scholarly journals Effect of Graphene Nanosheets on the Morphology, Crystallinity, and Thermal and Electrical Properties of Super Tough Polyamide 6 Using SEBS Compounds

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Farzaneh Alirezaei Hoor ◽  
Jalil Morshedian ◽  
Shervin Ahmadi ◽  
Mohammad Rakhshanfar ◽  
Alireza Bahramzadeh

Super tough polyamide 6 was prepared by using SEBS and effect of SEBS-g-MA as a compatibilizer of PA6/SEBS matrix on mechanical properties was investigated. Thus super tough polyamide 6/graphene nanocomposites were produced using graphene nanosheets (GNs) through the melt compounding method. To compare the effectiveness of graphene, effects of graphite and carbon black (the other carbon structures) are also studied on the same matrix. The effects of graphene on crystallinity, improvements of morphology, and thermal and electrical properties of the nanocomposites were researched and compared with similar samples of graphite and carbon black. Due to the reaction between the maleic anhydride groups of SEBS and amine groups of nylon chains during the melt mixing process, super tough polyamide 6 was produced with high impact and tensile strength. The most important results of this study can be noted as an increase in the electrical conductivity and thermal stability by adding graphene to PA6/SEBS blend. Also the effect of graphene compatibility on PA6/SEBS/SEBS-g-MA blend was investigated with studying morphology.

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1454
Author(s):  
Pietro Russo ◽  
Francesca Cimino ◽  
Antonio Tufano ◽  
Francesco Fabbrocino

The growing demand for lightweight and multifunctional products in numerous industrial fields has recently fuelled a growing interest in the development of materials based on polymer matrices including graphene-like particles, intrinsically characterized by outstanding mechanical, thermal, and electrical properties. Specifically, with regard to one of the main mass sectors, which is the automotive, there has been a significant increase in the use of reinforced polyamides for underhood applications and fuel systems thanks to their thermal and chemical resistance. In this frame, polyamide 6 (PA6) composites filled with graphene nanoplatelets (GNPs) were obtained by melt-compounding and compared in terms of thermal and mechanical properties with the neat matrix processed under the same condition. The results of the experimental tests have shown that the formulations studied so far offer slight improvements in terms of thermal stability but much more appreciable benefits regarding both tensile and flexural parameters with respect to the reference material. Among these effects, the influence of the filler content on the strength parameter is noteworthy. However, the predictable worsening of the graphene sheet dispersion for GNPs contents greater than 3%, as witnessed by scanning electron images of the tensile fractured sections of specimens, affected the ultimate performance of the more concentrated formulation.


2012 ◽  
Vol 621 ◽  
pp. 31-34 ◽  
Author(s):  
Pei Pei Zhang ◽  
Ke Ying Zhu ◽  
Li Qiang Su ◽  
Ru Xiao

In this paper, graphene was obtained by Oxidation-reduction method. The obtained graphene was characterized by XRD and FTIR. On this basis, graphene/polyamide 6(PA6) composites were prepared by melt compounding. The well-dispersed graphene nanosheets in PA6 matrix was investigated by SEM. The properties were characterized by XRD, DSC and TGA. The results showed that the α-phase of polyamide 6 induced into γ-phase by adding graphene. The crystallization temperature and the crystallinity of composites have been increased in some degree. Besides, the composite has a higher thermal stability.


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