scholarly journals Effect of Grain Size on the Stress Corrosion Cracking of Ultrafine Grained Cu-10 wt% Zn Alloy in Ammonia

2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Takuma Asabe ◽  
Muhammad Rifai ◽  
Motohiro Yuasa ◽  
Hiroyuki Miyamoto

The effect of grain size in the micron to submicron range on the stress corrosion cracking (SCC) of Cu-10 wt% Zn alloys was investigated using constant-load tests in ammonia vapor. The grain size was systematically varied from 4 μm to 0.12 μm by either cold-rolling or equal-channel angular pressing (ECAP), followed by annealing. The time to fracture increased with decreasing grain size above 1 μm but then began to decrease with decreasing grain size into the submicron range. This inverse trend in the submicron range is discussed in terms of a severe plastic deformation- (SPD-) induced ultrafine grain microstructure.

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Lin Chen ◽  
Huisheng Yang ◽  
Yanjing Su ◽  
Lijie Qiao

Purpose The purpose of this study is to develop the existence and mechanism of stress corrosion cracking (SCC) for A517 steel in marine environments. Design/methodology/approach Slow strain rate test (SSRT) and constant load tests were used to investigate the SCC susceptibility of A517 steel. In addition, the additive stresses caused by the corrosion film and hydrogen entering into steel were applied to reveal the fundamental mechanism of the SCC. Findings The SCC susceptibility increased due to anodic dissolution and additive stress caused by the corrosion-produced film under anode polarization. Furthermore, the SCC susceptibility increased with increasing cathodic polarization, which is due to the increased additional stress caused by hydrogen entering into the steel. However, when the cathode polarization further increased, the additional stress remained due to the constant hydrogen content, thus the SCC susceptibility did not vary. Moreover, the SCC susceptibility of A517 steel under an alternate immersion environment (AIE) was lower than that under a full immersion environment and the steel under the AIE with 0.5 W/D had the lowest SCC susceptibility. Originality/value The stress corrosion behaviors of A517 in marine environments under various conditions were systematically analyzed.


Metals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 824 ◽  
Author(s):  
Qingjuan Wang ◽  
Dan Liu ◽  
Libo Tong ◽  
Ying Zhou ◽  
Wei Wang ◽  
...  

The microstructure evolution and stress corrosion cracking (SCC) behaviors of ultrafine-grained (UFG) Cu-Cr-Zr alloys processed by equal-channel angular pressing (ECAP) and coarse-grain (CG) Cu-Cr-Zr alloys within NaNO2 solution were systematically investigated in the current study. After deformation by eight ECAP passes, the grain size was refined to ~200 nm. The slow strain rate tensile (SSRT) tests showed that the ultimate tensile strength (UTS) of CG samples in solution was slightly lower than that in the air, and the elongation was decreased from 57.3% to 52.6%. In contrast, both the UTS and elongation of UFG samples in air and solution were almost identical. In NaNO2 solution, the CG fracture surface showed an obvious dissolution, microvoids, and minor cracks, while the surface of the UFG fracture was relatively smooth. The resistance of UFG samples to SCC could be significantly enhanced compared with CG samples. The grain boundary volume fraction of UFG alloy was dramatically increased, which reduced the formation of pitting corrosion. In addition, the uniform distribution of Cr particles also improved the corrosion resistance of UFG alloys.


CORROSION ◽  
2004 ◽  
Vol 60 (3) ◽  
pp. 229-236 ◽  
Author(s):  
M. Yamamoto ◽  
J. Kuniya ◽  
S. Uchida

Abstract Uniaxial constant load (UCL) tests of the nickel-based alloy X750 (UNS N07550) were performed in high-temperature pure water (288°C, 8 ppm dissolved oxygen [DO]) to investigate stress corrosion cracking (SCC) fracture time and the crack initiation process. The SCC fracture was initiated at a stress level below the 0.2% offset yield stress and many small cracks were observed in the middle of the nonfractured test specimens. The distribution of the crack length for each observation time is shown by Weibull probability distributions. Crack initiation and propagation process had different behavior depending on the applied stress level and the stress intensity factor at the crack tip. SCC initiation at the minimum applied stress is discussed with respect to the grain size, which depended on the size of an initial crack.


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