment contributed to both the gliadin and glutenin fraction (as determined by the direct barium hydroxide method). Diastatic activity, as determined by the modified Rumsey method and by the rate of gas production in doughs without added sugar, revealed only slight decreases with those flours which showed improvement in baking quality due to heat treatment. Marked decreases were observed with the more severe heat treatments. Susceptibility of the starch to diastatic action was unaltered until marked damage to baking quality resulted, when significant decreases were noted. Heat inactivation of diastase evidently occurred before changes in amyloclastic susceptibility. Proteolytic activity markedly decreased with heat treatment, significant decreases being noted before diastatic activity was appreciably altered. The hydrogen ion concentration of flour extracts revealed no particular trend due to heat treatment, but the buffer value was somewhat increased. The biochemical changes investigated were, for the most part, in a direction associated with decreased baking quality, and provided no adequate explanation for the improvement in baking quality observed in certain samples when baked by the basic procedure.


2020 ◽  
Vol 21 (4) ◽  
pp. 11-20
Author(s):  
Maha Muhyi Alhussaini ◽  
Hassanain A. Hassan ◽  
Nada S. Ahmedzeki

   The moisture sorption isotherms of Mefenamic acid tablets were investigated by measuring the experimental equilibrium moisture content (EMC) using the static method of saturated salt solutions at three temperatures (25, 35, and 45°C) and water activity range from 0.056 to 0.8434. The results showed that EMC increased when relative humidity increased and the sorption capacity decreased, the tablets became less hygroscopic and more stable when the temperature increased at constant water activity. The sorption curves had a sigmoid shape, type II according to Brunauer’s classification. The hysteresis effect was significant along with the whole sorption process. The results were fitted to three models: Oswin, Smith, and Guggenhein - Anderson and de Boer. According to the fitting results, the GAB model was the most appropriate model to describe the sorption behavior of Mefenamic acid; it had a regression coefficient range (0.9803-0.994), %E (0.69-4.06), and low values of SEE (0.85-2.2). The monolayer moisture content was calculated using the GAB model and it was concluded that the tablets should be stored at moisture content equal or slightly higher than (0.2046, 0.1843, and 0.1437 %) for desorption and (0.2073, 0.1269, and 0.1452 %) for adsorption for the three temperatures.


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