scholarly journals Removal Characteristics of Organic Pollutants from Eutrophic Raw Water by Biological Pretreatment Reactors

2016 ◽  
Vol 2016 ◽  
pp. 1-7
Author(s):  
Guangcan Zhu ◽  
Zhonglian Yang ◽  
Xiwu Lu

Two biological contact oxidation reactors, cascade biofilm reactor (CSBR) and one-step biofilm reactor (OSBR), were used in this paper for pretreatment of eutrophic water from Lake Taihu in China. The CSBR was more effective and stable for eutrophic water treatment than OSBR, in terms of extracellular microcystin-LR,chlorophyll-a, DOC, and biodegradable dissolved organic carbon (BDOC) removal. Removal efficiencies of extracellular microcystin-LR andchlorophyll-a were 75.8% and 59.7% in CSBR and 60.5% and 53.0% after 2 h in OSBR. CSBR had much higher removal efficiency (34.3%) than OSBR (22.7%) for DOC, and CSBR could remove 67% BDOC, accounting for 34% of total DOC in source water. 11.5% of DOC was removed through means other than biological degradation, such as biofilm adsorption and bioflocculation. In CSBR at 5.5~13°C, 57.5% of atrazine was removed at 2 h hydraulic retention time, with background concentration of 136.5 ng/L. Meanwhile, removal efficiencies of three phthalic acid esters (PAEs) (dimethyl phthalate, di-(2-ethylhexyl) phthalate, and di-n-butyl phthalate) were 78.7%, 52.4%, and 85.3%, respectively. Only 35.2% of polycyclic aromatic hydrocarbons (PAHs) could be removed by CSBR with initial concentration of 21.5 μg/L. The results indicated that CSBR is effective in low-molecular-weight organic pollution pretreatment and provides benefits in terms of effluent quality.

1999 ◽  
Vol 40 (4-5) ◽  
pp. 107-114 ◽  
Author(s):  
A. Kornmüller ◽  
U. Wiesmann

The continuous ozonation of polycyclic aromatic hydrocarbons (PAH) was studied in a two stage ozonation system followed by serobic biological degradation. The highly condensed PAH benzo(e)pyrene and benzo(k)fluoranthene were oxidized selectiely in synthetic oil/water-emulsions. The influence of the ozone mass transfer gas-liquid on the reaction rate of benzo(k)fluoranthene was studied for process optimization. The dissolved ozone concentration is influenced by temperature to a higher degree than the reaction rate of PAH. In dependence on pH, PAH oxidation occurs by a direct reaction with ozone inside the oil droplets. Two main ozonation products of benzo(e)pyrene were quantified at different retention times during ozonation and their transformation could be shown in the biological treatment step.


2003 ◽  
Vol 47 (11) ◽  
pp. 189-194 ◽  
Author(s):  
Q.J. Yu ◽  
H. Xu ◽  
D. Yao ◽  
P. Williams

Biofilm (or attached growth) reactors can be effectively used to treat organic wastewater from various industries such as food processing industry. They have a number of advantages including high organic loading rates (OLRs) and improved operational stability. A flexible fibre biofim reactor (FFBR) has been developed for efficient and cost effective treatment of food processing wastewater. In the process, simple flexible fibre packing with a very high specific surface area is used as support for microorganisms. The COD removal efficiencies for a range of OLRs have been studied. The FFBR can support an increasingly high OLR, but with a corresponding decrease in the COD removal efficiency. Therefore, a two-stage FFBR was developed to increase the treatment efficiency for systems with high OLRs. Experimental results indicated that a high overall COD removal efficiency could be achieved. At an influent COD of about 2700 mg/L and an OLR of 7.7 kgCOD/m3d, COD removal efficiencies of 76% and 82% were achieved in the first and the second stage of the reactor, respectively. The overall COD removal efficiency was 96%. Therefore, even for wastewater samples with high organic strength, high quality treated effluents could be readily achieved by the use of multiple stage FFBRs.


2003 ◽  
Vol 48 (4) ◽  
pp. 53-60 ◽  
Author(s):  
E. Trably ◽  
D. Patureau ◽  
J.P. Delgenes

Anaerobically stabilized sewage sludge has potential to partially substitute synthetic fertilizers. The main risk with the recycling of urban sludge on agricultural soils is the accumulation of unwanted products, such as trace metals and organic micropollutants. In this context, the polycyclic aromatic hydrocarbons (PAHs) are particularly monitored because of their toxic properties at low concentrations and their high resistance to biological degradation. The aim of the present study was to optimize PAHs removal during anaerobic digestion of contaminated sewage sludge. Thirteen PAHs were monitored in laboratory-scale anaerobic bioreactors under mesophilic (35°C) and thermophilic (55°C) methanogenic conditions. Abiotic losses were statistically significant for the lightest PAHs, such as fluorene, phenanthrene and anthracene. It was shown that PAH removal was due to a specific biological activity. Biological PAHs removal was significantly enhanced by an increase of the temperature from 35°C to 55°C, especially for the heaviest PAHs. Bioaugmentation experiment was also performed by addition of a PAH-adapted bacterial consortium to a non-acclimated reactor. Significant enhancement of PAHs removal was observed. It was finally shown that PAH removal efficiencies and methanogenic performances were closely linked. The rate of biogas production may be used as an indicator of bacterial activity on PAH removal.


2012 ◽  
Vol 518-523 ◽  
pp. 2431-2438
Author(s):  
Ying Zhang Wang ◽  
Shang Hua Zhang ◽  
Chang Qing Pang ◽  
Jie Li

Luffa cylindrical sponge and plastic sponge were used as carriers in sequencing batch biofilm reactor (SBBR) for sewage treatment in this paper. The removals of suspended solid (SS), chemical oxygen demand (COD) and NH3-N in sewage were studied. The average removal efficiencies of SS, COD and NH3-N with luffa cylindrical sponge were 96%, 89% and 90%, respectively, while these with plastic sponge were 94%, 83% and 80%, respectively. As a natural, cheap and environment friendly biocarrier, luffa cylindrical sponge was easy to get a biofilm with enriched microbes during the first few days of sewage treatment. It was much more suitable as a carrier than the plastic sponge for SBBR.


2004 ◽  
Vol 50 (10) ◽  
pp. 107-114 ◽  
Author(s):  
C. Di Iaconi ◽  
F. Bonemazzi ◽  
A. Lopez ◽  
R. Ramadori

This paper reports the results of an investigation aimed at evaluating the laboratory-scale performance of an innovative process for treating tannery wastewater. In this process, biological degradation, carried out in a sequencing batch biofilm reactor (SBBR), is combined with chemical oxidation by ozone. Tannery wastewater treatment was carried out, at laboratory scale, on a real primary effluent coming from a centralised plant treating wastewater produced by a large tannery district in Northern Italy. SBBR performance both without and with ozonation, was assessed with very satisfactory results. In particular, in the latter instance the recorded COD, TKN and TSS average removals, (96%), (92%) and (98%) respectively, allowed the maximum allowable concentration values fixed by the Italian regulation in force to be achieved without any additional polishing step. During the investigation biofilm properties (biofilm concentration and biofilm density) and flow dynamics aspects (head loss, shear stress, bed porosity) were also studied. A major feature of the process is that, with or without ozonation, it was characterised by very low specific sludge production (0.05 kgVSS/kgCODremoved) and high biofilm density (i.e. 87-122 gVSS/Lsludge) both contributing to a rather high biofilm concentration (i.e. 31-44 gTSS/Lfilter).


Author(s):  
Junwon Park ◽  
Changsoo Kim ◽  
Youngmin Hong ◽  
Wonseok Lee ◽  
Hyenmi Chung ◽  
...  

In this study, we analyzed 27 pharmaceuticals in liquid and solid phase samples collected from the unit processes of four different sewage treatment plants (STPs) to evaluate their distribution and behavior of the pharmaceuticals. The examination of the relative distributions of various categories of pharmaceuticals in the influent showed that non-steroidal anti-inflammatory drugs (NSAIDs) were the most dominant. While the relative distribution of antibiotics in the influent was not high (i.e., 3%–5%), it increased to 14%–30% in the effluent. In the four STPs, the mass load of the target pharmaceuticals was reduced by 88%–95% mainly in the biological treatment process, whereas the ratio of pharmaceuticals in waste sludge to those in the influent (w/w) was only 2%. In all the STPs, the removal efficiencies for the stimulant caffeine, NSAIDs (acetaminophen, naproxen, and acetylsalicylic acid), and the antibiotic cefradine were high; they were removed mainly by biological processes. Certain compounds, such as the NSAID ketoprofen, contrast agent iopromide, lipid regulator gemfibrozil, and antibiotic sulfamethoxazole, showed varying removal efficiencies depending on the contribution of biodegradation and sludge sorption. In addition, a quantitative meta-analysis was performed to compare the pharmaceutical removal efficiencies of the biological treatment processes in the four STPs, which were a membrane bioreactor (MBR) process, sequencing batch reactor (SBR) process, anaerobic–anoxic–oxic (A2O) process, and moving-bed biofilm reactor (MBBR) process. Among the biological processes, the removal efficiency was in the order of MBR > SBR > A2O > MBBR. Among the tertiary treatment processes investigated, powdered activated carbon showed the highest removal efficiency of 18%–63% for gemfibrozil, ibuprofen, ketoprofen, atenolol, cimetidine, and trimethoprim.


2010 ◽  
Vol 61 (12) ◽  
pp. 3017-3025 ◽  
Author(s):  
X. L. Shi ◽  
X. B. Hu ◽  
Z. Wang ◽  
L. L. Ding ◽  
H. Q. Ren

A laboratory-scale anaerobic-anoxic-aerobic-moving bed biofilm reactor (A1-A2-O-MBBR) system was undertaken to treat coke plant wastewaters from two different factories (wastewater A and B). Wastewater B had higher BOD5/COD ratio and COD/TN ratio than wastewater A. The effects of reflux ratios on COD, TN and NH3-N removals were studied. Results indicated that, with the reflux ratio increased from 2 to 5, COD removals of wastewater A and wastewater B increased from 57.4% to 72.6% and 78.2% to 88.6%, respectively. Meanwhile, TN removals were also increased accompanying reflux ratio rise, from 53.1% to 74.4% for wastewater A and 64.2% to 83.5% for wastewater B. At the same reflux ratio, compared with wastewater A, higher COD and TN removal efficiencies were observed in wastewater B, which had higher BOD5/COD and COD/TN ratio. Reflux ratio had no significant influence on NH3-N removal; 99.0% of the overall NH3-N removal efficiency was achieved by the system for both coke plant wastewaters at any tested reflux ratio. MBBR was effective in NH3-N removal, and about 95% of the NH3-N was removed in the MBBR.


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