scholarly journals Chemical Composition of Essential Oils from SixZanthoxylumSpecies and Their Repellent Activities against Two Stored-Product Insects

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Wen-Juan Zhang ◽  
Zhe Zhang ◽  
Zhen-Yang Chen ◽  
Jun-Yu Liang ◽  
Zhu-Feng Geng ◽  
...  

The objective of this study was to analyze six essential oils fromZanthoxylumgenus (family Rutaceae) in China and evaluate their repellent activities againstTribolium castaneumandLasioderma serricorneadults. Six essential oils fromZanthoxylumgenus, includingZ. armatum,Z. dimorphophyllum,Z. dimorphophyllumvar.spinifolium,Z. piasezkii,Z. stenophyllum,andZ. dissitum,were obtained by hydrodistillation and their yields were ranging from 0.02% to 0.53%. Totally, there were 39 chemical components revealed by GC-MS. Among them, some components with high relative content existed in more than threeZanthoxylumspecies. For instance, bothδ-cadinene (1.21%–17.15%) and spathulenol (0.36%–10.19%) appeared in essential oils ofZ. dimorphophyllum,Z. piasezkii,Z. stenophyllum,andZ. dissitumwhich were found to have higher content of sesquiterpenoids. The repellent activities of six essential oil samples againstT. castaneumandL. serricorneadults were investigated for the first time. Data demonstrated that sixZanthoxylumspecies had much stronger repellent activities againstT. castaneumthanL. serricorneadults, especially in 2 hours after exposure. The results indicate that these six essential oils fromZanthoxylumhave significant potential to be developed into natural repellents to control insects in grains, food, and traditional Chinese medicinal materials.

2018 ◽  
Vol 73 (7-8) ◽  
pp. 313-318 ◽  
Author(s):  
Rose Vanessa Bandeira Reidel ◽  
Simona Nardoni ◽  
Francesca Mancianti ◽  
Claudia Anedda ◽  
Abd El-Nasser G. El Gendy ◽  
...  

Abstract The objective of the present paper was the assessment of the chemical composition of the essential oils from four Asteraceae species with a considerable food, medicinal, and agricultural value, collected in Egypt, together with their in vitro inhibitory activity against molds and yeasts. The essential oil of Launaea cornuta flowers was also evaluated for the first time, but because of its very low yield (<0.01%), no antifungal test was performed.


2014 ◽  
Vol 9 (1) ◽  
pp. 1934578X1400900
Author(s):  
Anass Elouaddari ◽  
Abdelaziz El Amrani ◽  
Jamal JamalEddine ◽  
José G. Barroso ◽  
Luis G. Pedro ◽  
...  

Air-dried aerial parts of wild Cladanthus mixtus were collected from two different regions of Morocco, Bouznika and Oujda, during 2011 and 2012. Forty individual plant samples were hydrodistilled using a Clevenger apparatus and the obtained essential oils were analyzed by GC and GC/MS. The yield obtained varies greatly with a range of 0.3 to 0.8%. The chemical composition of C. mixtus oils changes from one region to another. A total of 53 constituents were identified. To the best of our knowledge, two chemotypes were defined for the first time for this species in the regions studied. 2-Methyl-2- trans-butenyl methacrylate (32.8–35.2%) / ar-curcumene (13–14%) characterize the chemotypeof the C. mixtus plants from Bouznika, and trans-β-farnesene (35.5–50.3%) the chemotype from Oujda.


2013 ◽  
Vol 8 (2) ◽  
pp. 1934578X1300800 ◽  
Author(s):  
Tran Huy Thai ◽  
Ophélie Bazzali ◽  
Tran Minh Hoi ◽  
Nguyen Anh Tuan ◽  
Félix Tomi ◽  
...  

The essential oil isolated from Asarum cordifolium C. E. C. Fischer recently discovered in Vietnam, and A. glabrum Merr., an endangered species listed as vulnerable in the Red Data Book of Vietnam, have been analyzed by a combination of chromatographic and spectroscopic techniques including 13C NMR spectroscopy. The composition of A. cordifolium essential oil, investigated for the first time, was dominated by elemicin (82.5%). The essential oil isolated from A. glabrum contained safrole (41.9%) as its major component and was characterized by the diversity of phenylpropanoids contained in this oil (10 compounds).


2012 ◽  
Vol 7 (2) ◽  
pp. 1934578X1200700 ◽  
Author(s):  
Asta Judzentiene ◽  
Rita Butkiene ◽  
Jurga Budiene ◽  
Félix Tomi ◽  
Joseph Casanova

For the first time, the chemical composition of the seed essential oil of Rhododendron tomentosum was determined. Forty-seven compounds were identified, comprising 91.7% of the total oil. Palustrol (38.3%) and ledol (27.0%) were the predominant constituents. Some constituents, such as β-pinene oxide, iso-menthyl acetate, nerolidyl acetate, cadalene and guaiazulene were characteristic only for the seeds and were identified for the first time in Rh. tomentosum oils. For comparison purposes, the essential oil isolated from the shoots of the same plant were analyzed [GC(FID) in combination with RIs, GC-MS and 13C NMR]. More than a half of the oil was comprised of ledol (36.5%) and palustrol (21.0%). Quantitative analysis of ascaridol, a heat-sensitive compound, was carried out by 13C NMR spectroscopy. Indeed, ascaridol undergoes partial thermal isomerization to iso-ascaridol during GC analyses.


2019 ◽  
Vol 41 ◽  
pp. e46822
Author(s):  
Beatriz Eugenia Jaramillo-Colorado ◽  
Samyr Suarez-López ◽  
Vanessa Marrugo-Santander

The objectives of this work were the study of the volatile chemical composition of essential oils (EO’s) from Bursera graveolens obtained in the locality of Malagana, municipality of Mahates, Bolívar, Colombia, as well as to evaluate their repellent and fumigant properties. EO’s were extracted by hydro-distillation and characterized by gas chromatography-mass spectrometry (GC-MS). The major compounds found in B. graveolens were limonene (42.2%), pulegone (20.9%), carvone (7.5%), caryophyllene (4.1%), and trans-carveol (3.8%). The repellent activity of EO’s was determined by the area preference method, where the EO of B. graveolens presented repellent activity against the Tribolium castaneum weevil at a concentration of 1 at 2% and 4 hours of exposure (88.1 and 88.6% respectively). B. graveolens essential oil was more effective in its fumigant activity with LC50 of 108.2 μg oil mL-1. Also, the fumigant and repellent activities of two individual compounds present in the oil were evaluated, that is, limonene (majority) and caryophyllene. The results indicated that B. graveolens essential oil could be a promising alternative to new natural repellents and biocides.


2020 ◽  
Vol 42 ◽  
pp. e51639
Author(s):  
Beatriz Eugenia Jaramillo-Colorado ◽  
Flor María Palacio-Herrera ◽  
Edisson Duarte-Restrepo

 The objectives of this work were the study of the volatile chemical composition of essential oils (EO’s) from Swinglea glutinosa, as well as to evaluate their antioxidant, repellent and fumigant properties. The EO was obtained by hydrodistillation from the peel of the fruit, gathered in the city of Cartagena, Bolívar (Colombia). The volatile composition was analyzed by gas chromatography coupled to mass spectrometry (GC-MS). The major compounds found in S. glutinosa were germacrene D (4.8%), limonene (5.2%), a-terpineol (6.5%), b-pinene (8.5%), nerolidyl acetate (9.8%), and trans-nerolidol (34.6%). S. glutinosa showed antioxidant potential (85.8%) (IC50=142.49 µg mL-1). The EO deployed repellent activity against the Tribolium castaneum weevil at a concentration of 15.73 nL cm-1 at 2 hours of exposure (72%), while the result for the commercial repellent was 50% at the same concentration. EO from S. glutinosa displayed the best fumigant activity with LC50 of 153.4 μg mL-1 air. The essential oil from S. glutinosa can be considerated as a natural source of biocides and antioxidants.


2019 ◽  
Vol 14 (5) ◽  
pp. 1934578X1984300 ◽  
Author(s):  
Anam Arain ◽  
Syed Tufail Hussain Sherazi ◽  
Sarfaraz Ahmed Mahesar ◽  
Sirajuddin

The purpose of this study was to investigate the chemical composition of the essential oil extracted from Psidium guajava leaves and to explore the medicinal value of β-caryophyllene in pharmaceutical science. The essential oils of P. guajava leaves were extracted by the hydrodistillation method, using a Clevenger-type apparatus and the chemical composition of essential oils was investigated by gas chromatography–mass spectrometry. The yield of extracted essential oils was 0.6% (w/w) dry weight. The main compounds found in the leaves were β-caryophyllene (20.34%), globulol (8.20%), trans-nerolidol (7.72%), aromadendrene (4.34%), cis-α-bisabolene (3.82%), tetracosane (3.68%), octadecane (3.66%), Z, Z, Z-1,5,9,9-tetramethyl-1,4,7-cycloundecatriene (3.44%), β-bisabolene (3.41%), limonene (3.09%), octacosane (2.88%), δ-cadinene (2.52%), and 1,4-cadadiene (2.04%). The main chemical class of the essential oil was terpenoids, which represent 71.65%, followed by hydrocarbons (26.31%). A total of 50 components were identified, among these β-caryophyllene was found to be dominant, which has great medicinal value, and some other compounds were also identified for the first time in the essential oil of P. guajava leaves.


Author(s):  
Tran Hau Khanh ◽  
Pham Hong Ban ◽  
Tran Minh Hoi

Chemical composition of essential oils obtained from the leaf of Syzygium bullockii and Syzygium tsoongii were reported, corresponding oil content 0,36% and 0,27%. The analysis was performed by means of gas chromatography-flame ionization detector (GC-FID) and gas chromatography coupled with mass spectrometry (GC-MS). Twenty-seven components were identified in leaf oil of Syzygium bullockii, which represented about 76,75% of the total composition of the oil and six components were not identified, which represented 15,72%. The major constituents of the essential oil were (E)-caryophyllene (49,65%), spathulenol (4,29%), caryophyllene oxide (4,14%), bicyclogermacrene (3,35%), 2-tridecanone (3,25%). Fourty-six components were identified in leaf oil of Syzygium tsoongii, which presented about 99.71% of the total composition of the oil. The major constituents of the essential oil were E-caryophyllene (23,40%), bicyclogermacrene (21,23%), (Z)-β-ocimene (10,61%), α-humulene (6,33%), (E)-β-ocimene (4,99%). For the first time, the chemical compositions of the essential oils of Syzygium bullockii and Syzygium tsoongii from Vietnam were being reported.  


2009 ◽  
Vol 4 (8) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Asta Judzentiene ◽  
Félix Tomi ◽  
Joseph Casanova

Different techniques have been utilized to determine the composition of Artemisia absinthum (wormwood) essential oil. The oil was fractionated on a silica gel column and each fraction analyzed by GC(RI), GC-MS and 13C NMR. This allowed the identification, for the first time in A. absinthium, of two diterpenes, 9-geranyl-p-cymene and 9-geranyl-α-terpinene, and two homoditerpenes, 9-(15,16-dihydro-15-methylene)-geranyl-p-cymene and 9-(15,16-dihydro-15-methylene)-geranyl-α-terpinene. Chemical variability of A. absinthium essential oils from plants collected in the surroundings of Vilnius city over several years (1999-2007) was also shown. Chemical composition was determined by GC and GC-MS. Thujones ( cis+trans, 10.2-36.3%) and trans-sabinyl acetate (9.8-39.2%) were the two predominant constituents of almost all the investigated oils (13 out of 15 samples). The third major compound was myrcene (5.1-9.2%, in four samples), β-pinene (5.4-10.4%, in 5), linalool (4.7% in one), trans-sabinol (6.4%, in one) and 1,8-cineole (5.2-7.1%, in two). In one oil, the prevailing components were thujones ( cis+trans, 11.2%), trans-sabinene hydrate (11.0%) and trans-sabinyl acetate (8.8%), while another sample was characterized by a large quantity of trans-sabinyl acetate (55.2%) and the absence of thujones.


2010 ◽  
Vol 5 (7) ◽  
pp. 1934578X1000500 ◽  
Author(s):  
Janne Rojas ◽  
Alexis Buitrago ◽  
Luis B. Rojas ◽  
Antonio Morales ◽  
Shirley Baldovino

Essential oils extracted by hydrodistillation from leaves and roots of Ottoa oenanthoides Kunth (Apiaceae) were analyzed by GC/MS. The oils, obtained in yields of 0.10% and 0.66%, respectively, each contained four compounds, which were identified from their mass spectra and retention indices (RI). The major compound identified was 2-methoxy-8-methyl-1,4-naphthalindione (59.9% leaves, and 62.8%, roots), followed by 7-methoxy-1-naphthol (18.3% leaves and 17.3% roots), 2-naphthalenol (18.6% leaves and 15.0% roots), and 3-methoxy-2-naphthalenol (3.1% leaves and 2.1% roots). To the best of our knowledge, this is the first time that naphthalene derivatives have been reported for any species of the Apiaceae family.


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