scholarly journals Phosphorus Sorption Kinetics in Reclaimed Lignite Mine Soils under Different Age Stands ofRobinia pseudoacaciaL. in Northeast Germany

2015 ◽  
Vol 2015 ◽  
pp. 1-19 ◽  
Author(s):  
Anna Slazak ◽  
Dirk Freese
Keyword(s):  
Robinia Pseudoacacia ◽  
Sorption Kinetics ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Short Rotation ◽  
Lignite Mine ◽  
Significant Difference ◽  
Saturation Factor ◽  
Plant Available P ◽  
Total P

The objectives of the work were to study phosphorus (P) dynamics in postmining soils under short rotation coppices at different stages ofRobinia pseudoacaciaL. growth (2, 3, 4, and 14 years old). From the results obtained, the amount of total P, total organic P, plant available P, and P stock increased with increasing age ofR. pseudoacacia. However, values were very low compared to that recommended for optimum plant growth, reflecting a general deficit in P. Additionally, the P sorption and desorption processes were investigated. The total P sorption capacity obtained from the laboratory experiments was on average, 2.5 times greater for soils under the oldestR. pseudoacaciathan values measured at the younger sites. Values of P saturation factor (α) were comparatively lower compared to that reported in the literature. This may be attributed primarily to the less P saturation of the postmining soils, coupled with rather small contents of oxalate ironFeoxand aluminiumAlox(sum of 47 mmol kg−1). Results demonstrate significant difference between 2 and 14 years oldR. pseudoacacia; thus establishing of short rotation coppice (SRC) on degraded marginal sites may be a valuable method of soil reclamations.

scholarly journals Phosphorus Sorption Behavior of Torrefied Agricultural Byproducts under Sonicated Versus Non-Sonicated Conditions

2017 ◽  
Vol 6 (4) ◽  
pp. 1 ◽  
Author(s):  
Jehangir H. Bhadha ◽  
Stephen P. Jennewein ◽  
Raju Khatiwada
Keyword(s):  
Crop Production ◽  
Phosphorus Concentration ◽  
Sorption Behavior ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Concentration Maximum ◽  
Major Nutrients ◽  
P Leaching ◽  
Palm Fronds ◽  
Total P

The application of agrichar derived from organic feedstocks has the potential to improve soil fertility and crop production by providing major nutrients like phosphorus (P) to the crop, and in some cases also reducing P leaching. The effect of agrichar on the leaching of P in soils is not uniform and can vary depending on the type of agrichar and amount applied. The objective of this study was to (i) evaluate the behavior of four agrichars (rice hulls RH, palm fronds PF, horse bedding HB, and bagasse BG) for their ability to retain/release P and (ii) determine the effect of wet sonication on P sorption behavior. The feedstocks were torrefied at 500 °C using a top-lit updraft gasifier and used in multiple batch incubation experiments to evaluate equilibrium phosphorus concentration, maximum P sorption capacity (Smax), and adsorption/desorption potential. Both, RH (12.6 g kg-1) and HB (11.5 g kg-1) contained 10-15 times higher total P concentration than PF and BG, rendering RH and HB as potentially suitable products to be used as soil amendments. However, this initial P content of the agrichar seemed to have an overriding effect on the P sorption behavior of the agrichar. PF had Smax of 676 (±127) mg kg-1 for the non-sonicated agrichar, and 237 (±91) mg kg-1 following sonication. There was significant increase in CEC for PF and BG agrichar upon sonication. PF agrichar increased from 27 (±3) cmolc kg-1 to 41 (±4) cmolc kg-1 with sonication. Similarly, BG agrichar CEC increased from 21 (±2) cmolc kg-1 to 45 (±5) cmolc kg-1 with sonication. Initial total P and Ca concentration and their ratios was found to play significant roles on P adsorption and desorption. Major cations like Ca, Fe, Al and Mn are found to act as active sorption site for phosphorus controlling its fate and mobility along with compounding effects of other physicochemical parameters.

scholarly journals Soil phosphorus sorption properties in different fertilization systems

2019 ◽  
Vol 65 (No. 2) ◽  
pp. 78-82 ◽  
Author(s):  
Ewa Szara ◽  
Tomasz Sosulski ◽  
Magdalena Szymańska
Keyword(s):  
Binding Energy ◽  
Soil Phosphorus ◽  
Sorption Properties ◽  
Phosphorus Sorption ◽  
Sorption Coefficient ◽  
P Sorption ◽  
P Content ◽  
Sorption Parameters ◽  
Total P

The study aimed at the evaluation of the accumulation and vertical distribution of different forms of phosphorus (P) in reference to phosphorus sorption properties subject to mineral (NPK), mineral-organic (NPK + M), and organic (M) fertilisation. It was carried out in a long-term experimental field in Skierniewice (Central Poland) conducted since 1923 under rye monoculture. Total P content in the M and NPK soil profile was similar and lower than in the NPK + M soil. The content of organic P in A<sub>p</sub> and E<sub>et</sub> horizons of both manured soils was similar and higher than in the NPK soil. The Langmuir P sorption maximum (S<sub>max</sub>) in the studied soils ranged from 39.7 to 90 mg P/kg, while the Freundlich P sorption coefficient a<sub>F</sub> ranged from 6.9 to 41.9 mg P/kg. Higher variability of parameters related to the binding energy from the Lanqmuir (k) and Freundlich (a<sub>F</sub>) equations was determined between soil horizons than between the fertilisation systems. Nonetheless, in M and NPK + M soils, sorption parameters a<sub>F</sub> and S<sub>max</sub> and binding energy (k, b<sub>F</sub>) were considerably lower than in the NPK soil. The content of water extracted P in manured soils was higher than in the NPK soil.

scholarly journals Phosphorus Sorption in Soils Overlying Basement Complex Rock, Alluvium, Coastal Plain Sand and Imo Shale Parent Materials

2021 ◽  
pp. 41-54
Author(s):  
Robert Ehi Orhue ◽  
Adams Emomu ◽  
Esohe Obazuaye ◽  
Aimiesomon Michael Erhayimwen ◽  
Ajayi Gboyega Bepo
Keyword(s):  
Coastal Plain ◽  
Soil Samples ◽  
Phosphorus Sorption ◽  
Basement Complex ◽  
Parent Materials ◽  
P Sorption ◽  
Benin City ◽  
Randomized Design ◽  
Significant Difference ◽  
Sorption Index

This study aimed at evaluating phosphorus (P) sorption capacities in Soils overlying basement complex Rock (A), Alluvium (B), coastal plain sand (C) and Imo shale (C) parent materials. Completely randomized design was used to collect soil samples from 5 depths in 3 replications from Idanre, Koko, NIFOR and Uhomora in Nigeria. Samples collected were analyzed in the central analytical laboratory of the Nigerian Institute for Oil palm Research, Benin City, Nigeria between march 2016 and September 2017. 60 soil samples were equilibrated in 25 ml of 0.01 M CaCl2 containing various concentration of P as KH2PO4  to give 0, 50, 100, 150, 200 and 250 mg/L P for 24 hours (h)  at room temperature 25 ± 2 oC. Genstat statistical package was used to calculate Analysis of variance, correlation of Phosphorus sorption index (PSI) with soil properties, coefficient of variation, means separation and Least Significant difference (LSD). The rate and %P adsorption increased with increasing concentration of P added to the soils. The P sorption capacities of the soils considering Freundlich model decreased in the order of D > B > C >A. %P adsorbed was highest in D soils with value of 15.19% for 100 mg/kg P added. The PSI correlated with organic carbon r = -0.58 P ≤ .05 in C soils, r = 0.44 P ≤ .05 in D soils, it also correlated with N r = -0.58 P ≤ .05 in C Soils, K r = 0.57 P ≤ .05, r = 0.49 P ≤ .05 in C and D soils respectively. D soils sorbed more P than other soils hence the D soils will require more P fertilization to attain optimum P concentration in soil solution, however further study is required to determine the form of P sorbed by these parent materials.

scholarly journals Biochar Chemistry in a Weathered Tropical Soil: Kinetics of Phosphorus Sorption

Agriculture ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 295
Author(s):  
Marina Moura Morales ◽  
Nicholas Brian Comerford ◽  
Maurel Behling ◽  
Daniel Carneiro de Abreu ◽  
Iraê Amaral Guerrini
Keyword(s):  
Mineral Soil ◽  
Soil Surface ◽  
Kinetic Studies ◽  
Inorganic Phosphorus ◽  
Initial Reaction ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Published Research ◽  
Kinetics Of

The phosphorus (P) chemistry of biochar (BC)-amended soils is poorly understood. This statement is based on the lack of published research attempting a comprehensive characterization of biochar’s influence on P sorption. Therefore, this study addressed the kinetic limitations of these processes. This was accomplished using a fast pyrolysis biochar made from a mix of waste materials applied to a highly weathered Latossolo Vermelho distrofico (Oxisol) from São Paulo, Brazil. Standard method (batch method) was used. The sorption kinetic studies indicated that P sorption in both cases, soil (S) and soil-biochar (SBC), had a relatively fast initial reaction between 0 to 5 min. This may have happened because adding biochar to the soil decreased P sorption capacity compared to the mineral soil alone. Presumably, this is a result of: (i) Inorganic phosphorus desorbed from biochar was resorbed onto the mineral soil; (ii) charcoal particles physically covered P sorption locations on soil; or (iii) the pH increased when BC was added SBC and the soil surface became more negatively charged, thus increasing anion repulsion and decreasing P sorption.

scholarly journals Influence of soil pH on inorganic phosphorus sorption and desorption in a humid brazilian Ultisol

2005 ◽  
Vol 29 (5) ◽  
pp. 685-694 ◽  
Author(s):  
Shinjiro Sato ◽  
Nicholas Brian Comerford
Keyword(s):  
Soil Ph ◽  
Ph Value ◽  
Tropical Soils ◽  
Inorganic Phosphorus ◽  
Phosphorus Sorption ◽  
Tropical Regions ◽  
P Sorption ◽  
Phosphorus Desorption ◽  
P Desorption ◽  
P Bioavailability

Liming is a common practice to raise soil pH and increase phosphorus (P) bioavailability in tropical regions. However, reports on the effect of liming on P sorption and bioavailability are controversial. The process of phosphorus desorption is more important than P sorption for defining P bioavailability. However few studies on the relationship between soil pH and P desorption are available, and even fewer in the tropical soils. The effects of soil pH on P sorption and desorption in an Ultisol from Bahia, Brazil, were investigated in this study. Phosphorus sorption decreased by up to 21 and 34 % with pH increases from 4.7 to 5.9 and 7.0, respectively. Decreasing Langmuir K parameter and decreasing partition coefficients (Kd) with increasing pH supported this trend. Phosphorus desorption was positively affected by increased soil pH by both the total amount of P desorbed and the ratio of desorbed P to initially sorbed P. A decreased K parameter and increased Kd value, particularly at the highest pH value and highest P-addition level, endorsed this phenomenon. Liming the soil had the double effect of reducing P sorption (up to 4.5 kg ha-1 of remaining P in solution) and enhancing P desorption (up to 2.7 kg ha-1 of additionally released P into solution).

Phosphorus sorption and nitrogen transformation in two soils treated with piggery wastewater

Soil Research ◽  
2002 ◽  
Vol 40 (2) ◽  
pp. 335 ◽  
Author(s):  
I. R. Phillips
Keyword(s):  
Cation Exchange ◽  
Root Zone ◽  
Sandy Loam ◽  
Sorption Kinetics ◽  
Land Application ◽  
Piggery Wastewater ◽  
Wastewater Disposal ◽  
P Sorption ◽  
High Affinity ◽  
Irrigated Soils

Land application of piggery wastewater has the potential to contaminate receiving water bodies due to the presence of elevated concentrations of nitrogen (N) and phosphorus (P). This paper investigates P sorption and N transformation using soil from 2 wastewater disposal sites in south-east Queensland. Soil from Site 1 was classified as a clay (Vertosol) and soil from Site 2 was classified as a sandy loam (Sodosol). Soil was collected from wastewater disposal (irrigated) and non-disposal (non-irrigated) areas of each site. Nutrient sorption kinetics and transformation were studied by reacting each soil with either wastewater or an inorganic salt solution over a period of 21 days. Solution P concentrations decreased with time for all soils. These changes were greatest during the early stage of the study (&lt;10 days), after which time solution P concentrations remained relatively stable. Concentrations of solution P tended to remain higher in irrigated than non-irrigated soils. This was attributed to a loss of high-affinity sorption sites due to past wastewater additions. Cation exchange (for times &lt;3 days) and nitrification (for times &gt;3 days) were found to be the primary mechanisms responsible for decreases in solution ammonium (NH4-N) over the 21-day period. Phosphorus and NH4-N sorption isotherms were determined using a leaching procedure, and the data were adequately described (r2 &gt;0.95) by the Freundlich equation. Irrigated samples generally sorbed less P than non-irrigated soils. This was attributed to the loss of high-affinity P sorption sites due to previous wastewater additions. Cation exchange and competition between added and resident cations for the exchange sites was found to govern NH4-N sorption by these soils. Results from this study suggest that long-term land application of piggery wastewater may encourage leaching of N and P from the plant root-zone in soils with limited capacity to retain these nutrients. Appropriate management strategies to minimise these losses need to be developed to avoid degradation of the receiving soil and&sol;or water environments. sorption kinetics, nitrification, ammonium, nitrate.

A comparison of some surface soil phosphorus tests that could be used to assess P export potential

Soil Research ◽  
2007 ◽  
Vol 45 (5) ◽  
pp. 397 ◽  
Author(s):  
David Nash ◽  
Murray Hannah ◽  
Kirsten Barlow ◽  
Fiona Robertson ◽  
Nicole Mathers ◽  
...  
Keyword(s):  
Organic P ◽  
Soil Tests ◽  
Soil P ◽  
Olsen P ◽  
P Sorption ◽  
P Loss ◽  
Extractable P ◽  
Soil P Tests ◽  
Total P ◽  
Water Extractable

Phosphorus (P) exports from agricultural land are a problem world-wide and soil tests are often used to identify high risk areas. A recent study investigated changes in soil (0–20 mm), soil water and overland flow in 4 recently laser-graded (<1 year) and 4 established (laser-graded >10 years) irrigated pastures in south-eastern Australia before and after 3 years of irrigated dairy production. We use the results from that study to briefly examine the relationships between a series of ‘agronomic’ (Olsen P, Colwell P), environmental (water-extractable P, calcium chloride extractable P, P sorption saturation, and P sorption), and other (total P, organic P) soil P tests. Of the 2 ‘agronomic’ soil P tests, Colwell P explained 91% of the variation in Olsen P, and Colwell P was better correlated with the other soil tests. With the exception of P sorption, all soil P tests explained 57% or more of the total variation in Colwell P, while they explained 61% or less of Olsen P possibly due to the importance of organic P in this soil. Variations in total P were best explained by the organic P (85%), Calcium chloride extractable P (83%), water-extractable P (78%), and P sorption saturation (76%). None of the tests adequately predicted the variation in P sorption at 5 mg P/L equilibrating solution concentration. The results of this limited study highlight the variability between soil P tests that may be used to estimate P loss potential. Moreover, these results suggest that empirical relationships between specific soil P tests and P export potential will have limited resolution where different soil tests are used, as the errors in the relationship between soil test P and P loss potential are compounded by between test variation. We conclude that broader study is needed to determine the relationships between soil P tests for Australian soils, and based on that study a standard protocol for assessing the potential for P loss should be developed.

Phosphorus sorption and chemical characteristics of lightweight aggregates (LWA)-potential filter media in treatment wetlands

1997 ◽  
Vol 35 (5) ◽  
pp. 103-108 ◽  
Author(s):  
T. Zhu ◽  
P. D. Jenssen ◽  
T. Mæhlum ◽  
T. Krogstad
Keyword(s):  
Sorption Capacity ◽  
Metal Content ◽  
Exchange Capacity ◽  
Chemical Characteristics ◽  
Phosphorus Sorption ◽  
Filter Media ◽  
Total Metal Content ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Total Metal

Five light-weight aggregates (LWAs), suitable for filter media in subsurface flow constructed wetlands, were tested for potential removal of phosphorus (P). P-sorption variation is dependent on the chemical characteristics of the LWA. All LWAs exhibited high pH and high total metal content; however, P-sorption capacity varied by two orders of magnitude. Of the LWAs' chemical characteristics (total metal content, cation exchange capacity, and oxalate soluble Fe and Al), total metal content has the closest relationship with the P-sorption capacity. Among the four major metal ions (Mg, Ca, Fe and Al), Ca has the strongest correlation with the P-sorption capacity.

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