scholarly journals Microwave-Assisted Solvent-Free Synthesis of Zeolitic Imidazolate Framework-67

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Heng Zhang ◽  
Jing Zhong ◽  
Guoxiang Zhou ◽  
Junliang Wu ◽  
Zhenyu Yang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Micropore Volume ◽  
Milling Process ◽  
Absorption Capacity ◽  
Solvent Free ◽  
Zeolitic Imidazolate Framework ◽  
Metal Organic ◽  
Solvent Free Synthesis

A microporous metal-organic framework (MOF), cobalt-based zeolitic imidazolate framework-67 (ZIF-67), was synthesized by the combination of solvent-free hand-mill and microwave irradiation, without any organic solvent and within 30 minutes. The hand-milling process can mix the reactants well by the virtue of high moisture/water absorption capacity of reactants. In addition, the outstanding electromagnetic wave absorption capability of cobalt leads to efficient conversion to MOF structures before carbonization. The obtained ZIF-67 possesses high surface area and micropore volume.

Metal-organic-framework derived hollow manganese nickel selenide spheres confined with nanosheets on nickel foam for hybrid supercapacitors

2021 ◽  
Author(s):  
Bahareh ameri ◽  
Akbar Mohammadi Zardkhoshoui ◽  
Saied Saeed Hosseiny Davarani
Keyword(s):  
Active Sites ◽  
Nickel Foam ◽  
Metal Organic Framework ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Supercapacitive Performance ◽  
Hybrid Supercapacitors ◽  
Porous Networks ◽  
Metal Organic

Metal-organic frameworks (MOFs) derived nanoarchitectures have special features, such as high surface area (SA), abundant active sites, exclusive porous networks, and remarkable supercapacitive performance when compared to traditional nanoarchitectures. Herein,...

scholarly journals Metal-Organic Framework-Based Engineered Materials—Fundamentals and Applications

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1598 ◽  
Author(s):  
Tahir Rasheed ◽  
Komal Rizwan ◽  
Muhammad Bilal ◽  
Hafiz M. N. Iqbal
Keyword(s):  
Drug Delivery ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Co2 Reduction ◽  
Biological Species ◽  
Crystalline Materials ◽  
Potential Applications ◽  
Metal Organic ◽  
Catalytic Chemistry

Metal-organic frameworks (MOFs) are a fascinating class of porous crystalline materials constructed by organic ligands and inorganic connectors. Owing to their noteworthy catalytic chemistry, and matching or compatible coordination with numerous materials, MOFs offer potential applications in diverse fields such as catalysis, proton conduction, gas storage, drug delivery, sensing, separation and other related biotechnological and biomedical applications. Moreover, their designable structural topologies, high surface area, ultrahigh porosity, and tunable functionalities all make them excellent materials of interests for nanoscale applications. Herein, an effort has been to summarize the current advancement of MOF-based materials (i.e., pristine MOFs, MOF derivatives, or MOF composites) for electrocatalysis, photocatalysis, and biocatalysis. In the first part, we discussed the electrocatalytic behavior of various MOFs, such as oxidation and reduction candidates for different types of chemical reactions. The second section emphasizes on the photocatalytic performance of various MOFs as potential candidates for light-driven reactions, including photocatalytic degradation of various contaminants, CO2 reduction, and water splitting. Applications of MOFs-based porous materials in the biomedical sector, such as drug delivery, sensing and biosensing, antibacterial agents, and biomimetic systems for various biological species is discussed in the third part. Finally, the concluding points, challenges, and future prospects regarding MOFs or MOF-based materials for catalytic applications are also highlighted.

scholarly journals Experimental and Modeling of Dicamba Adsorption in Aqueous Medium Using MIL-101(Cr) Metal-Organic Framework

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 419
Author(s):  
Hamza Ahmad Isiyaka ◽  
Khairulazhar Jumbri ◽  
Nonni Soraya Sambudi ◽  
Jun Wei Lim ◽  
Bahruddin Saad ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Adsorption Capacity ◽  
Environmental Concern ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Data Matrix ◽  
Adsorption Parameters ◽  
Metal Organic ◽  
Organic Framework

Drift deposition of emerging and carcinogenic contaminant dicamba (3,6-dichloro-2-methoxy benzoic acid) has become a major health and environmental concern. Effective removal of dicamba in aqueous medium becomes imperative. This study investigates the adsorption of a promising adsorbent, MIL-101(Cr) metal-organic framework (MOF), for the removal of dicamba in aqueous solution. The adsorbent was hydrothermally synthesized and characterized using N2 adsorption-desorption isotherms, Brunauer, Emmett and Teller (BET), powdered X-ray diffraction (XRD), Fourier Transformed Infrared (FTIR) and field emission scanning electron microscopy (FESEM). Adsorption models such as kinetics, isotherms and thermodynamics were studied to understand details of the adsorption process. The significance and optimization of the data matrix, as well as the multivariate interaction of the adsorption parameters, were determined using response surface methodology (RSM). RSM and artificial neural network (ANN) were used to predict the adsorption capacity. In each of the experimental adsorption conditions used, the ANN gave a better prediction with minimal error than the RSM model. The MIL-101(Cr) adsorbent was recycled six times to determine the possibility of reuse. The results show that MIL-101(Cr) is a very promising adsorbent, in particular due to the high surface area (1439 m2 g−1), rapid equilibration (~25 min), high adsorption capacity (237.384 mg g−1) and high removal efficiency of 99.432%.

Highly stable metal-organic framework UiO-66-NH2 for high-performance triboelectric nanogenerators

2021 ◽  
Author(s):  
Yong-Mei Wang ◽  
Xinxin Zhang ◽  
Dingyi Yang ◽  
Liting Wu ◽  
Jiaojiao Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Triboelectric Nanogenerator ◽  
High Porosity ◽  
Chemically Modified ◽  
Metal Organic ◽  
Triboelectric Nanogenerators ◽  
Organic Framework

Abstract The high porosity, controllable size, high surface area, and chemical versatility of a metal-organic framework (MOF) enable it a good material for a triboelectric nanogenerator (TENG), and some MOFs have been incorporated in the fabrication of TENGs. However, the understanding of effects of MOFs on the energy conversion of a TENG is still lacking, which inhibits the improvement of the performance of MOF-based TENGs. Here, UiO-66-NH2 MOFs were found to significantly increase the power of a TENG and the mechanism was carefully examined. The electron-withdrawing ability of Zr-based UiO-66-family MOFs was enhanced by designing the amino functionalized 1,4-terephthalic acid (1,4-BDC) as ligand. The chemically modified UiO-66-NH2 was found to increase the surface roughness and surface potential of a composite film with MOFs embedded in polydimethylsiloxane (PDMS) matrix. Thus the total charges due to the contact electrification increased significantly. The composite-based TENG was found to be very durable and its output voltage and current were 4 times and 60 times higher than that of a PDMS-based TENG. This work revealed an effective strategy to design MOFs with excellent electron-withdrawing abilities for high-performance TENGs.

Formation of a Metal-Organic Framework with High Surface Area and Gas Uptake by Breaking Edges Off Truncated Cuboctahedral Cages

2013 ◽  
Vol 125 (43) ◽  
pp. 11492-11495 ◽  
Author(s):  
Ruirui Yun ◽  
Zhiyong Lu ◽  
Yi Pan ◽  
Xiaozeng You ◽  
Junfeng Bai
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A new metal–organic framework with ultra-high surface area

2014 ◽  
Vol 50 (26) ◽  
pp. 3450 ◽  
Author(s):  
Ronny Grünker ◽  
Volodymyr Bon ◽  
Philipp Müller ◽  
Ulrich Stoeck ◽  
Simon Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Construction of Electrochemical Aptamer Sensor Based on Pt-Coordinated Titanium-Based Porphyrin MOF for Thrombin Detection

2022 ◽  
Vol 9 ◽  
Author(s):  
Jiazi Jiang ◽  
Quan Cai ◽  
Minghan Deng
Keyword(s):  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Single Atom ◽  
Strong Interactions ◽  
Carbon Electrode ◽  
Hybridization Time ◽  
Metal Organic ◽  
Aptamer Sensor ◽  
Pyrrole Nitrogen

In this work, a Pt-coordinated titanium-based porphyrin metal organic framework (Ti-MOF-Pt) was prepared by embedding single-atom Pt through strong interactions between the four pyrrole nitrogen atoms in the rigid backbone of the porphyrin. The synthesized Ti-MOF-Pt was characterized by TEM, XRD, FTIR and BET. Then, the Ti-MOF-Pt has been used for glassy carbon electrode surface modification and consequently used for construction of a thrombin aptamer sensor. The high surface area provides by MOF and excellent electrochemical property provided by Pt enhance the sensing performance. After optimization of amount of aptamer, hybridization time and specific reaction time, the fabricated aptamer sensor exhibited a linear relationship with the logarithm of the thrombin concentration in the range of 4 pM to 0.2 μM. The detection limit can be calculated as 1.3 pM.

A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

2015 ◽  
Vol 223 ◽  
pp. 104-108 ◽  
Author(s):  
Xiu-Liang Lv ◽  
Minman Tong ◽  
Hongliang Huang ◽  
Bin Wang ◽  
Lei Gan ◽  
...  
Keyword(s):  
Surface Area ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Dye Uptake ◽  
Metal Organic ◽  
Organic Framework
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