scholarly journals High-Density Polyethylene and Heat-Treated Bamboo Fiber Composites: Nonisothermal Crystallization Properties

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Yanjun Li ◽  
Lanxing Du ◽  
Zhen Zhang ◽  
Qinglin Wu
Keyword(s):  
High Density Polyethylene ◽  
Three Dimensional ◽  
Treatment Temperature ◽  
High Density ◽  
Model Parameters ◽  
Scanning Calorimetry ◽  
Kinetic Rate Constant ◽  
Nonisothermal Crystallization ◽  
Heat Treated ◽  
Bamboo Fibers

The effect of heat-treated bamboo fibers (BFs) on nonisothermal crystallization of high-density polyethylene (HDPE) was investigated using differential scanning calorimetry under nitrogen. The Avrami-Jeziorny model was used to fit the measured crystallization data of the HDPE/BF composites and to obtain the model parameters for the crystallization process. The heat flow curves of neat HDPE and HDPE/heat-treated BF composites showed similar trends. Their crystallization mostly occurred within a temperature range between 379 K and 399 K, where HDPE turned from the liquid phase into the crystalline phase. Values of the Avrami exponent (n) were in the range of 2.8~3.38. Lamellae of neat HDPE and their composites grew in a three-dimensional manner, which increased with increased heat-treatment temperature and could be attributed to the improved ability of heterogeneous nucleation and crystallization completeness. The values of the modified kinetic rate constant (KJ) first increased and then decreased with increased cooling rate because the supercooling was improved by the increased number of nucleating sites. Heat-treated BF and/or a coupling agent could act as a nucleator for the crystallization of HDPE.

Tuning the Mechanical Properties of High-Density Polyethylene by ECAE Process

2015 ◽  
Author(s):  
Catalin Fetecau ◽  
Felicia Stan ◽  
Laurentiu Sandu ◽  
Florin Susac
Keyword(s):  
Mechanical Properties ◽  
High Density Polyethylene ◽  
Equal Channel Angular Extrusion ◽  
Morphological Changes ◽  
Longitudinal Axis ◽  
High Density ◽  
Scanning Calorimetry ◽  
Plastic Deformations ◽  
The Third ◽  
Indentation Tests

This paper investigates the ability of the equal channel angular extrusion (ECAE) process to induce morphological changes and hence tune the mechanical properties of high-density polyethylene (HDPE). In this study, differential scanning calorimetry (DSC), compression and cylindrical macro-indentation tests have been used to investigate the evolution of the mechanical properties of HDPE processed by ECAE up to four passes via route BC, i.e. counter clockwise 90° billet rotation about its longitudinal axis. It was found that the ECAE process induces significant plastic deformations with changes in the crystalline structure. The ECAE process increased the HDPE crystallinity by 10 to 15%. The number of ECAE passes has a significant effect on the magnitude of the mechanical properties especially on the elastic modulus and yield stress. Young’s modulus and yield strength decreased with increasing the number of ECAE passes and reached a stationary state after the third pass.

Tensile and flammability characterizations of corn straw slagging/high-density polyethylene composites

2019 ◽  
Vol 33 (11) ◽  
pp. 1466-1477
Author(s):  
Qingfa Zhang ◽  
Wenyu Lu ◽  
Liang Zhou ◽  
Donghong Zhang ◽  
Hongzhen Cai ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Flame Retardant ◽  
High Density Polyethylene ◽  
Oxygen Index ◽  
High Density ◽  
Corn Straw ◽  
Scanning Calorimetry ◽  
Scanning Electron

Biocomposites were prepared with corn straw slagging (CSS) and high-density polyethylene (HDPE) at four loading levels (10, 20, 30, and 40 wt%) by extrusion method. CSS/HDPE composites were tested by tension, oxygen index meter, differential scanning calorimetry, X-ray diffraction, and the scanning electron microscopy. The scanning electron microscopy showed that CSS was dispersed uniformly in the HDPE matrix and strong interfacial interaction was achieved, which had an important influence on the tensile strength of the composites. The tensile strength of the composites could be improved with proper increase of CSS and reached maximum value at 30 wt% content. Furthermore, the addition of CSS played an important role in improving the flame-retardant ability of CSS/HDPE composites, and the limited oxygen index was 31.26% at 40 wt% content, good flame-retardant effect achieved.

Influence of wood surface chemistry on the tensile and flexural properties of heat-treated mangrove/high-density polyethylene composites

2019 ◽  
Vol 76 (12) ◽  
pp. 6467-6486 ◽  
Author(s):  
Ganiyat Olusola Adebayo ◽  
Aziz Hassan ◽  
Rosiyah Yahya ◽  
Normasmira Abd Rahman ◽  
Ruth Lafia-Araga
Keyword(s):  
Surface Chemistry ◽  
Wood Surface ◽  
High Density Polyethylene ◽  
High Density ◽  
Flexural Properties ◽  
Heat Treated ◽  
Polyethylene Composites

Sepiolite as a nanofiller to improve mechanical and thermal behavior of recycled high-density polyethylene

2020 ◽  
Vol 36 (3) ◽  
pp. 185-195 ◽  
Author(s):  
Negin Farshchi ◽  
Yalda K Ostad
Keyword(s):  
Thermal Behavior ◽  
High Density Polyethylene ◽  
Low Cost ◽  
Process Condition ◽  
Softening Temperature ◽  
High Density ◽  
Plastic Pollution ◽  
Scanning Calorimetry ◽  
Melt Flow Rate ◽  
Recycled Hdpe

Regarding the current demand for controlling plastic pollution, recycling of polymer sounds a promising solution. However, recycling causes mechanical and thermal shortcomings in polymers. Addition of nanoparticles to recycled materials may overcome these shortcomings. Nanocomposites can be achieved either by blending or through polymerization. Sepiolite as a nanoparticle enhances the thermal properties of polymers. In this study, the effect of sepiolite as a nanoparticle has been investigated on the thermal and mechanical behavior of recycled high-density polyethylene (HDPE). Hardness, density, Vicat softening temperature, melt flow rate (MFR), and differential scanning calorimetry has been investigated on recycled HDPE containing different amount of sepiolite. Results showed that both the amount of recycled HDPE and the sepiolite content affect the mechanical and thermal behavior of samples. Increasing the amount of recycled component resulted in increasing of MFR, a slight increase in density, and decrease in Vicat softening point, hardness, melting temperature, and degree of crystallization. As an opposite effect of these to factors on crystallinity of HDPE, sepiolite content has better effects to be considered separately for each recycle content. Sepiolite can be introduced as a low-cost reinforcement filler in recycling industry for tuning new compositions based on process condition, or vice versa.

Stress-Induced Crystal-to-Crystal Transformations in High-Density Polyethylene-Layered Silicate Nanocomposites: A Spectroscopic Study

2005 ◽  
Vol 59 (9) ◽  
pp. 1148-1154 ◽  
Author(s):  
Spiros Tzavalas ◽  
Vasilis G. Gregoriou
Keyword(s):  
High Density Polyethylene ◽  
Mechanical Strain ◽  
Layered Silicate ◽  
High Density ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Polyethylene Matrix ◽  
Dsc Measurements ◽  
Infrared Measurements ◽  
Ft Ir

High-density polyethylene (HDPE)–clay nanocomposites have been prepared using the melt intercalation technique. Organically modified montmorillonite at various loadings (0.5–7%) was used as a nanoadditive. Fourier transform infrared spectroscopy (FT-IR) was utilized for the first time to monitor the stress-induced crystal-to-crystal transformations of the polyethylene matrix with respect to the clay loading as well as to the degree of mechanical strain. In addition, polarized infrared measurements revealed information on both the orientation and the stress-induced distortion of the crystals. It was concluded that the crystal-to-crystal transformations are hindered by the presence of the clay, which also prevented the crystals from orienting even at low clay loadings (1%). Finally, X-ray diffraction (XRD) and differential scanning calorimetry (DSC) measurements confirmed the presence of the stress-induced crystalline structures in agreement with the infrared measurements.

Investigations into the mechanical, morphological and thermal analyses of friction stir processing of high-density polyethylene composites

2016 ◽  
Vol 232 (7) ◽  
pp. 1193-1200 ◽  
Author(s):  
Jicheng Gao ◽  
Chao Li ◽  
Yifu Shen
Keyword(s):  
Tensile Strength ◽  
Friction Stir Processing ◽  
High Density Polyethylene ◽  
Thermal Analyses ◽  
Experimental Tests ◽  
Traverse Speed ◽  
High Density ◽  
Scanning Calorimetry ◽  
Friction Stir ◽  
Polyethylene Composites

The aim of this work is to fabricate the high-density polyethylene–copper composites by submerged friction stir processing at different traverse speeds. The scanning electron microscopy is used to analyze the distribution of microstructure and particles. The experimental results indicated that the macrostructure morphology, microstructure and tensile strength vary depending on the traverse speed. Compared with the pure high-density polyethylene, Cu-filled polymer composites showed lower tensile strength and higher microhardness. The maximal values of the tensile strength and microhardness were achieved at traverse speeds of 30 and 15 mm/min, respectively. The thermal properties of Cu-filled high-density polyethylene composites were studied by differential scanning calorimetry. The crystalline content of the composites was decreased due to the addition of copper. From the experimental tests, it can be concluded that submerged fiction stir processing has a great potential for producing polymer–metal composites.

scholarly journals Graphene Nanoplatelet-Reinforced Poly(vinylidene fluoride)/High Density Polyethylene Blend-Based Nanocomposites with Enhanced Thermal and Electrical Properties

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 361 ◽  
Author(s):  
Kartik Behera ◽  
Mithilesh Yadav ◽  
Fang-Chyou Chiu ◽  
Kyong Rhee
Keyword(s):  
Isothermal Crystallization ◽  
High Density Polyethylene ◽  
Vinylidene Fluoride ◽  
High Density ◽  
Scanning Calorimetry ◽  
Melt Mixing ◽  
Graphene Nanoplatelet ◽  
Polyethylene Blend ◽  
Poly Vinylidene Fluoride ◽  
Mixing Method

In this study, a graphene nanoplatelet (GNP) was used as a reinforcing filler to prepare poly(vinylidene fluoride) (PVDF)/high density polyethylene (HDPE) blend-based nanocomposites through a melt mixing method. Scanning electron microscopy confirmed that the GNP was mainly distributed within the PVDF matrix phase. X-ray diffraction analysis showed that PVDF and HDPE retained their crystal structure in the blend and composites. Thermogravimetric analysis showed that the addition of GNP enhanced the thermal stability of the blend, which was more evident in a nitrogen environment than in an air environment. Differential scanning calorimetry results showed that GNP facilitated the nucleation of PVDF and HDPE in the composites upon crystallization. The activation energy for non-isothermal crystallization of PVDF increased with increasing GNP loading in the composites. The Avrami n values ranged from 1.9–3.8 for isothermal crystallization of PVDF in different samples. The Young’s and flexural moduli of the blend improved by more than 20% at 2 phr GNP loading in the composites. The measured rheological properties confirmed the formation of a pseudo-network structure of GNP-PVDF in the composites. The electrical resistivity of the blend reduced by three orders at a 3-phr GNP loading. The PVDF/HDPE blend and composites showed interesting application prospects for electromechanical devices and capacitors.

scholarly journals Influence of Backfill Compaction on Mechanical Characteristics of High-Density Polyethylene Double-Wall Corrugated Pipelines

2019 ◽  
Vol 2019 ◽  
pp. 1-24 ◽  
Author(s):  
Hongyuan Fang ◽  
Peiling Tan ◽  
Bin Li ◽  
Kangjian Yang ◽  
Yunhui Zhang
Keyword(s):  
Finite Element ◽  
High Density Polyethylene ◽  
Three Dimensional ◽  
Local Buckling ◽  
Element Model ◽  
High Density ◽  
Model Matching ◽  
Exterior Wall ◽  
Finite Element Software ◽  
Hdpe Pipe

For flexible pipelines, the influence of backfill compaction on the deformation of the pipe has always been the focus of researchers. Through the finite element software, a three-dimensional soil model matching the exterior wall corrugation of the high-density polyethylene pipe was skillfully established, and the “real” finite element model of pipe-soil interaction verified the accuracy through field test. Based on the model, the strain distribution at any position of the buried HDPE pipe can be obtained. Changing the location and extent of the loose backfill, the strain and radial displacement distributions of the interior and exterior walls of the HDPE pipe under different backfill conditions when external load applied to the foundation were analyzed, and the dangerous parts of the pipe where local buckling and fracture may occur were identified. It is pointed out that when the backfill is loose, near the interface between the backfill loose region and the well-compacted region, the maximum circumferential strain occurs frequently, the exterior wall strain is more likely to increase greatly on the region near crown or invert, the interior wall strains increase in amplitude at springline, and the location of the loose region has a greater influence on the strain of the pipe than the size of the loose area.

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