scholarly journals Impact of Layer-by-Layer Self-Assembly Clay-Based Nanocoating on Flame Retardant Properties of Sisal Fiber Cellulose Microcrystals

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Chun Wei ◽  
Sihua Zeng ◽  
Yuyuan Tan ◽  
Wu Wang ◽  
Jian Lv ◽  
...  
Keyword(s):  
Zeta Potential ◽  
Flame Retardant ◽  
Self Assembly ◽  
Cationic Polyelectrolyte ◽  
Sisal Fiber ◽  
Layer By Layer ◽  
Gravimetric Analysis ◽  
Assembly Method ◽  
Flame Retardant Properties ◽  
Xrd Patterns

The renewable cationic polyelectrolyte chitosan (CH) and anionic nanomontmorillonite (MMT) layers were alternately deposited on the surface of sisal fiber cellulose microcrystals (SFCM) via layer-by-layer (LBL) self-assembly method. The structure and properties of the composites were characterized by zeta potential, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectrometer (FTIR), microcalorimeter (MCC), and so forth. The zeta potential results show that the cellulose microcrystalline surface charge reversed due to the adsorption of CH and MMT nanoplatelets during multilayer deposition. MMT characteristic diffraction peaks appear in XRD patterns of SFCM(CH/MMT)5and SFCM(CH/MMT)10composites. Additionally, FESEM reveals that the SFCM(CH/MMT)10surface is covered with a layer of material containing Si, which has been verified by elemental analysis. TGA results show that the initial decomposition (weight loss of 5%) temperature of SFCM(CH/MMT)5is increased by 4°C compared to that of pure SFCM. On the other hand, carbon residue percentage of SFCM(CH/MMT)10is 25.1%, higher than that of pure SFCM (5.4%) by 19.7%. Eventually, it is testified by MCC measurement that CH/MMT coating can significantly reinforce the flame retardant performance of SFCM.

Formation of H2Ti2O5·H2O nanotube-based hybrid coating on bamboo fibre materials through layer-by-layer self-assembly method for an improved flame retardant performance

Cellulose ◽  
2019 ◽  
Vol 26 (4) ◽  
pp. 2729-2741
Author(s):  
Chenmin Zheng ◽  
Sili Wen ◽  
Ziling Teng ◽  
Chunlu Ye ◽  
Qiaoling Chen ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Self Assembly ◽  
Hybrid Coating ◽  
Layer By Layer ◽  
Assembly Method ◽  
Bamboo Fibre

scholarly journals Layer-by-layer self-assembly preparation and desalination performance of graphene oxide membrane

2021 ◽  
Author(s):  
Jun Hu ◽  
Zuoguo Yang
Keyword(s):  
Graphene Oxide ◽  
Self Assembly ◽  
Composite Membranes ◽  
Rejection Rate ◽  
Cationic Polyelectrolyte ◽  
Layer By Layer ◽  
Operating Pressure ◽  
High Flux ◽  
Assembly Method ◽  
Multi Stage

Abstract Unlike previous utilization of ultrafiltration membranes as supporters of graphene oxide (GO) composite membranes, this study first adopts microporous nylon membranes as substrates. The cationic polyelectrolyte/GO composite membranes are prepared by the layer-by-layer self-assembly method via electrostatic attraction. The introduction of polycations between nanochannels in the GO membranes effectively suppresses the swelling and improves the stability of the membranes. It is found that the polyelectrolytes' charge density and the surface potential of the composite membranes jointly determine the membranes' properties. The experimental results show that the novel GO membranes can obtain high flux and considerable desalination performance under low operating pressure. Typically, the salt rejection rate reaches 66.8% for 1.0 g/L MgSO4, and the flux is 39.8 L·m−2·h−1·bar−1. Benefitting from the GO composite membranes keeping similar retention for both high and low concentration salt solutions, the ideal desalination performance could be obtained through multi-stage processes on the premise of ensuring high flux, which is more suitable for industry.

Hydrogen-Bonding Layer Protecting Polyelectrolyte Capsules and Its Mechanical Property Study with Atomic Force Microscope

2008 ◽  
Vol 8 (6) ◽  
pp. 2996-3002 ◽  
Author(s):  
Liqin Ge ◽  
Xing Wang ◽  
Long Ba ◽  
Zhongze Gu
Keyword(s):  
Hydrogen Bonding ◽  
Atomic Force Microscope ◽  
Elastic Deformation ◽  
Self Assembly ◽  
Laser Scanning ◽  
Confocal Laser ◽  
Bonding Layer ◽  
Layer By Layer ◽  
Assembly Method ◽  
Atomic Force

The hydrogen-bonding multilayered polyelectrolyte capsules with sizes around 6 μm were fabricated by layer-by-layer self-assembly method. The morphology of the obtained capsules was observed with Scanning Electron Microscope (SEM), Confocal Laser Scanning Microscope (CLSM) and Atomic Force Microscope (AFM), respectively. The elastic properties of the capsules were studied with AFM. The capsule was pressed by cantilever with different lengths, a glass bead glued at the end of the cantilever. The force curves were measured on the capsule in air. The Young's modulus of the capsule was obtained (E = 170 MPa for the loading). Results show that this model can predict the elastic deformation of the microcapsule. The accuracy of the elastic deformation of polymer capsule can be ensured using a cantilever of mediate stiffness. Our results show that the existence of the hydrogen-bonding layer makes the multilayered polyelectrolyte harder in comparison with the pure multilayered polyelectrolyte capsules.

Fabrication of montmorillonite and titanate nanotube based coatings via layer-by-layer self-assembly method to enhance the thermal stability, flame retardancy and ultraviolet protection of polyethylene terephthalate (PET) fabric

RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 53625-53634 ◽  
Author(s):  
Ying Pan ◽  
Wei Wang ◽  
Haifeng Pan ◽  
Jing Zhan ◽  
Yuan Hu
Keyword(s):  
Thermal Stability ◽  
Polyethylene Terephthalate ◽  
Flame Retardancy ◽  
Self Assembly ◽  
Layer By Layer ◽  
Pet Fabric ◽  
Thermal Oxidative Stability ◽  
Titanate Nanotube ◽  
Assembly Method ◽  
Ultraviolet Protection

Montmorillonite and titanate nanotube based coatings have been prepared through LbL self-assembly method, in order to enhance the thermal and thermal-oxidative stability, flame retardancy and UV protection of polyethylene terephthalate fabric.

scholarly journals UV-Curing of Novel Tri-functional Melamine-phosphate Oligomer: An Effect of Coating With Polyurethane Acrylate Towards Mechanical, Thermal And Flame Retardant Properties

2021 ◽  
Author(s):  
Pundalik Mali ◽  
Narendra Sonawane ◽  
Nilesh Pawar ◽  
Vikas Patil
Keyword(s):  
Flame Retardant ◽  
Thermo Gravimetric Analysis ◽  
Galvanized Steel ◽  
Gravimetric Analysis ◽  
Pencil Hardness ◽  
Uv Curable ◽  
Polyurethane Coatings ◽  
Melamine Phosphate ◽  
Polyurethane Acrylate ◽  
Flame Retardant Properties

Abstract A novel melamine-phosphate trifunctional acrylate MPTO) was successfully synthesized via simple cyclization of hexamethylolmelamine (HMM) with phosphorous oxychloride (POCl3) followed by addition reaction of hydroxyethylmethacrylate (HEMA). The molecular structure of MPTO was identified by FTIR and 1H-NMR, 13C-NMR, and GC-MS spectra. The synthesized MPTO oligomer was impregnated with polyurethane acrylate to make the various formulation of UV-cured coatings. The polyurethanes-MPTO oligomers were coated on wood and galvanized steel panels. The properties of UV-cured PU-MPTO were studied by differential scanning calorimeter (DSC), while their crystallinity by X-ray diffraction analysis (XRD). The thermo-gravimetric analysis (TGA) exhibited a high char yield of 18.4% at 800 °C. Moreover, coating films show prominent flame retardancy with UL-94 V-0 rating and maximum limiting index value (LOI) values of 34.8%, which are much higher than the common polyurethane coatings. The polyurethane coatings cured with MPTO exhibited excellent mechanical properties were estimated various tests such as adhesion, pencil hardness, solvent resistance, flexibility, and corrosion test. The coating performance revealed that MPTO improves the mechanical, thermal, and flame retardant properties because their unique structure contains melamine-phosphate moiety and long aliphatic chains of an acrylate ester. These high-performance melamine-based UV-curable coatings are promising for extensive applications.

Layer-by-layer Assembly Polyethylenimine/phytic Acid Coating With Gradient Structure for High-Efficiency and Durable Flame Retardant Cotton Fabric With Good Physical and Mechanical Properties

2021 ◽  
Author(s):  
Xinhua Liu ◽  
Hailong Liu ◽  
Yinchun Fang
Keyword(s):  
Physical Properties ◽  
Flame Retardant ◽  
Cotton Fabric ◽  
High Efficiency ◽  
Cotton Fabrics ◽  
Gradient Structure ◽  
Layer By Layer ◽  
Assembly Method ◽  
Lbl Assembly ◽  
Coated Cotton

Abstract In this study, intumescent flame retardant coating of polyethylenimine/phytic acid (PEI/PA) with gradient structure was constructed on cotton fabric through facile layer-by-layer (LBL) assembly method. The LOI value of coated cotton fabric reached over 40% indicating excellent flame retardancy. Reasonable controlling the LBL assembly process of PEI/PA coating brought less influence to the physical properties of cotton fabrics. And the coated cotton fabric revealed good flame retardant washing durability. Thermogravimetric analysis results of coated cotton fabrics showed that PEI/PA flame retardant coating changed the thermal decomposition process and promoted char formation revealing the obviously condensed phase flame retardant action. SEM images of char residues revealed that PEI/PA flame retardant coating promoted to form the intumescent flame retardant (IFR) char layer showing obvious IFR action. This research provides novel strategy for the development of high-efficiency flame retardant cotton fabric with good durability and physical properties using simple LBL assembly method.

A wearable and highly sensitive strain sensor based on a polyethylenimine–rGO layered nanocomposite thin film

2017 ◽  
Vol 5 (31) ◽  
pp. 7746-7752 ◽  
Author(s):  
Xueliang Ye ◽  
Zhen Yuan ◽  
Huiling Tai ◽  
Weizhi Li ◽  
Xiaosong Du ◽  
...  
Keyword(s):  
Thin Film ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Self Assembly ◽  
Strain Sensor ◽  
Layer By Layer ◽  
Nanocomposite Thin Film ◽  
Assembly Method ◽  
Reduced Graphene ◽  
Highly Sensitive

A novel strain sensor based on reduced graphene oxide with ultra-sensitive and ultra-durable performance was fabricated by the chemical layer-by-layer self-assembly method.

Functionalization of membrane surface by layer-by-layer self-assembly method for dyes removal

2020 ◽  
Vol 134 ◽  
pp. 140-148 ◽  
Author(s):  
Eduarda Freitas Diogo Januário ◽  
Natália de Camargo Lima Beluci ◽  
Taynara Basso Vidovix ◽  
Marcelo Fernandes Vieira ◽  
Rosângela Bergamasco ◽  
...  
Keyword(s):  
Self Assembly ◽  
Membrane Surface ◽  
Layer By Layer ◽  
Assembly Method ◽  
Dyes Removal
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