scholarly journals Enhanced Photocatalytic Activity of BiOBr/ZnO Heterojunction Semiconductors Prepared by Facile Hydrothermal Method

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Xiangchao Meng ◽  
Lingyun Jiang ◽  
Weiwen Wang ◽  
Zisheng Zhang

Hexagonal wurtzite pure ZnO and BiOBr-ZnO composites were synthesized by facile hydrothermal method. The amount of BiOBr as dopant was adjusted from 5 wt.% to 75 wt.%, and correspondingly the morphologies and crystal structures of the as-prepared composites were measured and discussed. Specifically, according to XRD patterns and SEM images, the main crystalline structure of ZnO was not destroyed after doping, but growth of ZnO crystals was inhibited by doping BiOBr. Meanwhile, the optical properties of the composites were measured by the diffuse reflectance spectra (DRS). The band gap of composites was also calculated using the classical Tauc equation and it was found to be around 3.0 eV. In the test of photocatalytic activation, the ZnO-BiOBr photocatalysts exhibited high photocatalytic efficiencies in the degradation ofRhodamine B(RhB) under visible-light irradiation. It was ascribed to not only the small size of crystalline, but also the reduction in the recombination rate of the photogenerated carriers for the enhancement effect of p-n heterojunction. This work sheds light on improving the photocatalytic performance by establishing the heterojunction and contributes to the development of a commercially competitive photocatalyst.

2013 ◽  
Vol 423-426 ◽  
pp. 163-166 ◽  
Author(s):  
Bao Wei Cao ◽  
Yun Hua Xu

Bi2WO6 doped with iodine ions were synthesized using hydrothermal method and their photocatalytic activities to degrade Rhodamine B (RhB) under visible-light was investigated. The successful incorporation of I ions in Bi2WO6 was proved by XRD and XPS. UV-vis absorption spectra results show that I ion was successfully doped into Bi2WO6 and a red shift for I-doped Bi2WO6 appeared when compared to pure Bi2WO6. The photocatalytic activities of the photocatalysts were evaluated by the decolorization of RhB under visible-light irradiation. The results showed that the photocatalytic activity of I-doped Bi2WO6 was much higher than the undoped Bi2WO6.


RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 42581-42588 ◽  
Author(s):  
Zahra Hosseinpour ◽  
Sara Hosseinpour ◽  
Malik Maaza ◽  
Alice Scarpellini

Co2+ and Ho3+ doped CuS nanostructures have been synthesized by a hydrothermal method. The nature of dopants influence the morphology, photocatalytic performance and the band gap values.


2016 ◽  
Vol 35 (9) ◽  
pp. 853-856 ◽  
Author(s):  
Yi Shen ◽  
Xiaomin Wang ◽  
Guifu Zuo ◽  
Fengfeng Li ◽  
Yanzhi Meng

AbstractMonoclinic BiVO4 photocatalyst was successfully synthesized by hydrothermal method under appropriate temperature. The photocatalytic performance of BiVO4 was improved by calcining at appropriate temperature. The structural and morphological properties of the synthesized BiVO4 photocatalysts were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. It is confirmed that the photocatalytic activity of the prepared catalysts was evaluated by the photodegradation of RhB under visible-light irradiation. BiVO4 calcined under appropriate temperature exhibited higher photocatalytic activity than uncalcined BiVO4 under visible light irradiation because calcination might effectively increases the purity of monoclinic bismuth vanadate.


2018 ◽  
Vol 47 (30) ◽  
pp. 10046-10056 ◽  
Author(s):  
Xiang Li ◽  
Mengyuan Su ◽  
Guifen Zhu ◽  
Kaige Zhang ◽  
Xia Zhang ◽  
...  

In this study, a novel few-layer WS2/Bi2MoO6 heterojunction with greatly enhanced visible light photocatalytic performance was synthesized via a facile hydrothermal method.


2022 ◽  
Author(s):  
Juan Qiu ◽  
Yingdi Wang ◽  
Xiang Liu

In our part, we synthesized the CuBi2O4/ BiOCl p-n heterojunction photocatalyst by convenient one-pot hydrothermal method. And the morphology, crystal phase, element composition and optical properties of as-synthesized CuBi2O4/BiOCl were...


Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 756
Author(s):  
Zhengru Zhu ◽  
Songlin Han ◽  
Yongqiang Cao ◽  
Junchao Jiang

In this study, novel photocatalysts MVO4/g-C3N4 (M = La, Gd) were prepared by the hydrothermal method, through which different loading amounts of 10–50%MVO4 and g-C3N4 were mixed and ultrasonically oscillated to gain heterojunction catalysts. All the samples were characterized by XRD, SEM, TEM, FT-IR, XPS, Us-vis, and PL to ensure the successful integration of LaVO4 and GdVO4 with g-C3N4. The obtained results showed that MVO4/g-C3N4 could effectually improve the separation efficiency of photogenerated carriers during the photodegradation process, thus improving the photodegradation efficiency, while among them, 40%GdVO4/g-C3N4 showed the best photocatalytic performance and degradation of tetracycline hydrochloride, reaching up to 91% for 3 h, which was 3.64 times higher than pristine g-C3N4. From the discussed results above, the possible mechanism of the photodegradation process was put forward. This study supplies a promising method to gain g-C3N4-based photocatalysts for antibiotics removal.


2021 ◽  
Vol 50 (9) ◽  
pp. 3253-3260 ◽  
Author(s):  
Shan Zhao ◽  
Junbiao Wu ◽  
Yan Xu ◽  
Xia Zhang ◽  
Yide Han ◽  
...  

CdS/Ag2S/g-C3N4 ternary composites showed excellent photocatalytic performance toward H2 evolution. Their improved photocatalytic activity could be attributed not only to the synergic effect, but also to the introduction of Ag2S.


2016 ◽  
Vol 45 (41) ◽  
pp. 16519-16525 ◽  
Author(s):  
Jiao Xue ◽  
Runwei Wang ◽  
Zongtao Zhang ◽  
Shilun Qiu

C, N co-modified niobium pentoxide (Nb2O5) nanoneedles have been successfully synthesized via a facile hydrothermal method with Niobium Chloride (NbCl5) as a precursor and triethylamine as both the carbon and nitrogen source.


2018 ◽  
Vol 38 ◽  
pp. 02014
Author(s):  
Yu Zhang ◽  
Jian Gu ◽  
Mengqi Zhang

The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.


Sign in / Sign up

Export Citation Format

Share Document