scholarly journals A Comparison Study of Mechanism: Cu2+Adsorption on Different Adsorbents and Their Surface-Modified Adsorbents

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Yaqin Yu ◽  
Xinrui Li ◽  
Jiemin Cheng
Keyword(s):  
Carbon Black ◽  
Adsorption Mechanism ◽  
Environmental Fate ◽  
Physical Adsorption ◽  
Hexadecyltrimethylammonium Bromide ◽  
Significant Implication ◽  
Isothermal Adsorption ◽  
Oxidized Carbon ◽  
Modified Adsorbents ◽  
Organic Bentonite

The isothermal adsorption kinetics of Cu2+onto Carbon Black (CB) and Oxidized Carbon Black (OCB) were studied under different solution conditions and compared with bentonite and organic bentonite with the hexadecyltrimethylammonium bromide (HDTMA). The adsorption capacities followed the order of OCB > CB > organic bentonite > bentonite, which was consistent with the orders of their surface roughness and specific surface area. The Fourier transmission infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscope (TEM) were used to explore the adsorption mechanism at molecular level. The adsorption process onto CB was physical adsorption. However, with the increase of oxygen-containing functional groups (C=O, C-O, and CNO), the chelation adsorption onto OCB became gradually dominant except physical adsorption. The ion exchange adsorption was the major adsorption mechanism of bentonite. The compounds were introduced into clay interlayer by complexing reaction with Cu2+, which improved the adsorption capacity of organic bentonite. The results present a significant implication for the environmental fate assessment of heavy metal pollution.

scholarly journals Graphene Oxide and Oxidized Carbon Black as Catalyst for Crosslinking of Phenolic Resins

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1330 ◽  
Author(s):  
Maria Rosaria Acocella ◽  
Aniello Vittore ◽  
Mario Maggio ◽  
Gaetano Guerra ◽  
Luca Giannini ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Graphene Oxide ◽  
Catalytic Activity ◽  
Thermal Treatment ◽  
Carbon Black ◽  
Crosslinking Reaction ◽  
Scanning Calorimetry ◽  
Indirect Methods ◽  
Phenolic Resins ◽  
Oxidized Carbon

Influence of different graphite-based nanofillers on crosslinking reaction of resorcinol, as induced by hexa(methoxymethyl)melamine, is studied. Curing reactions leading from low molecular mass compounds to crosslinked insoluble networks are studied by indirect methods based on Differential Scanning Calorimetry. Reported results show a catalytic activity of graphene oxide (eGO) on this reaction, comparable to that one already described in the literature for curing of benzoxazine. For instance, for an eGO content of 2 wt %, the exothermic crosslinking DSC peak (upon heating at 10 °C/min) shifted 6 °C. More relevantly, oxidized carbon black (oCB) is much more effective as catalyst of the considered curing reaction. In fact, for an oCB content of 2 wt %, the crosslinking DSC peak can be shifted more than 30 °C and a nearly complete crosslinking is already achieved by thermal treatment at 120 °C. The possible origin of the higher catalytic activity of oCB with respect to eGO is discussed.

Comparison of Co(ii) adsorption by a crosslinked carboxymethyl chitosan hydrogel and resin: behaviour and mechanism

2017 ◽  
Vol 41 (9) ◽  
pp. 3487-3497 ◽  
Author(s):  
Wenqiang Luo ◽  
Zhishan Bai ◽  
Yong Zhu
Keyword(s):  
Adsorption Mechanism ◽  
Physical Adsorption ◽  
Carboxymethyl Chitosan ◽  
Chitosan Hydrogel

This article studies the possible chemical and physical adsorption mechanism for Co(ii) onto the crosslinked carboxymethyl chitosan hydrogel and resin.

Gas phase hydrogenation of crotonaldehyde over platinum supported on oxidized carbon black

Carbon ◽  
1998 ◽  
Vol 36 (7-8) ◽  
pp. 1011-1019 ◽  
Author(s):  
F. Coloma ◽  
J. Narciso-Romero ◽  
A. Sepúlveda-Escribano ◽  
F. Rodríguez-Reinoso
Keyword(s):  
Carbon Black ◽  
Gas Phase ◽  
Oxidized Carbon

PHYSICAL ADSORPTION STUDIES IN CARBON BLACK TECHNOLOGY

1955 ◽  
Vol 33 (2) ◽  
pp. 314-319 ◽  
Author(s):  
M. H. Polley ◽  
W. D. Schaeffer ◽  
W. R. Smith
Keyword(s):  
Carbon Black ◽  
Adsorption Isotherms ◽  
Unit Area ◽  
Physical Adsorption ◽  
Butyl Rubber ◽  
Chemisorbed Oxygen ◽  
Heat Treated ◽  
Furnace Black ◽  
Cyclic Heat ◽  
Black Surface

The adsorption isotherms of n-butane and butene-1 on typical furnace and channel carbon blacks were determined over a range of temperatures, 55°–250 °C. The adsorption of n-butane on carbon black surfaces is attributed to physical adsorption; however, the extent of surface covered per unit area of carbon black is considerably greater at a given temperature than for a silica. Butene-1 is also physically adsorbed on the furnace blacks. The presence of approximately 3% chemisorbed oxygen on the surface of the channel blacks induces an isomerization of butene-1 to cis-butene-2. When oxygen is first chemisorbed on a furnace black surface, then that surface also interacts with butene-1. Those blacks which participate in the isomerization of butene-1 respond or "interact" in a cyclic heat treated Butyl rubber – carbon black masterbatch.

scholarly journals Oxidized Carbon Black: Preparation, Characterization and Application in Antibody Delivery across Cell Membrane

2018 ◽  
Vol 8 (1) ◽  
Author(s):  
Kittima Amornwachirabodee ◽  
Nattapol Tantimekin ◽  
Porntip Pan-In ◽  
Tanapat Palaga ◽  
Prompong Pienpinijtham ◽  
...  
Keyword(s):  
Cell Membrane ◽  
Carbon Black ◽  
Oxidized Carbon ◽  
Antibody Delivery

Biosorption of Textile Dye Red Bemacid ETL Using Activated Charcoal of Grape Marc (Oenological By-Product)

2019 ◽  
Vol 800 ◽  
pp. 151-156
Author(s):  
Yamina Chergui ◽  
Abdelkader Iddou ◽  
Hafida Hentit ◽  
Abdallah Aziz ◽  
Jean Claude Jumas
Keyword(s):  
Aqueous Solution ◽  
Zinc Chloride ◽  
Contact Time ◽  
Adsorption Mechanism ◽  
Activated Carbons ◽  
Batch Adsorption ◽  
Textile Dye ◽  
Isothermal Adsorption ◽  
Physical Methods ◽  
Grape Marc

The objective of this study was the synthesis of various activated carbons from grape marc issued from oenological by-product as a biosorbent. The biosolid was then applied to remove an industrial dye (red bemacid ETL) in aqueous solution. Activation of the synthesized charcoal was carried out using a solution of zinc chloride induced by two physical methods (microwaves and heating at 300°C). The obtained materials are characterized by FTIR and SEM methods. Results from batch adsorption tests have shown that pH solution, initial dye concentration and contact time affect the adsorption mechanism. Removal of the industrial dye revealed second order kinetics, exothermic adsorption and isothermal adsorption of BET type.

The Adsorption Behavior of Modified Peanut Shells for Cr (VI)

2013 ◽  
Vol 781-784 ◽  
pp. 2189-2194
Author(s):  
Yi Hua Jiang ◽  
Xin Long Jiang
Keyword(s):  
Adsorption Mechanism ◽  
Physical Adsorption ◽  
Peanut Shell ◽  
Chemical Adsorption ◽  
Chemical Methods ◽  
Ir Spectrometry ◽  
Freundlich Isotherms ◽  
Reduction Processes ◽  
Peanut Shells ◽  
Adsorption Activation Energy

The adsorption of Cr(VI) by modified peanut shell has been investigated using chemical methods and IR spectrometry. The optimal condition for the adsorption of Cr(VI) by modified peanut shell is at 308 K and pH = 1.0, which gives a static saturated adsorption capacity of 14.15 mg·g-1, an apparent adsorption rate constant of k298 = 2.43 × 10-4 s-1, and an apparent adsorption activation energy of 10.58 kJ·mol-1. The adsorption follows the Langmuir and Freundlich isotherms and the liquid film diffusion is the controlling process of the adsorption. The adsorption thermodynamic parameters are ΔH = 125.58 kJ·mol-1, ΔS = 0.473 9 kJ·mol-1·K-1, ΔG = -17.81– -27.27 kJ·mol-1. Small amount of desorption is observed only at pH > 11. Adsorption mechanism of modified peanut shells for Cr(VI) was both physical adsorption and chemical adsorption of adsorbent "adsorption-oxidation and reduction processes".

Adsorption and Calorimetric Investigations on Carbon Black Surfaces. III. Immersion Heats in Model Elastomers and Isosteric Heats of Adsorption of C-4 Hydrocarbons

1972 ◽  
Vol 45 (1) ◽  
pp. 117-128 ◽  
Author(s):  
W. H. Wade ◽  
M. L. Deviney ◽  
W. A. Brown ◽  
M. H. Hnoosh ◽  
D. R. Wallace
Keyword(s):  
Carbon Black ◽  
Physical Adsorption ◽  
High Viscosity ◽  
High Energy ◽  
Heat Evolution ◽  
Carbon Substrate ◽  
Heats Of Adsorption ◽  
Adsorption Sites ◽  
Heat Of Wetting ◽  
Black Surface

Abstract The heats of immersion of U-1 channel and SAF, SPF, HAF-HS, and HAF furnace blacks have been measured at 25° C in three isoprenoid olefins and four liquid elastomers of the polybutadiene, polyisoprene, and SBR types. An extensive microcalorimeter redesign was necessary because of the high viscosity of these latter fluids. The immersion heats observed with the liquid elastomers were similar to n-decane immersion heats and there was little evidence for specific interactions between these liquids and any of the blacks. The possibility that the very high structure SPF black gives slightly enhanced immersion heats should be further investigated. Since only integral immersion heats could be measured with the non-volatile liquid elastomers, the possibility is not ruled out that specific, relatively high-energy interactions may occur between the adsorbate and a very small fraction of the black surface. The similarities between the immersion heats with n-decane and the liquid elastomers indicate that almost all of the carbon black surface is accessible to the polymer segments. It appears that the rate of heat evolution may be considered a measure of the rate of attainment of intimate molecular contact between the liquid and carbon substrate. The enhancement in heat of wetting with increasing chain length over the C6 to C16 n-alkane series reported by others with a highly uniform, graphitized black was not observed with HAF. Isosteric heats of adsorption of n-butane and butene-1 at low surface coverages on several carbon blacks were calculated from adsorption isotherms obtained with a precision microgravimetric system. The isosteric heats as a function of coverage curves were typical of those expected for heterogeneous surfaces and reflected the presence of high energy physical adsorption sites at low coverages (θ<0.1).

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