scholarly journals Influence of Temperature on the Performance of LiNi1/3Co1/3Mn1/3O2 Prepared by High-Temperature Ball-Milling Method

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Ming Tian ◽  
Xuetian Li ◽  
Zhongbao Shao ◽  
Fengman Shen
Keyword(s):  
High Temperature ◽  
Electrochemical Performance ◽  
Ball Milling ◽  
Raw Materials ◽  
Retention Rate ◽  
Lithium Ion ◽  
Lithium Carbonate ◽  
Milling Process ◽  
Milling Method ◽  
Milling Temperature

Aiming at the preparation of high electrochemical performance LiNi1/3Co1/3Mn1/3O2 cathode material for lithium-ion battery, LiNi1/3Co1/3Mn1/3O2 was prepared with lithium carbonate, nickel (II) oxide, cobalt (II, III) oxide, and manganese dioxide as raw materials by high-temperature ball-milling method. Influence of ball-milling temperature was investigated in this work. It was shown that the fine LiNi1/3Co1/3Mn1/3O2 powder with high electrochemical performance can be produced by the high-temperature ball-milling process, and the optimal ball-milling temperature obtained in the current study was 750°C. Its initial discharge capacity was 146.0 mAhg−1 at the rate of 0.1 C, and over 50 cycles its capacity retention rate was 90.2%.

Facile synthesis of a novel Al-based composite as an anode for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (104) ◽  
pp. 85338-85343 ◽  
Author(s):  
Qing-Yu Li ◽  
Qi-Chang Pan ◽  
Guan-Hua Yang ◽  
Xi-Le Lin ◽  
Zhi-Xiong Yan ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Ball Milling ◽  
Anode Material ◽  
Lithium Ion ◽  
Facile Synthesis ◽  
Milling Method

The synthesis of a novel Al/MoS2/C composite with a facile ball milling method can improve the electrochemical performance significantly as an anode material for lithium-ion batteries.

Influence of Ball Milling Process on the Pinned Effect of Al2O3/Al Cermet Composite Powder

2018 ◽  
Vol 777 ◽  
pp. 80-84
Author(s):  
Jie Guang Song ◽  
Yue Liu ◽  
Long He ◽  
Jin Shi Li ◽  
Wang Chen ◽  
...  
Keyword(s):  
Ball Milling ◽  
High Performance ◽  
Milling Time ◽  
Raw Materials ◽  
Milling Process ◽  
Composite Powders ◽  
Rotating Speed ◽  
Milling Method ◽  
Cermet Materials ◽  
Ball Milling Time

The Al2O3/Al cermet composite powders were prepared via the ball milling method,which provide raw materials for preparing high performance cermet materials. The results show that the number of Al2O3 particles on the surface of Al particles increases first and then decreases with increasing the ball milling time and milling rotating speed. The number of Al2O3 particles on the surface of Al particles increases with increasing ball to powder mass ratio. The analysis of the ratio of performance to price shows that the better parameters for preparing the pinned Al2O3/Al cermet composite powders are as follows, the ball milling time 24h,the ball milling rotating speed 100 r/min and the ratio of ball to powder 1:2.

Scalable synthesis of silicon nanoplate-decorated graphite toward advanced lithium-ion battery anodes

Nanoscale ◽  
2021 ◽  
Author(s):  
Haimei Li ◽  
Xianglong Li ◽  
Denghui Wang ◽  
Siyuan Zhang ◽  
Wenqiang Xu ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Ball Milling ◽  
Lithium Battery ◽  
High Capacity ◽  
Lithium Ion ◽  
Milling Process ◽  
Cyclic Stability ◽  
Graphite Electrodes ◽  
Ball Milling Process ◽  
Scalable Synthesis

A silicon nanoplate-decorated graphite design is developed for lithium battery anodes via a simple ball milling process. The resultant silicon-graphite electrodes show high cyclic stability with high capacity, superior rate...

Probing the Effect of High Energy Ball Milling on the Structure and Properties of LiNi1/3Mn1/3Co1/3O2 Cathodes for Li-Ion Batteries

2016 ◽  
Vol 13 (3) ◽  
Author(s):  
Malcolm Stein ◽  
Chien-Fan Chen ◽  
Matthew Mullings ◽  
David Jaime ◽  
Audrey Zaleski ◽  
...  
Keyword(s):  
Particle Size ◽  
Electrochemical Performance ◽  
Crystallite Size ◽  
Ball Milling ◽  
Lithium Ion ◽  
High Energy ◽  
Li Ion Batteries ◽  
Structure And Properties ◽  
Transfer Resistance ◽  
Li Ion

Particle size plays an important role in the electrochemical performance of cathodes for lithium-ion (Li-ion) batteries. High energy planetary ball milling of LiNi1/3Mn1/3Co1/3O2 (NMC) cathode materials was investigated as a route to reduce the particle size and improve the electrochemical performance. The effect of ball milling times, milling speeds, and composition on the structure and properties of NMC cathodes was determined. X-ray diffraction analysis showed that ball milling decreased primary particle (crystallite) size by up to 29%, and the crystallite size was correlated with the milling time and milling speed. Using relatively mild milling conditions that provided an intermediate crystallite size, cathodes with higher capacities, improved rate capabilities, and improved capacity retention were obtained within 14 μm-thick electrode configurations. High milling speeds and long milling times not only resulted in smaller crystallite sizes but also lowered electrochemical performance. Beyond reduction in crystallite size, ball milling was found to increase the interfacial charge transfer resistance, lower the electrical conductivity, and produce aggregates that influenced performance. Computations support that electrolyte diffusivity within the cathode and film thickness play a significant role in the electrode performance. This study shows that cathodes with improved performance are obtained through use of mild ball milling conditions and appropriately designed electrodes that optimize the multiple transport phenomena involved in electrochemical charge storage materials.

Electrochemical performance and electronic properties of shell LiNi0.5Mn1.5O4 hollow spheres for lithium ion battery

2016 ◽  
Vol 09 (02) ◽  
pp. 1650027 ◽  
Author(s):  
Yongli Cui ◽  
Jiali Wang ◽  
Mingzhen Wang ◽  
Quanchao Zhuang
Keyword(s):  
Activation Energy ◽  
Electrochemical Performance ◽  
Electronic Properties ◽  
Lithium Ion Battery ◽  
Retention Rate ◽  
Hollow Spheres ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Hollow Microspheres ◽  
Cycle Stability

Shell spinel LiNi[Formula: see text]Mn[Formula: see text]O4 hollow microspheres were successfully synthesized by MnCO3 template, and characterized by XRD, SEM, and TEM. The results show that the hollow LiNi[Formula: see text]Mn[Formula: see text]O4 cathode has good cycle stability to reach 124.5, 119.8, and 96.6[Formula: see text]mAh/g at 0.5, 1, and 5 C, the corresponding retention rate of 98.1%, 98.2%, and 98.0% after 50 cycles at 20[Formula: see text]C, and the reversible capacity of 94.6[Formula: see text]mAh/g can be obtained at 1 C rate at 55[Formula: see text]C, 83.3% retention after 100 cycles. As the temperature decreases from 10[Formula: see text]C to [Formula: see text]C, the resistance of [Formula: see text] increases from 5.5 [Formula: see text] to 135 [Formula: see text], [Formula: see text] from 27 [Formula: see text] to 353.2 [Formula: see text], and [Formula: see text] from 12.7 [Formula: see text] to 73.0 [Formula: see text]. Moreover, the B constant and [Formula: see text] activation energy are 4480[Formula: see text]K and 37.22[Formula: see text]KJ/mol for the NTC spinel material, respectively.

The Preparation and Properties of Clay Bonded Silicon Carbide by Using Silicon Carbide Dusting Powder

2018 ◽  
Vol 922 ◽  
pp. 143-148 ◽  
Author(s):  
Shao Chun Xu ◽  
Zi Jing Wang ◽  
Ya Ming Zhang ◽  
Qiang Zhi ◽  
Xu Dong Wang ◽  
...  
Keyword(s):  
Silicon Carbide ◽  
Ball Milling ◽  
Bending Strength ◽  
Sintering Temperature ◽  
Raw Materials ◽  
Clay Content ◽  
Good Method ◽  
Sintering Additive ◽  
Carbide Refractory ◽  
Milling Method

In this paper, clay bonded silicon carbide was prepared through pressureless sintering process with silicon carbide dusting powder as raw materials and clay as sintering additive. The effects of the ball-milling method, sintering temperature and clay contents on the density, microstructure and mechanical properties of clay bonded silicon carbide refractory were studied. The planetary ball-milling was a good method to improve the density of the green body, and the density was increased simultaneously with an increase of the clay content. The liquid phase derived from low-melting eutectic mixtures of clay could prevent the superlative oxidation of silicon carbide. The mass increment of sintered samples decreased firstly and then increased at the sintering temperature range from 1250 to 1500 °C. The open porosity of samples decreased with the clay addition at a content range from 10 to 30 wt.%. The bending strength of the samples decreased firstly and then increased with the clay addition increasing. The optimum condition for preparing clay bonded silicon carbide with silicon carbide dusting powder was sintering at 1350 °C with 20 wt.% clay, and the obtained sample with a porosity of 24% achieved the bending strength of 78±7 MPa.

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