scholarly journals Effect of Nanostructure on Thermal Conductivity of Nanofluids

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Saba Lotfizadeh ◽  
Themis Matsoukas

The presence of colloidal particles is known to increase the thermal conductivity of base fluids. The shape and structure of the solid particles are important in determining the magnitude of enhancement. Spherical particles—the only shape for which analytic theories exist—produce the smallest enhancement. Nonspherical shapes, including clusters formed by colloidal aggregation, provide substantially higher enhancements. We conduct a numerical study of the thermal conductivity of nonspherical structures dispersed in a liquid at fixed volume fraction in order to identify structural features that promote the conduction of heat. We find that elongated structures provide high enhancements, especially if they are long enough to create a solid network (colloidal gel). Cross-linking further enhances thermal transport by directing heat in multiple directions. The most efficient structure is the one formed by hollow spheres consisting of a solid shell and a core filled by the fluid. In both dispersed and aggregated forms, hollow spheres provide enhancements that approach the theoretical limit set by Maxwell’s theory.

Author(s):  
Adam C. Gladen ◽  
Susan C. Mantell ◽  
Jane H. Davidson

A thermotropic material is modeled as an absorbing, thin slab containing anisotropic scattering, monodisperse, spherical particles. Monte Carlo ray tracing is used to solve the governing equation of radiative transfer. Predicted results are validated by comparison to the measured normal-hemispherical reflectance and transmittance of samples with various volume fraction and relative index of refraction. A parametric study elucidates the effects of particle size parameter, scattering albedo, and optical thickness on the normal-hemispherical transmittance, reflectance, and absorptance. The results are interpreted for a thermotropic material used for overheat protection of a polymer solar absorber. For the preferred particle size parameter of 2, the optical thickness should be less than 0.3 to ensure high transmittance in the clear state. To significantly reduce the transmittance and increase the reflectance in the translucent state, the optical thickness should be greater than 2.5 and the scattering albedo should be greater than 0.995. For optical thickness greater than 5, the reflectance is asymptotic and any further reduction in transmittance is through increased absorptance. A case study is used to illustrate how the parametric study can be used to guide the design of thermotropic materials. Low molecular weighted polyethylene in poly(methyl methacrylate) is identified as a potential thermotropic material. For this material and a particle radius of 200 nm, it is determined that the volume fraction and thickness should equal 10% and 1 mm, respectively.


2011 ◽  
Vol 133 (11) ◽  
Author(s):  
K. Hari Krishna ◽  
Harish Ganapathy ◽  
G. Sateesh ◽  
Sarit K. Das

Nanofluids, solid-liquid suspensions with solid particles of size of the order of few nanometers, have created interest in many researchers because of their enhancement in thermal conductivity and convective heat transfer characteristics. Many studies have been done on the pool boiling characteristics of nanofluids, most of which have been with nanofluids containing oxide nanoparticles owing to the ease in their preparation. Deterioration in boiling heat transfer was observed in some studies. Metallic nanofluids having metal nanoparticles, which are known for their good heat transfer characteristics in bulk regime, reported drastic enhancement in thermal conductivity. The present paper investigates into the pool boiling characteristics of metallic nanofluids, in particular of Cu-H2O nanofluids, on flat copper heater surface. The results indicate that at comparatively low heat fluxes, there is deterioration in boiling heat transfer with very low particle volume fraction of 0.01%, and it increases with volume fraction and shows enhancement with 0.1%. However, the behavior is the other way around at high heat fluxes. The enhancement at low heat fluxes is due to the fact that the effect of formation of thin sorption layer of nanoparticles on heater surface, which causes deterioration by trapping the nucleation sites, is overshadowed by the increase in microlayer evaporation, which is due to enhancement in thermal conductivity. Same trend has been observed with variation in the surface roughness of the heater as well.


2012 ◽  
Vol 693 ◽  
pp. 345-366 ◽  
Author(s):  
L. Jibuti ◽  
S. Rafaï ◽  
P. Peyla

AbstractIn this paper, we conduct a numerical investigation of sheared suspensions of non-colloidal spherical particles on which a torque is applied. Particles are mono-dispersed and neutrally buoyant. Since the torque modifies particle rotation, we show that it can indeed strongly change the effective viscosity of semi-dilute or even more concentrated suspensions. We perform our calculations up to a volume fraction of 28 %. And we compare our results to data obtained at 40 % by Yeo and Maxey (Phys. Rev. E, vol. 81, 2010, p. 62501) with a totally different numerical method. Depending on the torque orientation, one can increase (decrease) the rotation of the particles. This results in a strong enhancement (reduction) of the effective shear viscosity of the suspension. We construct a dimensionless number $\Theta $ which represents the average relative angular velocity of the particles divided by the vorticity of the fluid generated by the shear flow. We show that the contribution of the particles to the effective viscosity can be suppressed for a given and unique value of $\Theta $ independently of the volume fraction. In addition, we obtain a universal behaviour (i.e. independent of the volume fraction) when we plot the relative effective viscosity divided by the relative effective viscosity without torque as a function of $\Theta $. Finally, we show that a modified Faxén law can be equivalently established for large concentrations.


2014 ◽  
Vol 490-491 ◽  
pp. 109-112
Author(s):  
De Wen Cao ◽  
Jia Huan Wang ◽  
Yu Qing Sun ◽  
Ke Hua Chen ◽  
Cheng Ming Yu ◽  
...  

In the present work, the effect of the microstructure of AlSi6Mg2 alloy on its macro-rheological behavior of the steady AlSi6Mg2 alloy is investigated. Specifically, the effect of particle size, packing mode and degree of the agglomeration of particles are analyzed. It can be seen that the apparent viscosity decreases with increasing the particle size (d) ifdis between a few μm and 200 μm, while the solid particle size does not affect viscosity except this region. This theoretical prediction is in qualitatively agreement with the experimental data. The trend of the variation of the average agglomerate size with the particle size is the same as the one of viscosity. The packing mode of solid particles in agglomerate is closely related to the solid volume fraction and the characteristics of the alloy system. Subsequently, the state of agglomeration of solid particles which determines the rheology of semisolid AlSi6Mg2 alloy, while the external flow conditions (such as shear rate) influence the viscosity by changing the state of agglomeration. Consequently, the particle size, the packing mode and the average agglomerate size have different effect on the rheological behavior of SSMS.


Author(s):  
Tao Wang ◽  
Xinwei Wang ◽  
Haiping Hong ◽  
Zhongyang Luo ◽  
Kefa Cen

In this work, extensive equilibrium molecular dynamics simulations are conducted to study the shear viscosity of nanocolloidal dispersion. Strong oscillation of the pressure tensor autocorrelation function is observed. The computational domain contains solvent of liquid argon at 143.4 K and spherical particles with volume fraction of 3%. By studying the effect of the particle size, particle density, and acoustic impedance, it is found for the first time that the stress wave scattering/reflecting at the liquid-particle interface due to acoustic mismatch plays a critical important role in the oscillation of pressure tensor autocorrelation function. The Brownian motion/vibration of solid particles is considered to have little effect on the oscillation of pressure tensor autocorrelation function curve except the frequency. And when the particle size is comparable with the wavelength of stress wave, the diffraction of stress wave happens at the interface that will also weaken the oscillation of pressure tensor autocorrelation function.


Author(s):  
P. Bhattacharya ◽  
S. K. Saha ◽  
A. Yadav ◽  
P. E. Phelan ◽  
R. S. Prasher

A nanofluid is a fluid containing suspended solid particles, with sizes of the order of nanometers. Normally the fluid has a low thermal conductivity compared to the suspended particles. Therefore introduction of these particles into the fluid increases the effective thermal conductivity of the system. It is of interest to predict the effective thermal conductivity of such a nanofluid under different conditions like varying particle volume fraction, varying particle size, changing fluid conductivity or changing fluid viscosity, especially since only limited experimental data are available. Also, some controversy exists about the role of Brownian motion in enhancing the nanofluid’s thermal conductivity. We have developed a novel technique to compute the effective thermal conductivity of a nanofluid using Brownian dynamics simulation, which has the advantage of being computationally less expensive than molecular dynamics. We obtain the contribution of the nanoparticles towards the effective thermal conductivity using the equilibrium Green-Kubo method. Then we combine that with the thermal conductivity of the base fluid to obtain the effective thermal conductivity of the nanofluid, and thus are able to show that the Brownian motion contributes greatly to the thermal conductivity.


Author(s):  
Li Yuzheng ◽  
Liu Qianfeng ◽  
Bo Hanliang

The steam flow is simulated by FLUENT. The Lagrange-Euler method is used to simulate the droplet-laden flow in wave-type separators. Two-way coupling method is used to study the influence of the momentum transfer between droplets and carrier-phase in wave-type plate separators. A group of the trajectories of droplets with different diameters are performed in wave-type plate separator flow field. The result shows that the momentum transfer has tiny impact on the behaviors of droplets in a low velocity flow. However, the momentum transfer affects the behaviors of droplets more significantly with rising flow velocity. The one-way coupling method overestimates the diffusion of droplets. In addition, the momentum transfer affects the total pressure loss more significantly with rising volume fraction. The conclusion verifies the importance of the momentum transfer in droplet-laden flows, which could be used to simulate the behavior of droplets moving in a separator.


2012 ◽  
Vol 585 ◽  
pp. 14-18 ◽  
Author(s):  
Alok Agrawal ◽  
Alok Satapathy

A numerical simulation of the heat-transfer process within polypropylene matrix composite filled with micro-sized aluminium particles using Finite Element Method is proposed in this paper. Three-dimensional spheres-in-cube lattice array models are constructed to simulate the microstructure of composite materials with aluminium content ranging from about 1.5 to 42 vol% and the effective thermal conductivities of the composites are estimated. A commercially available finite-element package ANSYS is used for this numerical analysis. The result shows that the effective thermal conductivity (Keff) increases with increase in the volume fraction of the aluminium in the composites. The simulated values are compared with calculated Keff values obtained from other established correlations such as Rule-of-Mixture (ROM), Maxwell’s model and with published experimental results. This study reveals that the incorporation of aluminium particles results in enhancement of thermal conductivity of polypropylene thereby increasing its heat transportation capability. It is found that with incorporation of about 42 vol% of 100 micron sized aluminium particles thermal conductivity of the composite increases from 0.239 W/m-K to 0.875 W/m-K. This study also shows that the effect of particle size with same volume percentage on thermal conductivity is marginal.


1995 ◽  
Vol 48 (10) ◽  
pp. 650-658 ◽  
Author(s):  
J. R. Philip

We review the phenomenological approach, on the macroscopic or Darcy scale, to flow and volume change in clays and other swelling media. The formulation represents the generalization to media subject to volume change of the well-established phenomenological approach to flow in non-swelling media primarily established in the context of soil physics. The one-dimensional generalization to swelling media is straightforward, and may be usefully applied to practical one-dimensional systems, including three-component systems with solid particles, water, and air. On the other hand, the further generalizations to two- and three-dimensional systems have not yet been developed fully convincingly. Difficult questions include the mode of stress transmission and the tensorial stress-strain relations in multidimensional and multi-component systems. One means of gaining insight into these questions for media of high colloid content (such as clays) is through relevant solutions of the Poisson-Boltzmann equation governing electrical double-layer interactions in dense arrays of colloidal particles. These solutions give pertinent information on both the macroscopic and the microscopic scales. We present a progress report on work along these lines.


2013 ◽  
Vol 438-439 ◽  
pp. 329-332 ◽  
Author(s):  
Mei Jun Lu ◽  
Su Yang ◽  
Xue Zhen Feng ◽  
Shun Bo Zhao

In order to determine the thermal conductivity of the concrete for building reinforced concrete composite wall, the fine-aggregate concrete for the thermal insulation layer and the composite concrete for the reinforced concrete wall were made from the ordinary concrete by in-situ wet-sieving techniques. The compositions of these three kinds of fresh concrete were determined, which expressed by the volume fraction of crushed stone and the volume ratio of crushed stone to mortar. The thermal conductivity of concrete was measured by the one-dimensional steady heat flow meter. Based on the tests, the changes of thermal conductivity of concrete affected by the volume fraction of crushed stone and the volume ratio of crushed stone to mortar were analyzed. The correlation analysis shows that the correlation of the thermal conductivity is better with the volume ratio of crushed stone to mortar. The formula for forecasting the thermal conductivity of concrete is proposed.


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