scholarly journals Stretchable and Hydrophobic Electrochromic Devices Using Wrinkled Graphene and PEDOT:PSS

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Srinivasa Kartik Nemani ◽  
Dayong Chen ◽  
Marwan H. Mohamed ◽  
Hossein Sojoudi
Keyword(s):  
Self Assembly ◽  
Graphene Film ◽  
Electrochromic Device ◽  
Color Contrast ◽  
Water Contact ◽  
Smart Windows ◽  
Wide Range ◽  
Average Water ◽  
Materials Used ◽  
New Generation

We present an electrochromic device (ECD) fabricated using PEDOT:PSS and graphene as active conductive electrode films and a flexible compliant polyurethane substrate with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-TSFI) additive, as ionic medium. This device with a docile, elastic intermediate substrate along with a transparency controlled PEDOT:PSS film provides a wide color contrast and fast switching rate. We harness wrinkling instability of graphene to achieve a hydrophobic nature without compromising transparency of the ECD. This mechanical self-assembly approach helps in controlling the wavelength of wrinkles generated by inducing measured prestrain conditions and regulating the modulus contrast by selection of underlying materials used, hereby controlling the extent of transparency. The reduction and oxidation switching times for the device were analyzed to be 5.76 s and 5.34 s for a 90% transmittance change at an operating DC voltage of 15 ± 0.1 V. Strain dependent studies show that the performance was robust with the device retaining switching contrasts even at 15% uniaxial strain conditions. Our device also exhibits superior antiwetting properties with an average water contact angle of 110°  ± 2° at an induced radial prestrain of 30% in the graphene film. A wide range color contrast, flexibility, and antiwetting nature of the device envision its uses in smart windows, visors, and other wearable equipment where these functionalities are of outmost importance for developing new generation of smart interactive devices.

scholarly journals Design of functionalised circular tandem repeat proteins with longer repeat topologies and enhanced subunit contact surfaces

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Jazmine P. Hallinan ◽  
Lindsey A. Doyle ◽  
Betty W. Shen ◽  
Mesfin M. Gewe ◽  
Brittany Takushi ◽  
...  
Keyword(s):  
Tandem Repeat ◽  
Self Assembly ◽  
De Novo ◽  
Viral Receptor ◽  
Viral Neutralization ◽  
Sh2 Domains ◽  
Repeat Proteins ◽  
Wide Range ◽  
Tandem Repeat Proteins ◽  
New Generation

AbstractCircular tandem repeat proteins (‘cTRPs’) are de novo designed protein scaffolds (in this and prior studies, based on antiparallel two-helix bundles) that contain repeated protein sequences and structural motifs and form closed circular structures. They can display significant stability and solubility, a wide range of sizes, and are useful as protein display particles for biotechnology applications. However, cTRPs also demonstrate inefficient self-assembly from smaller subunits. In this study, we describe a new generation of cTRPs, with longer repeats and increased interaction surfaces, which enhanced the self-assembly of two significantly different sizes of homotrimeric constructs. Finally, we demonstrated functionalization of these constructs with (1) a hexameric array of peptide-binding SH2 domains, and (2) a trimeric array of anti-SARS CoV-2 VHH domains. The latter proved capable of sub-nanomolar binding affinities towards the viral receptor binding domain and potent viral neutralization function.

scholarly journals Convective meniscus splitting of polysaccharide microparticles on various surfaces

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kosuke Okeyoshi ◽  
Miki Yamashita ◽  
Kulisara Budpud ◽  
Gargi Joshi ◽  
Tatsuo Kaneko
Keyword(s):  
Self Assembly ◽  
Xanthan Gum ◽  
Gravitational Force ◽  
Splitting Method ◽  
Universal Method ◽  
Water Contact ◽  
Uniaxial Orientation ◽  
Wide Range ◽  
New Strategy ◽  
Polymeric Structures

AbstractIn contrast to convective self-assembly methods for colloidal crystals etc., “convective meniscus splitting method” was developed to fabricate three-dimensionally ordered polymeric structures. By controlling the geometry of evaporative interface of polymer solution, a deposited membrane with uniaxial orientation and layered structures can be prepared. Here it is demonstrated that xanthan gum polysaccharide microparticles with diameter ~ 1 µm can bridge a millimeter-scale gap to form such a membrane because the capillary force among the particles is more dominant than the gravitational force on the evaporative interface. This method is applicable for various substrates with a wide range of wettability (water contact angle, 11°–111°), such as glass, metals, and plastics. The specific deposition can be also confirmed between frosted glasses, functional-molecules-modified glasses, and gold-sputtered substrates. By using such a universal method, the membrane formed on a polydimethylsiloxane surface using this method will provide a new strategy to design a functional polysaccharide wall in microfluidic devices, such as mass-separators.

scholarly journals A Planar Electrochromic Device using WO3 Nanoparticles and a Modified Paper-Based Electrolyte

Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 1065 ◽  
Author(s):  
Ana Marques ◽  
Lídia Santos ◽  
Sónia Pereira ◽  
Umberto Emanuele ◽  
Stefano Sinopoli ◽  
...  
Keyword(s):  
Solution Process ◽  
Cost Effective ◽  
Electrochromic Device ◽  
Blue Color ◽  
Smart Windows ◽  
Deep Blue ◽  
Wide Range ◽  
Initial Charge ◽  
Production Technologies ◽  
Easy Integration

Electrochromic devices are increasing its interest in the last decades due to the wide range of applications, from smart windows to biosensors or from smart labels to super-capacitors. So, the development of simple and cost-effective production technologies based on solution process and mask less approach is of great interest. In this work, a new planar and flexible electrochromic device based on tungsten oxide (WO3) nanoparticles with a paper-based modified electrolyte was successfully produced, using a CO2 laser technology for electrodes patterning and hydrothermal synthesis for the nanoparticles production. The devices were fabricated with a paper pad inserted in the sensor area for hydration on time of usage, thus replacing the electrolyte material of a typical electrochromic structure with a multi-layer stack, eliminating leakage problems, easy integration with other devices and enhancing the shelf life of the devices to several months. The produced device presents a low power consumption of only 2.86 μA·cm−2, with a deep blue color and an initial charge modulation of 11.5.

scholarly journals Naturally Self-Assembled Nanosystems and Their Templated Structures for Photonic Applications

2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
K. Pradeesh ◽  
Nageswara Rao Kotla ◽  
Shahab Ahmad ◽  
Vindesh K. Dwivedi ◽  
G. Vijaya Prakash
Keyword(s):  
Self Assembly ◽  
Molecular Level ◽  
Low Cost ◽  
Interstitial Space ◽  
Structural Flexibility ◽  
Space Filling ◽  
Wide Range ◽  
Self Assembled ◽  
New Generation ◽  
Self Aggregation

Self-assembly has the advantage of fabricating structures of complex functionalities, from molecular levels to as big as macroscopic levels. Natural self-assembly involves self-aggregation of one or more materials (organic and/or inorganic) into desired structures while templated self-assembly involves interstitial space filling of diverse nature entities into self-assembled ordered/disordered templates (both from molecular to macro levels). These artificial and engineered new-generation materials offer many advantages over their individual counterparts. This paper reviews and explores the advantages of such naturally self-assembled hybrid molecular level systems and template-assisted macro-/microstructures targeting simple and low-cost device-oriented fabrication techniques, structural flexibility, and a wide range of photonic applications.

Factors Affecting Molecular Self-Assembly and Its Mechanism

2012 ◽  
Vol 9 (1) ◽  
pp. 43 ◽  
Author(s):  
Hueyling Tan
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Molecular Engineering ◽  
Molecular Structures ◽  
Polymer Science ◽  
New Approach ◽  
Factors Affecting ◽  
Dna Structures ◽  
Self Assembling ◽  
Wide Range

Molecular self-assembly is ubiquitous in nature and has emerged as a new approach to produce new materials in chemistry, engineering, nanotechnology, polymer science and materials. Molecular self-assembly has been attracting increasing interest from the scientific community in recent years due to its importance in understanding biology and a variety of diseases at the molecular level. In the last few years, considerable advances have been made in the use ofpeptides as building blocks to produce biological materials for wide range of applications, including fabricating novel supra-molecular structures and scaffolding for tissue repair. The study ofbiological self-assembly systems represents a significant advancement in molecular engineering and is a rapidly growing scientific and engineering field that crosses the boundaries ofexisting disciplines. Many self-assembling systems are rangefrom bi- andtri-block copolymers to DNA structures as well as simple and complex proteins andpeptides. The ultimate goal is to harness molecular self-assembly such that design andcontrol ofbottom-up processes is achieved thereby enabling exploitation of structures developed at the meso- and macro-scopic scale for the purposes oflife and non-life science applications. Such aspirations can be achievedthrough understanding thefundamental principles behind the selforganisation and self-synthesis processes exhibited by biological systems.

Materials for bullet core

2020 ◽  
Vol 2020 (10) ◽  
pp. 8-21
Author(s):  
A. G. Kolmakov ◽  
◽  
I. O. Bannykh ◽  
V. I. Antipov ◽  
L. V. Vinogradov ◽  
...  
Keyword(s):  
High Speed ◽  
Bending Strength ◽  
Low Alloy Steels ◽  
Hard Alloys ◽  
Small Arms ◽  
Alloy Steels ◽  
Materials Used ◽  
Basic Ideas ◽  
New Generation ◽  
Natural Composite

he basic ideas about the process of introducing cores into protective barriers and the most common core patterns and their location in conventional and sub-caliber small arms bullets are discussed. The materials used for manufacture of cores are analyzed. It is concluded that for mass bullets of increased armor penetration the most rational choice can be considered the use of high-carbon low-alloy steels of a new generation with a natural composite structure and hardness of up to 70 HRC. For specialized armor-piercing bullets, cores made from promising economically-alloyed high-speed steels characterized by a high complex of «hardness—bending strength» are better alternative than ones made of hard alloys or tungsten alloys.

scholarly journals Bio-Based Alternatives to Phenol and Formaldehyde for the Production of Resins

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim
Keyword(s):  
Raw Materials ◽  
Phenol Formaldehyde ◽  
Raw Material ◽  
Wood Industry ◽  
Suitable Material ◽  
The Past ◽  
Wide Range ◽  
Recent Developments ◽  
Sustainable Materials ◽  
Materials Used

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.

scholarly journals The Impact of Initial Conditions in N-Body Simulations of Debris Discs

2015 ◽  
Vol 32 ◽  
Author(s):  
E. Thilliez ◽  
S. T. Maddison
Keyword(s):  
Numerical Simulations ◽  
Initial Conditions ◽  
Parent Body ◽  
Dust Trapping ◽  
Physical Context ◽  
Disc Width ◽  
Wide Range ◽  
Belt Width ◽  
New Generation ◽  
The Impact

AbstractNumerical simulations are a crucial tool to understand the relationship between debris discs and planetary companions. As debris disc observations are now reaching unprecedented levels of precision over a wide range of wavelengths, an appropriate level of accuracy and consistency is required in numerical simulations to confidently interpret this new generation of observations. However, simulations throughout the literature have been conducted with various initial conditions often with little or no justification. In this paper, we aim to study the dependence on the initial conditions of N-body simulations modelling the interaction between a massive and eccentric planet on an exterior debris disc. To achieve this, we first classify three broad approaches used in the literature and provide some physical context for when each category should be used. We then run a series of N-body simulations, that include radiation forces acting on small grains, with varying initial conditions across the three categories. We test the influence of the initial parent body belt width, eccentricity, and alignment with the planet on the resulting debris disc structure and compare the final peak emission location, disc width and offset of synthetic disc images produced with a radiative transfer code. We also track the evolution of the forced eccentricity of the dust grains induced by the planet, as well as resonance dust trapping. We find that an initially broad parent body belt always results in a broader debris disc than an initially narrow parent body belt. While simulations with a parent body belt with low initial eccentricity (e ~ 0) and high initial eccentricity (0 < e < 0.3) resulted in similar broad discs, we find that purely secular forced initial conditions, where the initial disc eccentricity is set to the forced value and the disc is aligned with the planet, always result in a narrower disc. We conclude that broad debris discs can be modelled by using either a dynamically cold or dynamically warm parent belt, while in contrast eccentric narrow debris rings are reproduced using a secularly forced parent body belt.

scholarly journals Polymer cyclization for the emergence of hierarchical nanostructures

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chaojian Chen ◽  
Manjesh Kumar Singh ◽  
Katrin Wunderlich ◽  
Sean Harvey ◽  
Colette J. Whitfield ◽  
...  
Keyword(s):  
Self Assembly ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Structural Similarity ◽  
Vital Role ◽  
Nanomaterial Synthesis ◽  
Wide Range ◽  
Linear Poly ◽  
Polymer Folding ◽  
Dynamics Simulations

AbstractThe creation of synthetic polymer nanoobjects with well-defined hierarchical structures is important for a wide range of applications such as nanomaterial synthesis, catalysis, and therapeutics. Inspired by the programmability and precise three-dimensional architectures of biomolecules, here we demonstrate the strategy of fabricating controlled hierarchical structures through self-assembly of folded synthetic polymers. Linear poly(2-hydroxyethyl methacrylate) of different lengths are folded into cyclic polymers and their self-assembly into hierarchical structures is elucidated by various experimental techniques and molecular dynamics simulations. Based on their structural similarity, macrocyclic brush polymers with amphiphilic block side chains are synthesized, which can self-assemble into wormlike and higher-ordered structures. Our work points out the vital role of polymer folding in macromolecular self-assembly and establishes a versatile approach for constructing biomimetic hierarchical assemblies.

scholarly journals Review of Functional Treatments for Modified Wood

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 327
Author(s):  
Morwenna J. Spear ◽  
Simon F. Curling ◽  
Athanasios Dimitriou ◽  
Graham A. Ormondroyd
Keyword(s):  
High Performance ◽  
Responsive Materials ◽  
Wood Modification ◽  
Wide Range ◽  
Natural Wood ◽  
Impregnation Modification ◽  
New Applications ◽  
New Generation ◽  
Dimensional Instability ◽  
Modified Wood

Wood modification is now widely recognized as offering enhanced properties of wood and overcoming issues such as dimensional instability and biodegradability which affect natural wood. Typical wood modification systems use chemical modification, impregnation modification or thermal modification, and these vary in the properties achieved. As control and understanding of the wood modification systems has progressed, further opportunities have arisen to add extra functionalities to the modified wood. These include UV stabilisation, fire retardancy, or enhanced suitability for paints and coatings. Thus, wood may become a multi-functional material through a series of modifications, treatments or reactions, to create a high-performance material with previously impossible properties. In this paper we review systems that combine the well-established wood modification procedures with secondary techniques or modifications to deliver emerging technologies with multi-functionality. The new applications targeted using this additional functionality are diverse and range from increased electrical conductivity, creation of sensors or responsive materials, improvement of wellbeing in the built environment, and enhanced fire and flame protection. We identified two parallel and connected themes: (1) the functionalisation of modified timber and (2) the modification of timber to provide (multi)-functionality. A wide range of nanotechnology concepts have been harnessed by this new generation of wood modifications and wood treatments. As this field is rapidly expanding, we also include within the review trends from current research in order to gauge the state of the art, and likely direction of travel of the industry.

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