scholarly journals Comparative Study on the Performance of Blended and Nonblended Fly Ash Geopolymer Composites as Durable Construction Materials

2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Debabrata Dutta ◽  
Somnath Ghosh
Keyword(s):  
Fly Ash ◽  
Magnesium Sulfate ◽  
Silica Fume ◽  
Construction Materials ◽  
Sodium Silicate Solution ◽  
Sulfate Solution ◽  
Significant Drop ◽  
One Year ◽  
Magnesium Sulfate Solution ◽  
Geopolymer Paste

This article represents that the mechanical and microstructural properties and durability of fly ash-based geopolymers blended with silica fume and borax are better than those of conventional fly ash-based geopolymers. Fly ash itself contains the sources of silica and alumina which are required for geopolymerisation. But a sufficient amount of high-reactive silica is able to rapidly initiate geopolymerisation with activation. Pure potassium hydroxide pellets and sodium silicate solution were used for preparation of alkaline activator solution. Fly ash geopolymer paste exhibited better mechanical properties in the presence of silica fume with slight portion of borax. The effect of silica fume-blended geopolymer paste on temperature fluctuation (heating and cooling cycle at certain temperatures) showed better performance than nonblended fly ash-based specimens. Durability property was evaluated by immersion of geopolymer specimens in 10% magnesium sulfate solution for a period of one year. The change in weight, strength, and microstructure was studied and compared. In the magnesium sulfate solution, a significant drop of strength to around 37.26% occurred after one year for nonblended fly ash-based specimens. It is evident that specimens prepared incorporating silica fume had the best performance in terms of their properties.

Mechanical Properties of Mortars Prepared by Alkali Activated Fly Ash Coming from Different Production Batches

2015 ◽  
Vol 244 ◽  
pp. 140-145 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Construction Materials ◽  
Chemical Properties ◽  
Raw Material ◽  
Fly Ashes ◽  
Coal Burning ◽  
Alkali Solutions ◽  
One Year ◽  
Alkali Activated

Fly ash is a well utilizable secondary raw material for the production of alkali activated construction materials. It is a significant alumina-silicates source suitable for the chemical reaction resulting in hardened composites. Physical and chemical properties of fly ashes as a co-product of coal burning mainly depend on characteristics of coal, burning temperature and combustion conditions. High variability of the properties of fly ash causes an uncertainty in the properties of alkali activated mortars. Time behaviour of the composition of the fly ash produced in a heating plant located in Košice, Slovakia as well as leaching behaviour of both alumina and silica from particular batches during one-year period was documented. Leaching tests were carried out using the distilled water and alkali solutions with three different concentrations. Both compressive and tensile strengths of alkali activated mortars were measured, and the correlation between the mechanical properties of hardened mortars and the chemical composition of fly ashes as well as their leaching characteristics was investigated.

scholarly journals Importance of Cation Species during Sulfate Resistance Tests for Alkali-Activated FA/GGBFS Blended Mortars

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3547
Author(s):  
Youngkeun Cho ◽  
Joo Hyung Kim ◽  
Sanghwa Jung ◽  
Yoonseok Chung ◽  
Yeonung Jeong
Keyword(s):  
Compressive Strength ◽  
Magnesium Sulfate ◽  
Sulfate Solution ◽  
Magnesium Ions ◽  
Sulfate Resistance ◽  
Granulated Blast Furnace Slag ◽  
Significant Difference ◽  
Furnace Slag ◽  
Alkali Activated ◽  
Magnesium Sulfate Solution

In this study, the changes in mass, compressive strength, and length of blended mortars were analyzed to investigate their sulfate resistance according to the ground granulated blast furnace slag (GGBFS) blending ratio and type of sulfate solution applied. All alkali-activated mortars showed an excellent sulfate resistance when immersed in a sodium sulfate (Na2SO4) solution. However, when immersed in a magnesium sulfate (MgSO4) solution, different sulfate resistance results were obtained depending on the presence of GGBFS. The alkali-activated GGBFS blended mortars showed a tendency to increase in mass and length and decrease in compressive strength when immersed in a magnesium sulfate solution, whereas the alkali-activated FA mortars did not show any significant difference depending on the types of sulfate solution applied. The deterioration of alkali-activated GGBFS blended mortars in the immersion of a magnesium sulfate solution was confirmed through the decomposition of C–S–H, which is the reaction product from magnesium ions, and the formation of gypsum (CaSO4·2H2O) and brucite (Mg(OH)2).

Shrinkage of Blended Cement Pastes with Mineral Additions

2013 ◽  
Vol 539 ◽  
pp. 55-59
Author(s):  
Yi Chen ◽  
Wu Yao ◽  
Dan Jin
Keyword(s):  
Fly Ash ◽  
Silica Fume ◽  
Cement Paste ◽  
Mercury Intrusion Porosimetry ◽  
Construction Materials ◽  
Blended Cement ◽  
Cement Pastes ◽  
Mercury Intrusion ◽  
Mineral Additions ◽  
By Products

Mineral additions such as fly ash and silica fume are industrial by products, and play an important role in properties improvement for construction materials. In this work, the shrinkage of cement paste blended with fly ash and silica fume by different substitute ratio was studied. Pore structures of specimens at different ages were determined by mercury intrusion porosimetry (MIP) and shrinkage deformation was measured by standard shrinkage tests. The effects of mineral addtions on shrinkage were discussed. The results show that the fly ash was significantly effective on shrinkage at early ages. Based on the research, several suitable advices were offered to optimize the performances of materials and reduce the shrinkage.

scholarly journals Strength of Geopolymer Paste using a Ternary Blend of Fly Ash Ggbfs and Silica Fume under Ambient Conditions

2019 ◽  
Vol 8 (11) ◽  
pp. 3784-3790
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Adverse Effects ◽  
Silica Fume ◽  
Ternary Blend ◽  
Ambient Conditions ◽  
Solid Ratio ◽  
Mix Proportioning ◽  
Geopolymer Paste

In this paper, compressive strength (CS) of geopolymer paste has been studied under ambient conditions using locally available Class C fly ash, GGBFS and silica fume and a combination alkali activator, namely: NaOH and Na2SiO3 . Two approaches were used for mix proportioning and 60 mixes of the paste were proportioned. It is found that all the mixes proportioned were workable and no adverse effects were observed within 30 minutes of mixing. It is found that the ‘minimum voids’ approach along with a constant fly ash – to – activator ratio (FA/AA) is the best approach for the design of geopolymer mixes, rather than a constant water- to- solid ratio (w/s). Further, the role of GGBFS and SF on the CS of the paste has also been highlighted.

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