scholarly journals Investigations on the Structural and Mechanical Properties of Polyurethane Resins Based on Cu(II)phthalocyanines

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Tamer E. Youssef ◽  
Hamad Al-Turaif ◽  
AbdulAziz A. Wazzan

This work report was reported on the effect of the addition of organic filler, that is, 2(3),9(10),16(17),23(24)-octahydroxycopper(II)phthalocyanine [(OH)8CuPc] (3), on the thermal, tensile, and morphological properties of a polyurethane matrix. The mechanical and dynamic mechanical thermal tests together with microstructural characterization of CuPc/PU composites were performed. The three PU composite films containing up to 1, 15, and 30 wt% of CuPc have different behaviors in terms of their morphological issues, thermal properties, and tensile behavior in comparison with the PU film as the reference material. Very high elongations at break from 910% to 1230%, as well as high tensile strengths, illustrate excellent ultimate tensile properties of the prepared samples. The best mechanical and thermomechanical properties were found for the sample filled with 30 wt% of CuPc.

2021 ◽  
Vol 36 (2) ◽  
pp. 137-143
Author(s):  
S. A. Awad

Abstract This paper aims to describe the thermal, mechanical, and surface properties of a PVA/HPP blend whereby the film was prepared using a solution casting method. The improvements in thermal and mechanical properties of HPP-based PVA composites were investigated. The characterization of pure PVA and PVA composite films included tensile tests, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results of TGA and DSC indicated that the addition of HPP increased the thermal decomposition temperature of the composites. Mechanical properties are significantly improved in PVA/HPP composites. The thermal stability of the PVA composite increased with the increase of HPP filler content. The tensile strength increased from 15.74 ± 0.72 MPa to 27.54 ± 0.45 MPa and the Young’s modulus increased from 282.51 ± 20.56 MPa to 988.69 ± 42.64 MPa for the 12 wt% HPP doped sample. Dynamic mechanical analysis (DMA) revealed that at elevated temperatures, enhanced mechanical properties because of the presence of HPP was even more noticeable. Morphological observations displayed no signs of agglomeration of HPP fillers even in composites with high HPP loading.


1992 ◽  
Vol 280 ◽  
Author(s):  
N. David Theodore ◽  
Gordon Tam

ABSTRACTSiGe alloys have recently been of interest for fabrication of heterojunction bipolar transistors using pre-existing or modified silicon-processing technology. These devices are faster than devices using pure silicon. Because of the interest in developing SiGe device structures, various elements of processing relevant to fabrication of the devices are being investigated. One such element has been the use of thermal oxidation for isolation of SiGe devices. Utilization of the technique requires an understanding of oxidation behavior of SiGe layers under a variety of oxidation conditions. Past studies in the literature have investigated the oxidation of SiGe at atmospheric pressure or at very high pressures (∼650–1300 atmospheres). The present study investigates the wet-oxidation of SiGe structures at intermediate pressures (∼25 atmospheres) and temperatures (∼750°C). Unlike atmospheric oxidation, most of the Ge (from SiGe) remains in the oxidized silicon (SiO2) in the form of GeO2. Occasional segregation of Ge to the oxidizing interface is noted. The microstructural behavior of partially and entirely oxidized structures is presented.


2010 ◽  
Vol 24 (01n02) ◽  
pp. 136-147 ◽  
Author(s):  
SHEAU HOOI LIM ◽  
KAIYANG ZENG ◽  
CHAOBIN HE

This paper presents recent studies on the processing and characterization of epoxy-alumina nanocomposites. Nano-sized alumina particles are incorporated into epoxy resin via solvent-assisted method, so that the particles are dispersed homogeneously in the epoxy matrix. The morphologies, mechanical and thermomechanical properties of the resulting nanocomposites are studied using transmission electron microscope (TEM), conventional tensile testing and thermomechanical testing methods. TEM results show that the alumina nano-particles with a higher specific surface area tend to agglomerate. Furthermore platelet shape particles shows a better dispersion homogeneity as well as better improvement in the mechanical properties of the composites compared to the rod shape particles.


2017 ◽  
Vol 23 (2) ◽  
pp. 280-294 ◽  
Author(s):  
Mohamad Mahmoudi ◽  
Alaa Elwany ◽  
Aref Yadollahi ◽  
Scott M. Thompson ◽  
Linkan Bian ◽  
...  

2015 ◽  
Vol 830-831 ◽  
pp. 231-233 ◽  
Author(s):  
P.K. Mandal ◽  
Ravi Kant

The effect of microalloying elements in Ti-Nb-V containing high strength low alloy (HSLA) steel has been investigated in the present study. The addition of low alloying elements (such as Ti, Nb and V) and distinct heating treatment processes has been used to improve the mechanical properties of HSLA steel. The effect on the microstructure and mechanical properties of normalizing treatment (at 950°C) of as forged steel has been investigated. The microstructural characterization of microalloyed HSLA steel is carried out by using different techniques such as optical microscopy, scanning electron microscopy (SEM) etc. The hardness, tensile testing and Charpy V notch impact tests are performed to study the mechanical behaviour of the alloy. It has been concluded that the precipitation strengthening mechanism for the improvement of impact toughness due to secondary precipitates such as TiN, Ti(C, N), VN etc.


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