scholarly journals Physicochemical and Luminescent Properties of Copolymers Composed of Three Monomers: Polythiophenes Based on 3-Hexylthiophene and 3,4-Ethylenedioxythiophene

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Marco Antonio Ramírez-Gómez ◽  
Karla Karina Guzmán-Rabadán ◽  
Edgar González-Juárez ◽  
Marisol Güizado-Rodríguez ◽  
Gabriel Ramos-Ortiz ◽  
...  
Keyword(s):  
Luminescent Properties ◽  
Oxidation Potential ◽  
Photon Absorption ◽  
High Electron ◽  
Excited State Lifetime ◽  
Two Photon Absorption ◽  
H Nmr ◽  
Two Photon ◽  
Ft Ir ◽  
Fluorescent Tags

The chemical synthesis and physicochemical and luminescent characterizations of polymers based on 3-HT, EDOT, and 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl) bisthiophene (fluorene) or (E)-2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethyl 2-(thiophen-3-yl)acetate (TDR1) are reported. The fluorene unit was bound to the conjugate backbone, while the Disperse Red 1 (DR1) chromophore was present as a pendant group. Characterizations by 1H NMR, FT-IR, DSC-TGA, GPC, UV-vis, cyclic voltammetry, fluorescence quantum yield, excited state lifetime, and two-photon absorption cross-section were carried out. These polymers combined the physicochemical properties of EDOT and 3-HT, such as high electron density, high charge mobility, low oxidation potential, and good processability. The optical properties of these copolymers were highly dependent on the presence of EDOT, the molecular weight, and the regioregularity rather than the presence of the third component (fluorene or TDR1). The good nonlinear absorption and luminescent properties exhibited by these copolymers were exploited to fabricate nanoparticles used as fluorescent tags for the imaging of microstructures.

Bisporphyrin connected by tetrathiafulvalene

2009 ◽  
Vol 13 (01) ◽  
pp. 114-121 ◽  
Author(s):  
Kazuya Ogawa ◽  
Yasunori Nagatsuka
Keyword(s):  
Cross Section ◽  
Density Functional ◽  
Polar Solvent ◽  
Soret Band ◽  
Oxidation Potential ◽  
Time Dependent ◽  
Photon Absorption ◽  
Functional Theory ◽  
Two Photon Absorption ◽  
Two Photon

A new porphyrintetrathiafulvalene composite, where two porphyrins are bridged by te trathiafulvalene (TTF) using acetylene bonds was synthesized. The Q-band of the monomeric porphyrin appears at 590 nm whereas that of the composite is red-shifted to 620 nm and intensified. The Soret band is also red-shifted from 427 nm to 435 nm and much broadened, indicating the expansion of π-conjugation over the porphyrin and tetrathiafulvalene units. The HOMOs and LUMOs were calculated using time-dependent density functional theory. Voltammetric experiments revealed that the first oxidation potential of the TTF moiety in the composite was shifted by +155 mV compa red with TTF in the absence of composite. The effective two-photon absorption (2PA) cross section values were measured by using a nanosecond open aperture Z-scan method. The maximum effective 2PA cross section values were obtained at 760 nm, as 7300 GM in benzonitrile and 5900 GM in toluene. The values obtained in the polar solvent were 1.2 to 1.5 times larger than those in the nonpolar solvent.

Synthesis, characterization, photophysical and DNA photocleavage properties of amphiphilic porphyrins

2014 ◽  
Vol 18 (03) ◽  
pp. 221-230 ◽  
Author(s):  
Jie Zhang ◽  
Mingyu Teng ◽  
Dan Li
Keyword(s):  
Cross Sections ◽  
Photophysical Properties ◽  
Photon Absorption ◽  
Quantum Yields ◽  
Two Photon Absorption ◽  
Pyridinium Cation ◽  
H Nmr ◽  
Two Photon ◽  
Porphyrin Derivatives ◽  
Tof Ms

A series of amphiphilic porphyrins appended with pyridinium cation and/or polyethylene glycol have been synthesized and fully characterized by 1 H NMR, IR and MALDI-TOF-MS. Their photophysical properties were determined and the singlet oxygen (1 O 2) quantum yields of these compounds are in the range of 0.30–0.61 in CHCl 3 and 0.048–0.18 in Tris buffer. The measured two-photon absorption (TPA) cross-sections σ(2) of these porphyrin derivatives are between 110 and 240 GM. These amphiphilic porphyrins show some photocleavage activities (10%–21%) towards the anionic DNA observed at 100 μM.

Synthesis and Physicochemical Characterization of New Polythiophenes Based on Three Different Monomers

2015 ◽  
Vol 1767 ◽  
pp. 57-62 ◽  
Author(s):  
Karla K. Guzmán-Rabadán ◽  
Marco A. Ramírez-Gómez ◽  
Marisol Güizado-Rodríguez ◽  
Jorge A. Guerrero-Álvarez ◽  
Víctor Barba ◽  
...  
Keyword(s):  
Organic Solar Cells ◽  
Electronic Devices ◽  
Physicochemical Characterization ◽  
Oxidation Potential ◽  
High Electron ◽  
High Electron Density ◽  
H Nmr ◽  
Ft Ir ◽  
Functional Membranes

ABSTRACTThe chemical synthesis of the copolymers poly(3-HT-co-EDOT-co-fluorene) and poly(3-HT-co-EDOT-co-TDR1) is reported. The first copolymer is derived of 3-hexylthiophene (3-HT), 3,4-ethylenedioxythiophene (EDOT) and 2,2'- (9,9-dioctyl-9H-fluorene-2,7-diyl) bisthiophene (fluorene). The second copolymer is derived of 3-hexylthiophene (3-HT), 3,4-ethylenedioxythiophene (EDOT) and (E)-2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethyl 2-(thiophen-3-yl)acetate (TDR1). Their physicochemical characterization by 1H NMR, FT-IR, DSC-TGA, GPC, UV-vis, cyclic voltammetry was carried out. These copolymers combine the high electron density and low oxidation potential of EDOT with the high charge mobility and processability of 3-HT. These are candidates for applications as active or barrier layer in electronic devices (bulk heterojuntion organic solar cells) or as functional membranes (e.g., sensors).

Broadband Excited State Dynamics of Common Reverse Saturable Absorbing Dye Media.

1994 ◽  
Vol 374 ◽  
Author(s):  
Kenneth J. McEwan ◽  
Richard C. Hollins
Keyword(s):  
Excited State ◽  
Organic Liquid ◽  
Excited State Absorption ◽  
Photon Absorption ◽  
Excited State Lifetime ◽  
Absorption And Emission ◽  
Two Photon Absorption ◽  
Two Photon ◽  
State Response ◽  
Photon Excitation

AbstractIn this paper we describe a technique by which the broadband excited state absorption/emission and dynamics can be measured for materials with either linear or two photon absorption. The technique is applied to two different dyes in solution and to a cyano-biphenyl organic liquid. The ratio of σex/σgr for HITCI in methanol is greater than 1 from 400 to 570nm and at 532nn is determined to be 25; the excited state lifetime is 800ps. For CAP in methanol σex/σgr is greater than 1 from 400–650nm and is 14 at 532nm. Dimer absorption and emission are found to contribute to the excited state response in this material. In the organic liquid broadband (400–570nm) excited state absorption is measured following two photon excitation at 588nm.

Second order interference in two photon absorption

1996 ◽  
Vol 43 (9) ◽  
pp. 1765-1771 ◽  
Author(s):  
M. W. HAMILTON and D. S. ELLIOTT
Keyword(s):  
Second Order ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon

Studies of Two Photon Absorption in Heavy Metal Oxide Based Glasses

2010 ◽  
Vol 25 (3) ◽  
pp. 289-292 ◽  
Author(s):  
Fei-Fei CHEN ◽  
Tie-Feng XU ◽  
Shi-Xun DAI ◽  
Qiu-Hua NIE ◽  
Xiang SHEN ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Oxide ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon
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