scholarly journals Fabrication and Characteristics of Mn@ Cu3(BTC)2 for Low-Temperature Catalytic Reduction of NOx with NH3

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Zhuo Yao ◽  
Dianli Qu ◽  
Yuxiang Guo ◽  
Yujing Yang ◽  
Hong Huang
Keyword(s):  
Catalytic Reduction ◽  
Copper Ions ◽  
Structural Characteristics ◽  
Exchange Method ◽  
Pore Sizes ◽  
Structure Surface ◽  
Metal Organic ◽  
Reduction Of Nox ◽  
Reduced Water ◽  
Catalytic Performances

Novel catalysts with high activity for the selective catalytic reduction of NO with NH3 (NH3-SCR) at low temperatures are highly demanded. In this study, mixed-node metal-organic frameworks (MOFs), e.g. Mn@CuBTC with controlled Mn composition in Cu3(BTC)2, were fabricated using postsynthetic exchange method and their structural characteristics and catalytic performances for NH3-SCR reaction were assessed. A series of analyses in terms of structure, surface morphology, texture, and chemical state determined that Mn ions were successfully incorporated into the Cu3(BTC)2 crystal lattice as well as adsorbed on the walls of nanopores in the framework. The pore sizes can be finely tuned in the presence of Mn ions in the cages, which significantly suppressed water adsorption. The NH3-SCR activity of Mn@CuBTC exhibited nearly 100% NOx conversion rate in the temperature range (230–260°C). The superior NH3-SCR performance is attributed to the proper pore sizes, reduced water content, and the synergistic effect between manganese and copper ions in the MOF structure, which enhanced NH3 bound to the active Lewis sites.

The selective catalytic reduction of NOx over a Cu/ZSM-5/SAPO-34 composite catalyst

RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 104923-104931 ◽  
Author(s):  
Jixing Liu ◽  
Weiyu Song ◽  
Chi Xu ◽  
Jian Liu ◽  
Zhen Zhao ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Mass Fraction ◽  
Catalytic Reduction ◽  
Composite Catalyst ◽  
Composite Catalysts ◽  
Scr Of No ◽  
Reduction Of Nox ◽  
Seed Method ◽  
Catalytic Performances

A series of Cu/ZSM-5/SAPO-34 composite catalysts with varying ZSM-5 mass fraction were synthesized using a pre-seed method, and their catalytic performances were tested for selective catalytic reduction (SCR) of NO with NH3.

scholarly journals A CeO2/ZrO2-TiO2 Catalyst for the Selective Catalytic Reduction of NOx with NH3

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 592 ◽  
Author(s):  
Wenpo Shan ◽  
Yang Geng ◽  
Yan Zhang ◽  
Zhihua Lian ◽  
Hong He
Keyword(s):  
Selective Catalytic Reduction ◽  
Ph Value ◽  
Catalytic Reduction ◽  
Space Velocity ◽  
Catalytic Performance ◽  
Excellent Activity ◽  
Reduction Of Nox ◽  
High Space ◽  
Catalytic Performances ◽  
High Space Velocity

In this study, CeZr0.5TiaOx (with a = 0, 1, 2, 5, 10) catalysts were prepared by a stepwise precipitation approach for the selective catalytic reduction of NOx with NH3. When Ti was added, all of the Ce-Zr-Ti oxide catalysts showed much better catalytic performances than the CeZr0.5Ox. Particularly, the CeZr0.5Ti2Ox catalyst showed excellent activity for broad temperature range under high space velocity condition. Through the control of pH value and precipitation time during preparation, the function of the CeZr0.5Ti2Ox catalyst could be controlled and the structure with highly dispersed CeO2 (with redox functions) on the surface of ZrO2-TiO2 (with acidic functions) could be obtained. Characterizations revealed that the superior catalytic performance of the catalyst is associated with its outstanding redox properties and adsorption/activation functions for the reactants.

Recent advances in the preparation of zeolites for the selective catalytic reduction of NOx in diesel engines

2019 ◽  
Vol 4 (6) ◽  
pp. 975-985 ◽  
Author(s):  
Ling Zhang ◽  
Qinming Wu ◽  
Xiangju Meng ◽  
Ulrich Müller ◽  
Mathias Feyen ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Diesel Engines ◽  
Catalytic Reduction ◽  
Pore Sizes ◽  
Recent Advances ◽  
Small Pore ◽  
Reduction Of Nox ◽  
Scr Of Nox

Metal-exchanged zeolites with small pore sizes have attracted much attention in recent years due to their application in the selective catalytic reduction (SCR) of NOx in diesel engines.

Investigation of the SCR Catalyst Ce-V/TiO2

2009 ◽  
Vol 610-613 ◽  
pp. 274-280
Author(s):  
Fen Wang ◽  
Xiu Feng Ren ◽  
Jian Feng Zhu ◽  
Hai Bo Yang
Keyword(s):  
Reaction Temperature ◽  
Catalytic Reduction ◽  
Sol Gel ◽  
Selective Reduction ◽  
Catalytic Performance ◽  
Scr Catalyst ◽  
Nox Conversion ◽  
Selective Reduction Of Nox ◽  
Reduction Of Nox ◽  
Catalytic Performances

The Ce-V/TiO2 catalysts with the selective catalytic reduction (SCR) were prepared by method of Sol-gel and insuccation. The phase compositions, microstructures and specific surface area of the catalysts were analyzed by XRD, SEM and BET, respectively. The effect of CeO2 and V2O5 loading and reaction temperature on the catalytic performances of the as-prepared catalysts was investigated by using the selective reduction of NOx with NH3. The results showed all the as-prepared Ce-V/TiO2 catalysts were made up of nanometer grains. Compared to conventional TiO2 catalysts, the as-prepared Ce-V/TiO2 catalysts possessed better catalytic performance, higher adsorbability and larger area of contact with reactant, which is due to large quantity surface micropores. The NOx conversion of SCR over 5wt%Ce-10wt%V/TiO2 catalysts reached 96.2% at the reaction temperature of 500 oC.

Investigation and Preparation of the SCR Catalysts Nano-Co/Ce-V-Zr-TiO2

2010 ◽  
Vol 663-665 ◽  
pp. 1097-1102
Author(s):  
Xiu Feng Ren ◽  
Fen Wang ◽  
Yuan Zhou ◽  
Hong En Nian ◽  
Yu Na Pang ◽  
...  
Keyword(s):  
Reaction Temperature ◽  
Catalytic Reduction ◽  
Sol Gel ◽  
Selective Reduction ◽  
Catalytic Performance ◽  
Scr Catalysts ◽  
Selective Reduction Of Nox ◽  
Reduction Of Nox ◽  
Co Precipitation ◽  
Catalytic Performances

The nano-Co/Ce-V-Zr-TiO2 catalysts with the selective catalytic reduction (SCR) were prepared by methods of Sol-gel, impregnation (IM) and co-precipitation (CP). The phase compositions, microstructures and specific surface area of the catalysts were analyzed by BET, XRD and SEM, respectively. The effect of CeO2, CoO, V2O5 and V2O5 loading and reaction temperature on the catalytic performances of the as-prepared catalysts was investigated by using the selective reduction of NOx with NH3. The results showed all the as-prepared Co/Ce-V-Zr-TiO2 catalysts were made up of nanometer grains. Compared to conventional TiO2 catalysts, the as-prepared Co/Ce-V-Zr-TiO2 catalysts possessed better catalytic performance, higher adsorbability and larger area of contact with reactant, which is due to large quantity surface micropores. The NOx conversion of SCR over 8 wt%Co/Ce-V-Zr-TiO2 catalysts reached 98.3% at the reaction temperature of 550 oC. Furthermore, the activity of Co/Ce-V-Zr-TiO2 catalysts were improved by the Co loading, however, further increasing the Co loading lead to decrease the catalysis activity.

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