scholarly journals Surface Modification of Asymmetric Polysulfone/Polyethylene Glycol Membranes by DC Ar-Glow Discharge Plasma

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Chalad Yuenyao ◽  
Thawat Chittrakarn ◽  
Yutthana Tirawanichakul ◽  
Suksawat Sirijarukul

Polysulfone/polyethylene glycol (PSF/PEG) membranes were prepared by dry/wet phase inversion method. Effects of direct current glow discharge plasma using argon as working gas on morphological structures and gas separation properties of membranes were studied. Alteration of membrane characteristics were analyzed by various techniques like contact angle, scanning electron microscope, Fourier transform infrared spectroscopy, and dynamic mechanical thermal analysis. Gas separation properties were measured in terms of permeation and ideal O2/N2 selectivity. Results showed that hydrophilic and gas separation properties of PSF/PEG membranes increased by plasma surface modification. It was also shown that the dosage of PEG and plasma treatment affected the morphological structures and mechanical and gas separation properties. The macro voids and transmembrane structure disappeared with a little amount of PEG dosage. Pore size and mechanical strength tend to decrease with increasing PEG dosage up to 10 wt%. Glass transition temperature (Tg) receded from 201.8 to 143.7°C for pure PSF and PSF/PEG with PEG dosage of 10 wt%. O2 and N2 gases permeation through the 10-minute plasma treated membranes tend to increase. However, the permeation strongly dispersed when treatment time was more extended.

2014 ◽  
Vol 1048 ◽  
pp. 72-76
Author(s):  
Huan Da Zheng ◽  
Juan Zhang ◽  
Bing Du ◽  
Qu Fu Wei ◽  
Lai Jiu Zheng

Meta-aramid fibers were treated by sub-atmospheric pressure dielectric barrier glow discharge plasma. The effect of plasma treatment time on the fiber surface physical and chemical properties was studied by using surface characterization techniques. Scanning electron microscopy (SEM) was performed to determine the surface morphology changes. FT-IR spectroscopy measurements were performed to investigate the change of chemical structure. Dynamic contact angle analysis (DCAA) was used to examine the changes of the fiber surface wettability. SEM analysis showed that there was obvious crack along the fibers’ axial direction present on the fiber surface, which resulted in the better wetting behavior of the plasma-treated PMIA fiber. FT-IR analysis showed that plasma had little effect on the chemical structure of PMIA fibers. DCAA analysis showed that the wettability of the samples could be improved with the treatment time increasing. In addition, a slight decrease in breaking strength was observed at the treatment time ranging from 60 to 180 s in comparison with the untreated sample.


2019 ◽  
Vol 490 ◽  
pp. 266-277 ◽  
Author(s):  
Pezhman Zolfaghari ◽  
Hamid Reza Khaledian ◽  
Nasrin Aliasgharlou ◽  
Sirous Khorram ◽  
Afzal Karimi ◽  
...  

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