scholarly journals Mechanical Properties of Boehmite Evaluated by Atomic Force Microscopy Experiments and Molecular Dynamic Finite Element Simulations

2016 ◽  
Vol 2016 ◽  
pp. 1-13 ◽  
Author(s):  
J. Fankhänel ◽  
D. Silbernagl ◽  
M. Ghasem Zadeh Khorasani ◽  
B. Daum ◽  
A. Kempe ◽  
...  

Boehmite nanoparticles show great potential in improving mechanical properties of fiber reinforced polymers. In order to predict the properties of nanocomposites, knowledge about the material parameters of the constituent phases, including the boehmite particles, is crucial. In this study, the mechanical behavior of boehmite is investigated using Atomic Force Microscopy (AFM) experiments and Molecular Dynamic Finite Element Method (MDFEM) simulations. Young’s modulus of the perfect crystalline boehmite nanoparticles is derived from numerical AFM simulations. Results of AFM experiments on boehmite nanoparticles deviate significantly. Possible causes are identified by experiments on complementary types of boehmite, that is, geological and hydrothermally synthesized samples, and further simulations of imperfect crystals and combined boehmite/epoxy models. Under certain circumstances, the mechanical behavior of boehmite was found to be dominated by inelastic effects that are discussed in detail in the present work. The studies are substantiated with accompanying X-ray diffraction and Raman experiments.

2000 ◽  
Vol 39 (Part 1, No. 6B) ◽  
pp. 3711-3716 ◽  
Author(s):  
Hatsuki Shiga ◽  
Yukako Yamane ◽  
Etsuro Ito ◽  
Kazuhiro Abe ◽  
Kazushige Kawabata ◽  
...  

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 652
Author(s):  
Divine Sebastian ◽  
Chun-Wei Yao ◽  
Lutfun Nipa ◽  
Ian Lian ◽  
Gary Twu

In this work, a mechanically durable anticorrosion superhydrophobic coating is developed using a nanocomposite coating solution composed of silica nanoparticles and epoxy resin. The nanocomposite coating developed was tested for its superhydrophobic behavior using goniometry; surface morphology using scanning electron microscopy and atomic force microscopy; elemental composition using energy dispersive X-ray spectroscopy; corrosion resistance using atomic force microscopy; and potentiodynamic polarization measurements. The nanocomposite coating possesses hierarchical micro/nanostructures, according to the scanning electron microscopy images, and the presence of such structures was further confirmed by the atomic force microscopy images. The developed nanocomposite coating was found to be highly superhydrophobic as well as corrosion resistant, according to the results from static contact angle measurement and potentiodynamic polarization measurement, respectively. The abrasion resistance and mechanical durability of the nanocomposite coating were studied by abrasion tests, and the mechanical properties such as reduced modulus and Berkovich hardness were evaluated with the aid of nanoindentation tests.


Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1661
Author(s):  
Katarzyna Adamiak ◽  
Katarzyna Lewandowska ◽  
Alina Sionkowska

Collagen films are widely used as adhesives in medicine and cosmetology. However, its properties require modification. In this work, the influence of salicin on the properties of collagen solution and films was studied. Collagen was extracted from silver carp skin. The rheological properties of collagen solutions with and without salicin were characterized by steady shear tests. Thin collagen films were prepared by solvent evaporation. The structure of films was researched using infrared spectroscopy. The surface properties of films were investigated using Atomic Force Microscopy (AFM). Mechanical properties were measured as well. It was found that the addition of salicin modified the roughness of collagen films and their mechanical and rheological properties. The above-mentioned parameters are very important in potential applications of collagen films containing salicin.


2018 ◽  
Vol 114 (3) ◽  
pp. 513a
Author(s):  
Yuri M. Efremov ◽  
Mirian Velay-Lizancos ◽  
Daniel M. Suter ◽  
Pablo D. Zavattieri ◽  
Arvind Raman

PLoS ONE ◽  
2012 ◽  
Vol 7 (1) ◽  
pp. e30204 ◽  
Author(s):  
David Martinez-Martin ◽  
Carolina Carrasco ◽  
Mercedes Hernando-Perez ◽  
Pedro J. de Pablo ◽  
Julio Gomez-Herrero ◽  
...  

Author(s):  
Hosam Gharib Abdelhady

Objectives: This research aims at investigating the effect of nano-encapsulating the MagnevistTM, a magnetic resonance imaging agent, within generation four, 1, 4- diaminobutane core polyamidoamine dendrimers on their molecular morphology and their nano-mechanical properties in liquid.Methods: Atomic force microscopy was applied in its imaging and force measuring modes to investigate, on the molecular scale, the morphological and nano-mechanical changes in generation four, 1, 4-diaminobutane core polyamidoamine dendrimers due to the nano-encapsulation of Magnevist in liquid.Results: The weight gain of dendrimers indicates the loading of ~ 30 Magnevist molecules. This has increased the rigidity of the dendrimer molecules, compared to unloaded dendrimers. Atomic force microscopy showed individual well-defined nano-spherical particles with nanoscopic dimensions of (40±13 nm in diameter and 4.38±0.54 nm in height). In contrast, imaging of non encapsulated dendrimers revealed loose aggregates of 15±3.5 nm in diameter and 0.9±0.2 nm in height.Conclusions: The atomic force microscopy, in liquid, was successfully applied to differentiate between Magnevist nano-encapsulated and non-encapsulated dendrimers, in their morphology and in their nano-mechanical properties. The results confirm the nano-encapsulation of Magnevist within generation four, 1,4-diaminobutane core polyamidoamine dendrimers. This loading increased the rigidity of the nanoencapsulated dendrimer, packed ~ 9 Magnevist-G 4 molecules together and may probably enhance the magnetic resonance images and increase their duration of time in the bloodstream when compared with Magnevist alone. Thus elongating the imaging sessions without the need for additional contrast agent doses.


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