scholarly journals Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Maytham Kadhim Obaid ◽  
Luqman Chuah Abdullah ◽  
Intidhar Jabir Idan
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Correlation Coefficients ◽  
Maximum Adsorption Capacity ◽  
Trimethylammonium Chloride ◽  
Order Kinetic ◽  
Kenaf Core ◽  
Reactive Orange 16 ◽  
Core Fiber ◽  
Reactive Orange

Evaluated removal of reactive orange 16 (RO16) dye from aqueous solution was studied in batch mode by using kenaf core fiber as low-cost adsorbents. In this attempt, kenaf core fiber with size 0.25–1 mm was treated by using (3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHMAC) as quaternization agent. Then effective parameters include adsorbent dose, pH, and contact time and initial dye concentration on adsorption by modified kenaf core fiber was investigated. In addition, isotherms and kinetics adsorption studies were estimated for determination of the equilibrium adsorption capacity and reactions dynamics, respectively. Results showed that the best dose of MKCF was 0.1 g/100 mL, the maximum removal of RO16 was 97.25 at 30°C, pH = 6.5, and agitation speed was 150 rpm. The results also showed that the equilibrium data were represented by Freundlich isotherm with correlation coefficientsR2=0.9924, and the kinetic study followed the pseudo-second-order kinetic model with correlation coefficientsR2=0.9997forCo=100 mg/L. Furthermore, the maximum adsorption capacity was 416.86 mg/g. Adsorption through kenaf was found to be very effective for the removal of the RO16 dye.

scholarly journals Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber

2017 ◽  
Vol 36 (1-2) ◽  
pp. 694-712 ◽  
Author(s):  
Intidhar J Idan ◽  
Luqman C Abdullah ◽  
Thomas SY Choong ◽  
Siti Nurul Ain B Md Jamil
Keyword(s):  
Maximum Adsorption Capacity ◽  
Trimethylammonium Chloride ◽  
Order Kinetic ◽  
Adsorption Studies ◽  
Kenaf Core ◽  
Core Fiber ◽  
Percentage Removal ◽  
Acid Blue 25 ◽  
Acid Blue ◽  
Acid Green 25

Quaternized kenaf core fiber (QKCF) was used as an adsorbent for adsorption of anionic Acid Blue-25 (AB) and anionic Acid Green-25 (AG) dyes. Chemical treatment with (3-chloro-2-hydroxypropyl) trimethylammonium chloride under basic condition was applied in order to alter the surface properties of the raw kenaf core fiber. Adsorption studies were carried out to delineate the effect of initial dye concentration, temperature and pH on removal of dyes. The results show that the percentage removal of Acid Blue-25 and Acid Green-25 dyes were increased by increasing the concentrations of dyes. In addition, the maximum percentage removal was 99.8% and 99.65% for Acid Blue-25 and Acid Green-25, respectively. Langmuir, Freundlich and Temkin isotherm models were applied to analyze the data for dye adsorption at 15℃, 25℃, 35℃, and 45℃. The experimental data were best represented by the Langmuir model with maximum adsorption capacity of 303.03 mg/g and 344.83 mg/g for Acid Blue-25 and Acid Green-25 dyes, respectively, at 15℃, and the kinetic data for both dyes were best represented by the pseudo-second-order kinetic model. Thermodynamic studies indicated that the reactions of Acid Blue-25 and Acid Green-25 dyes were endothermic. It was concluded that QKCF adsorbent can be utilized as an efficient low-cost adsorbent for removal of anionic dyes.

Kinetics of lead ion biosorption from aqueous solution onto lyophilized Aspergillus niveus

2010 ◽  
Vol 5 (1) ◽  
Author(s):  
Hülya Karaca ◽  
Turgay Tay ◽  
Merih Kıvanç
Keyword(s):  
Adsorption Capacity ◽  
Correlation Coefficients ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Lead Ions ◽  
Lead Ion ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Aspergillus Niveus ◽  
Pseudo Second Order

The biosorption of lead ions (Pb2+) onto lyophilized fungus Aspergillus niveus was investigated in aqueous solutions in a batch system with respect to pH, contact time and initial concentration of the ions at 30 °C. The maximum adsorption capacity of lyophilized A. niveus was found to be 92.6 mg g−1 at pH 5.1 and the biosorption equilibrium was established about in 30 min. The adsorption capacity obtained is one of the highest value among those reported in the literature. The kinetic data were analyzed using the pseudo-first-order kinetic, pseudo-second-order kinetic, and intraparticle diffusion equations. Kinetic parameters, such as rate constants, equilibrium adsorption capacities, and related correlation coefficients for the kinetic models were calculated and discussed. It was found that the adsorption of lead ions onto lyophilized A. niveus biomass fit the pseudo-second-order kinetic model well. The Langmuir and Freundlich isotherm parameters for the lead ion adsorption were applied and the Langmuir model agreed better with the adsorption of lead ions onto lyophilized A. niveus.

scholarly journals Modified/Unmodified Nanoparticle Adsorbents of Cellulose Origin With High Adsorptive Potential for Removal of Pb(II) From Aqueous Solution

2017 ◽  
Vol 13 (27) ◽  
pp. 425
Author(s):  
Azeh Yakubu ◽  
Gabriel Ademola Olatunji ◽  
Folahan Amoo Adekola
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Contact Time ◽  
Adsorption Process ◽  
Correlation Coefficients ◽  
Solution Temperature ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Kinetics Of Adsorption ◽  
Kinetics Of

This investigation was conducted to evaluate the adsorption capacity of nanoparticles of cellulose origin. Nanoparticles were synthesized by acid hydrolysis of microcrystalline cellulose/cellulose acetate using 64% H3PO4 and characterized using FTIR, XRD, TGA-DTGA, BET and SEM analysis. Adsorption kinetics of Pb (II) ions in aqueous solution was investigated and the effect of initial concentration, pH, time, adsorbent dosage and solution temperature. The results showed that adsorption increased with increasing concentration with removal efficiencies of 60% and 92.99% for Azeh2 and Azeh10 respectively for initial lead concentration of 3 mg/g. The effects of contact time showed that adsorption maximum was attained within 24h of contact time. The maximum adsorption capacity and removal efficiency were achieved at pH6. Small dose of adsorbent had better performance. The kinetics of adsorption was best described by the pseudo-second-Order model while the adsorption mechanism was chemisorption and pore diffusion based on intra-particle diffusion model. The isotherm model was Freundlich. Though, all tested isotherm models relatively showed good correlation coefficients ranging from 0.969-1.000. The adsorption process was exothermic for Azeh-TDI, with a negative value of -12.812 X 103 KJ/mol. This indicates that the adsorption process for Pb by Azeh-TDI was spontaneous. Adsorption by Azeh2 was endothermic in nature.

Fast Removal of Pb2+ from Aqueous Solution by Water Insoluble Konjac Glucomannan

2009 ◽  
Vol 610-613 ◽  
pp. 65-68 ◽  
Author(s):  
Xue Gang Luo ◽  
Feng Liu ◽  
Xiao Yan Lin
Keyword(s):  
Aqueous Solution ◽  
Correlation Coefficients ◽  
Konjac Glucomannan ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Equilibrium Process ◽  
Fast Removal

Konjac glucomannan (KGM) was converted into water insoluble konjac glucomannan (WIKGM) by treating with NaOH through completely deacetylated reaction. Adsorption study was carried out for the adsorption of Pb2+ from aqueous solution using water insoluble konjac glucomannan. The influences of pH, contact time, temperature and initial Pb2+ concentration on the absorbent were studied. Results of kinetic data showed that the Pb2+ adsorption rate was fast and good correlation coefficients were obtained for the pseudo second-order kinetic model. The equilibrium process was described well by the Langmuir isotherm model with maximum adsorption capacity of 9.18 mg/g on WIKGM at 25°C.

Study on Adsorption of Cu(II) on Chitosan Nanofiber Membranes

2014 ◽  
Vol 13 (05n06) ◽  
pp. 1460009 ◽  
Author(s):  
Jianhua Cao ◽  
Dongzhou Li ◽  
Weihua Liang ◽  
Dayong Wu
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Ph Effect ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Equilibrium Isotherms ◽  
Electrospinning Technique ◽  
Chitosan Nanofiber ◽  
Pseudo Second Order ◽  
Nanofiber Membranes

Chitosan nanofiber membranes by electrospinning technique were used to remove Cu ( II ) from aqueous solution. The adsorption kinetics, equilibrium isotherms, and pH effect were investigated in batch experiments. The Langmuir isotherm and pseudo second-order kinetic models agree well with the experimental data. The chitosan nanofiber membranes are effective for Cu ( II ) adsorption at pH6. Results showed that the maximum adsorption capacity of the chitosan nanofiber membranes with Cu ( II ) is 118.62 mg g-1. The chitosan nanofiber membranes can be used as an effective adsorbent for the removal of Cu ( II ) in aqueous solution due to high adsorption capacity.

scholarly journals SURFACE MODIFICATION OF CANARIUM OVATUMENGL.(PILI) SHELL AS ADSORBENT OF LEAD(Pb2+) FROM AQUEOUS SOLUTION

2021 ◽  
Author(s):  
Ernesto Jr. S. Cajucom ◽  
◽  
Lolibeth V. Figueroa ◽  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Freundlich Isotherm ◽  
Cost Effective ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Carboxylic Groups ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Surface Modified

This study was carried out to investigate the efficiency of raw pili shell (RPS) and the surface modified pili shell using EDTA (EMPS) and oxalic acid (OMPS). A comparative study on the adsorption capacity of the adsorbents was performed against lead (Pb2+) from aqueous solution. The adsorbents were characterized by FTIR, which showed higher peak of adsorption bands of carboxylic groups on the acid modified pili shells. Scanning electron microscope orSEM was also used to describe the surface morphology of the adsorbents. The linear form of Langmuir and Freundlich models were applied to represent adsorption data. The calculated equilibrium data of Pb (II) best fitted to Langmuir compare to Freundlich isotherm model with maximum adsorption capacity (qmax) of 27.03 mg/g and 45.45 mg/g using EMPS and OMPS, respectively. Kinetic sorption models were used to determine the adsorption mechanism and the kinetic data of all the adsorbents correlated (R2=1) wellwith the pseudo second order kinetic model. Among the three adsorbents, OMPS shown higher percent removal of lead compared to RPS and EMPS. The large adsorption capacity rate indicated that chemically modified pili shell in present study has great potential to be used as a cost-effective adsorbent for the removal of lead ions from the water.

Investigation of Modified Mangrove Bark on the Sorption of Oil in Water

2014 ◽  
Vol 567 ◽  
pp. 74-79 ◽  
Author(s):  
Asadpour Robabeh ◽  
Nasiman Sapari ◽  
Mohamed Hasnain Isa ◽  
Kalu Uka Orji
Keyword(s):  
Palmitic Acid ◽  
Adsorption Capacity ◽  
Sorption Capacity ◽  
Oil Spills ◽  
Low Cost ◽  
Correlation Coefficients ◽  
Kinetic Studies ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Order Kinetic Model

Today oil spills generally cause worldwide worry due to their damaging effects on environment. Use of agricultural wastes such as raw and modified mangrove barks (RhizophoraApiculata), as an abundant and low cost adsorbent for oil-products spill cleanup in aquatic systems, has been developed to control these spills. Sorption capacity can improve by modification of adsorbent. The modification significantly increased the hydrophobicity of the adsorbent. The raw mangrove bark was modified using fatty acid (Palmitic acid) to improve its adsorption capacity. Oil sorption capacity of the modified bark was studied and compared with the raw bark. Kinetic tests were conducted with a series of contact time. The kinetic studies show good correlation coefficients for a pseudo-first-order kinetic model. A correlation between surface functional groups of the adsorbent was studied by FTIR spectrum. The results gave the maximum adsorption capacity of 2640.00 ± 2.00 mg/g for Palmitic acid treated bark (PTB). The prepared adsorbent revealed the potential to use as a low-cost adsorbent in oil-spill clean-up.

Adsorption of leather dye onto activated carbon prepared from bottle gourd: equilibrium, kinetic and mechanism studies

2013 ◽  
Vol 67 (1) ◽  
pp. 201-209 ◽  
Author(s):  
Edson Luiz Foletto ◽  
Caroline Trevisan Weber ◽  
Diego Silva Paz ◽  
Marcio Antonio Mazutti ◽  
Lucas Meili ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Intraparticle Diffusion ◽  
Second Order ◽  
Adsorption Kinetic ◽  
Bottle Gourd ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Equilibrium Data

Activated carbon prepared from bottle gourd has been used as adsorbent for removal of leather dye (Direct Black 38) from aqueous solution. The activated carbon obtained showed a mesoporous texture, with surface area of 556.16 m2 g−1, and a surface free of organic functional groups. The initial dye concentration, contact time and pH significantly influenced the adsorption capacity. In the acid region (pH 2.5) the adsorption of dye was more favorable. The adsorption equilibrium was attained after 60 min. Equilibrium data were analyzed by the Langmuir, Freundlich, Dubinin–Radushkevich and Temkin isotherm models. The equilibrium data were best described by the Langmuir isotherm, with maximum adsorption capacity of 94.9 mg g−1. Adsorption kinetic data were fitted using the pseudo-first-order, pseudo-second-order, Elovich and intraparticle diffusion models. The adsorption kinetic was best described by the second-order kinetic equation. The adsorption process was controlled by both external mass transfer and intraparticle diffusion. Activated carbon prepared from bottle gourd was shown to be a promising material for adsorption of Direct Black 38 from aqueous solution.

scholarly journals Facile preparation and highly efficient sorption of magnetic composite graphene oxide/Fe3O4/GC for uranium removal

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Aili Yang ◽  
Zhijun Wang ◽  
Yukuan Zhu
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
High Efficiency ◽  
Removal Rate ◽  
Low Cost ◽  
Hydrothermal Carbonization ◽  
Maximum Adsorption Capacity ◽  
Magnetic Composite ◽  
Order Kinetic

AbstractIn this work, we reported for the first time a novel magnetic composite graphene oxide/Fe3O4/glucose-COOH (GO/Fe3O4/GC) that was facilely prepared from glucose through the hydrothermal carbonization and further combination with graphene oxide (GO). The chemical and structural properties of the samples were investigated. By the batch uranium adsorption experiments, the magnetic composite GO/Fe3O4/GC exhibits an excellent adsorption performance and fast solid–liquid separation for uranium from aqueous solution. GO/Fe3O4/GC (the maximum adsorption capacity (Qm) was 390.70 mg g−1) exhibited excellent adsorption capacity and higher removal rate (> 99%) for U(VI) than those of glucose-COOH (GC) and magnetic GC (MGC). The effect of the coexisting ions, such as Na+, K+, Mg2+, Ca2+, and Al3+, on the U(VI) removal efficiency of GO/Fe3O4/GC was examined. The equilibrium sorption and sorption rate for the as-prepared adsorbents well fit the Langmuir model and pseudo second-order kinetic model, respectively. The thermodynamic parameters (ΔH0 = 11.57 kJ mol−1 and ΔG0 < 0) for GO/Fe3O4/GC indicate that the sorption process of U(VI) was exothermic and spontaneous. Thus, this research provides a facile strategy for the preparation of the magnetic composite with low cost, high efficiency and fast separation for the U(VI) removal from aqueous solution.

scholarly journals Study on Adsorption of Nickel and Methylene Blue in Aqueous Solution by Magnetic Carboxylate-Rich Carbon

2021 ◽  
Vol 37 (2) ◽  
Author(s):  
Doan Van Dat ◽  
Nguyen Hoai Thuong ◽  
Tran Thi Kieu Ngan ◽  
Le Thi Thanh Nhi ◽  
Dao My Uyen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Capacity ◽  
Ph Value ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
High Adsorption ◽  
Endothermic Process ◽  
High Adsorption Capacity

In this study, magnetic carboxylate-rich carbon material (Fe3O4@CRC) was synthesized via a low-temperature carbonization method and applied as an adsorbent for adsorption of Ni(II) ions and methylene blue (MB) in aqueous solution. The synthesized Fe3O4@CRC was characterized by various techniques (XRD, FTIR, FE-SEM, TEM, EDX, VSM, and BET). The adsorption kinetics, isotherms, thermodynamics, and the effects of key adsorption factors, including the pH value, initial adsorbate concentration, contact time, adsorbent dose and temperature were investigated in detail. The results showed that Fe3O4@CRC exhibited a high adsorption capacity for MB and Ni(II) with the maximum adsorption capacity of 187.26 mg/g and 106.75 mg/g, respectively. The adsorption of MB and Ni(II) on Fe3O4@CRC was a spontaneous and endothermic process, and was best described with the first-order kinetic model, Freundlich (for MB) and Langmuir (for Ni(II)) isotherm models. In addition, Fe3O4@CRC could maintain a high adsorption capacity after many consecutive cycles. Therefore, the Fe3O4@CRC material can be used as a highly efficient adsorbent for the removal of heavy metals and dyes from wastewater due to the advantages of high adsorption performance, easy separation, and good reusability.  

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