scholarly journals Hybrid Monolith of Graphene/TEMPO-Oxidized Cellulose Nanofiber as Mechanically Robust, Highly Functional, and Recyclable Adsorbent of Methylene Blue Dye

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Asif Hussain ◽  
Jiebing Li ◽  
Jun Wang ◽  
Fei Xue ◽  
Yundan Chen ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Specific Surface ◽  
Charge Density ◽  
Surface Charge ◽  
Surface Area ◽  
Specific Surface Area ◽  
Surface Charge Density ◽  
Cellulose Nanofibers ◽  
Maximum Adsorption Capacity ◽  
Assembly Method

Herein we demonstrate first report on fabrication, characterization, and adsorptive appraisal of graphene/cellulose nanofibers (GO/CNFs) monolith for methylene blue (MB) dye. Series of hybrid monolith (GO/CNFs) were assembled via urea assisted self-assembly method. Hybrid materials were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction patterns, Raman spectroscopy, elemental analysis, thermogravimetric curve analysis, specific surface area, surface charge density measurement, and compressional mechanical analysis. It was proposed that strong chemical interaction (mainly hydrogen bonding) was responsible for the formation of hybrid assembly. GO/CNFs monolith showed mechanically robust architecture with tunable pore structure and surface properties. GO/CNFs adsorbent could completely remove trace to moderate concentrations of MB dye and follow pseudo-second-order kinetics model. Adsorption isotherm behaviors were found in the following order: Langmuir isotherm > Freundlich isotherm > Temkin isotherm model. Maximum adsorption capacity of 227.27 mg g−1 was achieved which is much higher than reported graphene based monoliths and magnetic adsorbent. Incorporation of nanocellulose follows exponential relationship with dye uptake capacities. High surface charge density and specific surface area were main dye adsorptive mechanism. Regeneration and recycling efficiency was achieved up to four consecutive cycles with cost-effective recollection and zero recontamination of treated water.

scholarly journals Efficient Removal of Methylene Blue from Aqueous Solutions Using a High Specific Surface Area Porous Carbon Derived from Soybean Dreg

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1754
Author(s):  
Zhiwei Ying ◽  
Lu Huang ◽  
Lili Ji ◽  
He Li ◽  
Xinqi Liu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Methylene Blue ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
Carbon Material ◽  
High Specific Surface Area ◽  
Maximum Adsorption Capacity ◽  
X Ray

Porous carbon material with high specific surface area was prepared from soybean dreg by a simple and effective two-step method (high temperature pyrolysis and activation). The structural characteristics of the synthesized carbon were evaluated by Brunauer–Emmett–Teller (BET), N2 adsorption/desorption measurements/techniques, an elemental analyzer (EA), scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), an X-ray diffractometer (XRD), Raman spectroscopy (Raman), a Fourier transform infrared spectrometer (FTIR), and X-ray photoelectron spectroscopy (XPS). The specific surface area of SDB-6-K was 2786 m2 g−1, the pore volume was 2.316 cm3 g−1, and the average pore size was 3.326 nm. The high specific surface area and effective functional groups of carbon material promoted the adsorption of methylene blue. The maximum adsorption capacity of SDB-6-K to methylene blue was 2636 mg g−1 at 318 K. The adsorption kinetic and isotherm data were most suitable for pseudo-second-order and Langmuir equations. The results showed that the adsorbent had excellent adsorptive ability and had good practical application potential in the field of dye wastewater treatment in the future.

Synthesis of Novel Core-Shell Structured Hydroxyapatite/Meso-Silica for Removal of Methylene Blue from Aqueous Solutions

2012 ◽  
Vol 463-464 ◽  
pp. 543-547 ◽  
Author(s):  
Cheng Feng Li ◽  
Xiao Lu Ge ◽  
Shu Guang Liu ◽  
Fei Yu Liu
Keyword(s):  
Methylene Blue ◽  
Aqueous Solutions ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Low Cost ◽  
Nitrogen Adsorption ◽  
Precipitation Method ◽  
Core Shell ◽  
Adsorption Desorption

Core-shell structured hydroxyapatite (HA)/meso-silica was prepared and used as absorbance of methylene blue (MB). HA/meso-silica was synthesized in three steps: preparation of nano-sized HA by wet precipitation method, coating of dense silica and deposition of meso-silica shell on HA. As-received samples were characterized by Fourier transformed infare spectra, small angle X-ray diffraction, nitrogen adsorption-desorption isotherm and transmission electron microscopy. A wormhole framework mesostructure was found for HA/meso-silica. The specific surface area and pore volume were 128 m2•g-1 and 0.36 cm3•g-1, respectively. From the adsorption isotherm, HA/meso-silica with the great specific surface area exhibited a prominent adsorption capacity of MB (134.0 mg/g) in comparison with bare HA (0 mg/g). This study might shed light on surface modification of conventional low-cost adsorbents for removal of organic pollutants from aqueous solutions.

Bi2WO6 Nanoparticles Prepared by Combustion Synthesis with Different Fuels and their Photocatalytic Activity

2014 ◽  
Vol 604 ◽  
pp. 93-101
Author(s):  
Maris Kodols ◽  
Sabine Didrihsone ◽  
Janis Grabis
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Citric Acid ◽  
Ethylene Glycol ◽  
Specific Surface ◽  
Crystallite Size ◽  
Combustion Synthesis ◽  
Surface Area ◽  
Specific Surface Area ◽  
Solution Ph

The influence of glycine, glycerine, ethylene glycol and citric acid fuel and their ratio to NO3- on formation and dispersity of Bi2WO6 nanoparticles prepared by combustion synthesis has been studied. The pure crystalline Bi2WO6 with specific surface area 24,8 m2/g and crystallite size of 28 nm was obtained by using glycerine as fuel at its ratio to NO3- of 0,67. The photocatalytic activity of the prepared Bi2WO6 in degradation of methylene blue depended on its specific surface area of samples and solution pH.

scholarly journals Silkworm cocoon derived N, O-codoped hierarchical porous carbon with ultrahigh specific surface area for efficient capture of methylene blue with exceptionally high uptake: kinetics, isotherm, and thermodynamics

RSC Advances ◽  
2019 ◽  
Vol 9 (58) ◽  
pp. 33872-33882
Author(s):  
Genxing Zhu ◽  
Qi Liu ◽  
Fengyi Cao ◽  
Qi Qin ◽  
Mingli Jiao
Keyword(s):  
Methylene Blue ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
Uptake Kinetics ◽  
High Uptake ◽  
Hierarchical Porous Carbon ◽  
Hierarchical Porous ◽  
Silkworm Cocoon

Silkworm cocoon derived N, O-HPC (SBET = 2270.19 m2 g−1) was synthesized, and demonstrated exceptionally high uptake of MB (2104.29 mg g−1).

scholarly journals Preparation of phosphorus-doped boron nitride and its adsorption of heavy metals from flue gas

2020 ◽  
Vol 7 (8) ◽  
pp. 200079
Author(s):  
Yanlong Li ◽  
Hongxi Li ◽  
Rundong Li ◽  
Xin Su ◽  
Shengqiang Shen
Keyword(s):  
Heavy Metals ◽  
Boron Nitride ◽  
Specific Surface ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Specific Surface Area ◽  
Flue Gas ◽  
Maximum Adsorption Capacity ◽  
Addition Rate ◽  
Phosphorus Doped

Boron nitride, also known as white graphene, has attracted extensive attention in the fields of adsorption, catalysis and hydrogen storage due to its excellent chemical properties. In this study, a phosphorus-doped boron nitride (P-BN) material was successfully prepared using red phosphorus as a dopant for the preparation of porous boron nitride precursors. The phosphorus content in the P-BN was adjusted based on the addition rate of phosphorus. The specific surface area of P-BN first increased and then decreased with increasing addition rate of phosphorus. The maximum specific surface area was 837.8 m 2 g −1 when the phosphorus addition rate was 0.50. The P-BN prepared in the experiments was used as an adsorbent, and its adsorption capacity for heavy metals from flue gas was investigated. In particular, P-BN presented a stronger adsorption selectivity for zinc compared with other heavy metals, and its adsorption capacity for zinc was 5–38 times higher than for other heavy metals. The maximum adsorption capacity of P-BN for zinc and copper in a single heavy metal atmosphere was 69.45 and 53.80 mg g −1 , respectively.

Effect of Anatase/Rutile Phase Ratio on the Photodegradation of Methylene Blue under UV Irradiation

2020 ◽  
Vol 998 ◽  
pp. 78-83
Author(s):  
Yi Yi Zaw ◽  
Du Ang Dao Channei ◽  
Thotsaphon Threrujirapapong ◽  
Wilawan Khanitchaidecha ◽  
Auppatham Nakaruk
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Specific Surface ◽  
Band Gap ◽  
Surface Area ◽  
Calcination Temperature ◽  
Organic Compounds ◽  
Specific Surface Area ◽  
Uv Irradiation ◽  
Rutile Phase

Titanium dioxide (TiO2) is known as one of the widely used catalysts in photocatalysis process. Recently, the photocatalysis of TiO2 has been implied in water purification and treatment, particularly dyes and organic compounds degradations. Naturally, the TiO2 can be found in three phases including anatase, rutile and brookite; each phase has its own specific properties such as grain size, stability and band gap energy. In this work, the effect of calcination temperature on the structure, morphology and photocatalytic activity were investigated. The data suggested that the anatase/rutile ratio of TiO2 can be controlled through the calcination process. The phase transformation data strongly indicated the liner function between percentage of rutile phase and calcination temperature. The BET analysis provided the consistent data with XRD patterns by showing that the specific surface area was decreased by increasing calcination temperature. The photodegradation of methylene blue under UV irradiation proved that the mixed phase of anatase/rutile ratio at 78.5/21.5 provided the highest photocatalytic activity. The phase composition ratio can influence the nanoparticles properties including band gap, specific surface area and energy band structure. Therefore, the control of anatase/rutile ratio was an alternative to enhance the photocatalytic activity of TiO2 nanoparticles for dyes and organic compounds degradations.

scholarly journals Bio-polishing sludge adsorbents for dye removal

2016 ◽  
Vol 18 (4) ◽  
pp. 15-21 ◽  
Author(s):  
Muhammad Abbas Ahmad Zaini ◽  
Norulaina Alias ◽  
Mohd. Azizi Che Yunus
Keyword(s):  
Methylene Blue ◽  
Specific Surface ◽  
Surface Area ◽  
Functional Groups ◽  
Specific Surface Area ◽  
Treatment Strategies ◽  
Blue Dye ◽  
Surface Functional Groups ◽  
Adsorption Capacities ◽  
Maximum Removal

Abstract The objective of this work is to evaluate the removal of methylene blue dye by bio-polishing sludge-based adsorbents. The adsorbents were characterized according to the specific surface area, pH upon the treatment and surface functional groups. The adsorption of dye was carried out at room temperature, and the adsorption data were analyzed using the isotherm and kinetics models. The bio-polishing sludge is rich in ash content, and the presence of surface functional groups varied with the treatment strategies. The specific surface area of adsorbents is between 7.25 and 20.8 m2/g. Results show that the maximum removal of methylene blue by sludge adsorbents was observed to have the following order: untreated sludge (SR) > zinc chloride-treated (SZ) > microwave-dried (SW) = potassium carbonate-treated (SK) > acid-washed (SH). The maximum adsorption capacities for SR and SZ as predicted by the Langmuir model are 170 and 135 mg/g, respectively. Although SR demonstrates a higher maximum removal than SZ, the latter exhibits greater removal intensity and rate constant even at high dye concentration. The bio-polishing sludge is a promising adsorbent for dye wastewater treatment.

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