scholarly journals Alginate Production from Alternative Carbon Sources and Use of Polymer Based Adsorbent in Heavy Metal Removal

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Çiğdem Kıvılcımdan Moral ◽  
Merve Yıldız

Alginate is a biopolymer composed of mannuronic and guluronic acids. It is harvested from marine brown algae; however, alginate can also be synthesized by some bacterial species, namely,AzotobacterandPseudomonas. Use of pure carbohydrate sources for bacterial alginate production increases its cost and limits the chance of the polymer in the industrial market. In order to reduce the cost of bacterial alginate production, molasses, maltose, and starch were utilized as alternative low cost carbon sources in this study. Results were promising in the case of molasses with the maximum 4.67 g/L of alginate production. Alginates were rich in mannuronic acid during early fermentation independent of the carbon sources while the highest guluronic acid content was obtained as 68% in the case of maltose. The polymer was then combined with clinoptilolite, which is a natural zeolite, to remove copper from a synthetic wastewater. Alginate-clinoptilolite beads were efficiently adsorbed copper up to 131.6 mg Cu2+/g adsorbent at pH 4.5 according to the Langmuir isotherm model.

2020 ◽  
Vol 14 (3) ◽  
pp. 384-395
Author(s):  
Juan Yin ◽  
Chao-Bing Deng ◽  
Hongxiang Zhu ◽  
Jianhua Xiong ◽  
Zhuo Sun

Sulfate reducing bacteria (SRB) are widely used to remove heavy metals because of their high efficiency. However, the metabolic processes of SRB require additional carbon sources, and the development of low-cost carbon sources has gradually attracted attention. The utilization of sugar byproduct resources, as the low-cost carbon sources, has great practical significance for environmentally sustainable development in Guangxi, China. This study aims to cultivate SRB with low-cost sugar byproducts, apply them to controlling a lead-polluted environment, and study the effects and mechanisms of controlling lead pollution. The research results show that the best culture effect of SBR can be obtained by mixing the filter mud and vinasse in a ratio of 1:1 to 3:1. SRB have average lead removal rates of more than 96.97% in solutions with different lead concentration of 10∼100 mg/L, and SRB have a higher tolerance to high concentrations of lead due to factors such as the organic substance composition of sugar byproducts and the porosity of filter mud. Scanning electron microscopy combined with energy dispersive spectrometry and X-ray diffraction analysis show that SRB mainly cause Pb2+ to form PbS precipitate through redox reactions to remove lead from the solution. Therefore, low-cost filters of a mud and vinasse mixture can be used as a medium for SRB and exhibit high heavy metal removal efficiency, thus providing a new utilization of filter mud and vinasse.


2018 ◽  
Vol 162 ◽  
pp. 05007 ◽  
Author(s):  
Thamer Mohammed ◽  
Raheek Ibrahim ◽  
Alia Naji

The objective of the study is to treat industrial wastewater and perform a thermodynamic experimental study for more economical and efficient adsorption process. This has been done by biosorption and chemisorption of chromium ions from synthetic wastewater into already prepared pomegranate peel as a natural adsorbent. Pomegranate peel proved to be an economic solution since it is available locally and it has an elevated adsorption capacity. Adsorption has been done in a fixed bed column (10 cm inside diameter, and 30 cm height) with continuous flow rate of 1 ml/min. The characteristic properties of adsorption for the pomegranate peel, analyzed by FTIR and SEM, proved that pomegranate peel is a good adsorbent because of its effective combinations and holes on its exterior. Also, comparing between adsorption ability of pomegranate peel together with Langmuir and Freundlich models indicates that Langmuir is preferable in fitting the experimental data. However, the elimination efficiency of the pomegranate peel was 90%, and the greatest adsorption capability was 9.45 mg/g. While, thermodynamic study results showed that endothermic adsorption was approved from positive values of ΔH°, also the negative values of ΔG° proved that the adsorption is unprompted and convenient.


Author(s):  
Bingbing Qiu ◽  
Xuedong Tao ◽  
Hao Wang ◽  
Wenke Li ◽  
Xiang Ding ◽  
...  

2014 ◽  
Vol 625 ◽  
pp. 889-892 ◽  
Author(s):  
Safoura Daneshfozoun ◽  
Bawadi Abdullah ◽  
Mohd Azmuddin Abdullah

This study developed an effective and economical physical pretreatment of OPEFB to be used as biosorbent for the removal of heavy metal ions such as Cu+2, Zn+2and Pb2+. The effects of fibres sizes, metal ions concentration (100-1000 ppm), initial pH (4-10) and contact time (20-150 min) were investigated in batch system. Samples were characterized with Atomic Absorption Spectrometry (AAS), Transmission Electron Microscopy (TEM) and Fourier Transmission Infra-red Spectroscopy (FTIR). Results showed pH-dependence adsorption efficiency and increased adsorption with initial metal concentrations where more than 92% adsorption efficiency achieved. We have successfully developed an eco-friendly, low cost adsorbent without any chemical modification or excessive energy disposal.


2016 ◽  
Vol 7 (4) ◽  
pp. 387-419 ◽  
Author(s):  
Renu ◽  
Madhu Agarwal ◽  
K. Singh

Heavy metals are discharged into water from various industries. They can be toxic or carcinogenic in nature and can cause severe problems for humans and aquatic ecosystems. Thus, the removal of heavy metals from wastewater is a serious problem. The adsorption process is widely used for the removal of heavy metals from wastewater because of its low cost, availability and eco-friendly nature. Both commercial adsorbents and bioadsorbents are used for the removal of heavy metals from wastewater, with high removal capacity. This review article aims to compile scattered information on the different adsorbents that are used for heavy metal removal and to provide information on the commercially available and natural bioadsorbents used for removal of chromium, cadmium and copper, in particular.


2020 ◽  
Vol 1010 ◽  
pp. 489-494
Author(s):  
Abdul Hafidz Yusoff ◽  
Rosmawani Mohammad ◽  
Mardawani Mohamad ◽  
Ahmad Ziad Sulaiman ◽  
Nurul Akmar Che Zaudin ◽  
...  

Conventional methods to remove heavy metals from polluted water are expensive and not environmentally friendly. Therefore, this study was carried out to investigate the potential of agricultural waste such as pineapple peel (Ananas Cosmos) as low-cost absorbent to remove heavy metals from synthetic polluted water. The results showed that Cd, Cr and Pb were effectively removed by the biosorbent at 12g of pineapple peels in 100 mL solution. The optimum contact time for maximum adsorption was found to be 90 minutes, while the optimum pH for the heavy metal’s adsorption was 9. It was demonstrated that with the increase of adsorbent dosage, the percent of heavy metals removal was also increased due to the increasing adsorption capacity of the adsorbent. In addition, Langmuir model show maximum adsorption capacity of Cd is 1.91 mg/g. As conclusions, our findings show that pineapple peel has potential to remove heavy metal from polluted water.


Author(s):  
E I Ugwu ◽  
O Tursunov ◽  
D Kodirov ◽  
L M Shaker ◽  
A A Al-Amiery ◽  
...  

2020 ◽  
Vol 17 (9) ◽  
pp. 4666-4670
Author(s):  
Himanshu Sekhar Rath ◽  
Mira Das ◽  
Smita Rath ◽  
U. N. Dash ◽  
Alakananda Tripathy

The goal of this research is to determine the current standard of water quality along the Brahmani River stretch in terms of physico-chemical parameters. The River Brahmani receives a substantial amount of industrial waste in the identified study area and is witness to a large amount of human and agricultural activities. Nowadays Ninety percent of Brahmani’s required water is secured with groundwater resources and it is essential to forecast pollutant content in those resources. Hence, this research aimed at using of nanoparticles such as Activated Carbons (ACs) for removal of heavy metal such as nickel and zinc in Brahmani river using the Langmuir approach. Adsorption seems to be the most widely used method for heavy metal recovery due to its low cost, easy installation and the presence of alternative adsorbents. In addition, the process of adsorption can also be made in use to recover heavy metal ions from wastewater. Despite these advantages, adsorption is hard to commercialize. Due to the strong absorption capacity, high number of pores and wide, common area, nanoparticles are treated as the effective method in removal of heavy metals in rivers. Comparative analysis shows that seventy-one percent of heavy metals can be removed using the nanotechnology model.


2015 ◽  
Vol 773-774 ◽  
pp. 1286-1290 ◽  
Author(s):  
M.F.H. Azizul-Rahman ◽  
A.A. Mohd Suhaimi ◽  
Norzila Othman

The heavy metal contain in the industrial wastewater can cause a pollution towards the environment and human due to its toxicity. Therefore extensive studies were conducted for the heavy metal removal. This study was conducted under several conditions by varying pH, biosorbent dosage, initial wastewater concentration and contact time. The results revealed that optimum pH, for high strength synthetic wastewater was 8.0 meanwhile for low strength synthetic wastewater was 7.0. Both high and low strength synthetic wastewater was optimum at 30 minutes of contact time with 1.5g and 0.02g of bisorbent dosage respectively. Meanwhile, the optimum initial metal concentration for high and low strength synthetic wastewater was 400ppm and 1ppm respectively. The results had proven that watermelon rind is able to treat wastewater with high and low concentration of metal.


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