scholarly journals The Adsorption Capacity and Geotechnical Properties of Modified Clay Containing SSA Used as Landfill Liner-Soil Materials

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Haijun Lu ◽  
Yiqie Dong ◽  
Jixiang Li ◽  
Changhong Wang
Keyword(s):  
Compressive Strength ◽  
Hydraulic Conductivity ◽  
Adsorption Capacity ◽  
Unconfined Compressive Strength ◽  
Batch Adsorption ◽  
Landfill Liner ◽  
Modified Clay ◽  
Conductivity Increase ◽  
Chemical Solutions ◽  
Sludge Ash

The potential of clay containing 0~5% sewage sludge ash (SSA) is assessed for use as a landfill liner-soil material. Low temperature N2adsorption, batch adsorption, permeability, and unconfined compressive strength tests are performed to evaluate pore structure, adsorption capacity, hydraulic conductivity, and unconfined compressive strength of the clays. The pore size distribution of the modified clay containing SSA is mainly composed of micropores (<2 nm) and mesopores (2~7 nm). With the increasing of SSA from 0% to 5%, the adsorption capacity of Zn(II) and Cu(II) to the clay increases 37% and 273%, respectively. The hydraulic conductivity of modified clay is from 3.62 × 10−8to 2.17 × 10−8 cm/s. At SSA = 3%, the unconfined compressive strength of the clay reaches the maximum value of 601.1 kPa. After the clay containing SSA is contaminated by acid and alkali chemical solutions, the amount of mesopores and hydraulic conductivity increase. The adsorption capacity and unconfined compressive strength of contaminated clay decrease about 2∼44% and 25.7∼38.2%, respectively. The modified clay containing SSA can meet the adsorption and geotechnical requirement of landfill liners.

scholarly journals The Adsorption Capacity, Pore Structure, and Thermal Behavior of the Modified Clay Containing SSA

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Haijun Lu ◽  
Qian Zhang ◽  
Yiqie Dong ◽  
Jixiang Li ◽  
Xiong Zhang
Keyword(s):  
Adsorption Capacity ◽  
Batch Adsorption ◽  
Barrier Material ◽  
Sewage Sludge Ash ◽  
Soil Material ◽  
Landfill Liner ◽  
Modified Clay ◽  
Chemical Solutions ◽  
Sludge Ash ◽  
Adsorption Concentration

Sewage sludge ash (SSA) was created by burning municipal sludge. The potential of clay containing 1 or 3 or 5% SSA was assessed for use as a landfill liner-soil material. Batch adsorption, low temperature N2adsorption, and TG-DTA tests were performed to evaluate the adsorption capacity, micropore structure, thermostability, and components of soils under Cr(VI) and Pb(II) chemical solutions. With the increasing amount of SSA in modified clay, the adsorption capacity of Cr(VI) and Pb(II) to the modified clay increases gradually. After absorption, the pore size of modified clay ranges from 2 nm to 8 nm. With the increasing amount of absorption, the pore volume decreases and the specific surface area increases. With the increasing of adsorption concentration of Cr(VI) and Pb(II), the mass loss percentage of modified clay increases to 23.4% and 12.6%, respectively. The modified clay containing SSA may be used as a good barrier material to attenuate contamination of Cr(VI) and Pb(II) in landfills.

Lateritic Soil Treated with Waste Wood Ash As Liner in Landfill Construction

2019 ◽  
Vol 25 (2) ◽  
pp. 127-139 ◽  
Author(s):  
Johnson R. Oluremi ◽  
Adrian O. Eberemu ◽  
Stephen T. Ijimdiya ◽  
Kolawole J. Osinubi
Keyword(s):  
Compressive Strength ◽  
Hydraulic Conductivity ◽  
Unconfined Compressive Strength ◽  
Wood Ash ◽  
Engineering Properties ◽  
Volumetric Shrinkage ◽  
Lateritic Soil ◽  
Waste Wood ◽  
K Value ◽  
British Standard

ABSTRACTInherent variability in engineering properties of lateritic soil in relation to its plasticity, permeability, strength, workability, and natural moisture content, has made it an unpredictable material for use in civil engineering works, resulting in the need for its treatment by stabilization. A lateritic soil classified as A-6(6) and CL, according to American Association of State Highway and Transportation Officials and Unified Soil Classification System of ASTM (2011), was treated with up to 10 percent waste wood ash (WWA). Compaction was carried out using four energies, namely, reduced British Standard light, British Standard light (BSL), West African Standard, and British Standard heavy, on samples, which were then examined for hydraulic conductivity, volumetric shrinkage, and unconfined compressive strength as major criteria for use as liner and for the development of acceptable zones. Specimens with 4 percent WWA content compacted with a minimum BSL energy satisfied the maximum hydraulic conductivity (k) value of 1 × 10−9 m/s, maximum volumetric shrinkage strain of 4 percent, and minimum unconfined compressive strength value of 200 kN/m2 required for use as liner in engineered landfills. The overall acceptable zone was enlarged for up to 4 percent WWA content, thereby accommodating higher moulding water content, but the minimum compactive effort required to achieve it became reduced. The beneficial treatment of lateritic soil with up to 4 percent WWA will perform satisfactorily as liner and covers in waste containment application and will minimize the pollution and environmental impact of wood waste disposal.

scholarly journals Effect of Rice Husk Ash on the Hydraulic Conductivity and Unconfined Compressive Strength of Compacted Bentonite Enhanced Waste Foundry Sand

2020 ◽  
Vol 5 (1) ◽  
pp. 85-96
Author(s):  
J. Ochepo
Keyword(s):  
Compressive Strength ◽  
Hydraulic Conductivity ◽  
Rice Husk ◽  
Unconfined Compressive Strength ◽  
Rice Husk Ash ◽  
Foundry Sand ◽  
Liner Material ◽  
British Standard ◽  
Compacted Bentonite ◽  
Waste Foundry Sand

A laboratory study of the hydraulic conductivity, (HC), and unconfined compressive strength, (UCS), of compacted bentonite enhanced waste foundry sand (BEWFS) treated with rice husk ash, (RHA) for possible use as liner material is presented. The bentonite enhanced waste foundry sand, BEWFS, was obtained by blending waste foundry sand (WFS) with 12% bentonite by weight of the WFS and mixing the resulting blend thoroughly to obtain a homogenous mix. RHA was added to the BEWFS in increment of 2, 4, 6, 8 and 10% respectively of the dry weight of the BEWFS. The entire blended material was thoroughly mix together to obtain sample with different content of RHA. Index tests, compaction, UCS and HC tests were carried out on the blended materials to determine the effect of RHA on the behaviour of the BEWFS. HC as well as UCS of the materials were study using three compactive efforts of British standard light, (BSLC), West African standard, (WASC) and British standard heavy, (BSHC) compactive efforts respectively. The results obtained show that addition of RHA to BEWFS affected the index properties of the material marginally where the liquid limit increased to 35 from 32 %, plastic limit reduced from 12 to 11% and plasticity index increased from 20 to 25% respectively. The HC of the material was found to increase slightly from 6.28 x 10-08 to 3.90 x 10-08, 2.64 x 10-09 to 2.07 x 10-08 and 8.55 x 10-11 to 1.83 x 10-10 m/s with addition of up to 10 % RHA content and compacted at BSLC, WASC and BSHC respectively. Similarly, the UCS was found to increase to peak values of 177.22, 288.48 and 454.26 kN/m2 at same RHA content and compactive efforts. The implication of this result is that the addition of RHA up to 10% to BEWFS slightly increase the HC but does not compromise it while the strength gain in term of UCS can be said to compensate for the slight lost in HC. It is recommended that BEWFS treated with between 8 to 10% RHA content and compacted at BSHC compactive effort can be applied as liner in engineered waste containment system.

scholarly journals Stormwater Runoff Treatment Using Pervious Concrete Modified with Various Nanomaterials: A Comprehensive Review

2021 ◽  
Vol 13 (15) ◽  
pp. 8552
Author(s):  
Vahid Alimohammadi ◽  
Mehdi Maghfouri ◽  
Delaram Nourmohammadi ◽  
Pejman Azarsa ◽  
Rishi Gupta ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Compressive Strength ◽  
Adsorption Capacity ◽  
Removal Rate ◽  
Stormwater Runoff ◽  
Infiltration Rate ◽  
Stormwater Treatment ◽  
Adsorption Mechanisms ◽  
Wide Range ◽  
Adsorption Processes

Clean water is a vital need for all living creatures during their lifespan. However, contaminated stormwater is a major issue around the globe. A wide range of contaminants, including heavy metals, organic and inorganic impurities, has been discovered in stormwater. Some commonly utilized methods, such as biological, physical and chemical procedures, have been considered to overcome these issues. However, these current approaches result in moderate to low contaminant removal efficiencies for certain classes of contaminants. Of late, filtration and adsorption processes have become more featured in permeable concretes (PCs) for the treatment of stormwater. As nanoparticles have vast potential and unique characterizations, such as a higher surface area to cure polluted stormwater, employing them to improve permeable concretes’ capabilities in stormwater treatment systems is an effective way to increase filtration and adsorption mechanisms. The present study reviews the removal rate of different stormwater contaminants such as heavy metals, organic and other pollutants using nanoparticle-improved PC. The application of different kinds of nanomaterials in PC as porous media to investigate their influences on the properties of PC, including the permeability rate, compressive strength, adsorption capacity and mix design of such concrete, was also studied. The findings of this review show that different types of nanomaterials improve the removal efficiency, compressive strength and adsorption capacity and decrease the infiltration rate of PC during the stormwater treatment process. With regard to the lack of comprehensive investigation concerning the use of nanomaterials in PC to treat polluted stormwater runoff, this study reviews 242 published articles on the removal rate of different stormwater contaminants by using PC improved with nanoparticles.

scholarly journals Fly Ash Coated with Magnetic Materials: Improved Adsorbent for Cu (II) Removal from Wastewater

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 63
Author(s):  
Maria Harja ◽  
Gabriela Buema ◽  
Nicoleta Lupu ◽  
Horia Chiriac ◽  
Dumitru Daniel Herea ◽  
...  
Keyword(s):  
Fly Ash ◽  
Adsorption Capacity ◽  
Copper Ions ◽  
Synthetic Wastewater ◽  
Bet Surface Area ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Copper Adsorption ◽  
X Ray

Fly ash/magnetite material was used for the adsorption of copper ions from synthetic wastewater. The obtained material was characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) surface area, and vibrating sample magnetometer (VSM). Batch adsorption experiments were employed in order to investigate the effects of adsorbent dose, initial Cu (II) concentration and contact time over adsorption efficiency. The experimental isotherms were modeled using Langmuir (four types of its linearization), Freundlich, Temkin, and Harkins–Jura isotherm models. The fits of the results are estimated according to the Langmuir isotherm, with a maximum adsorption capacity of 17.39 mg/g. The pseudo-second-order model was able to describe kinetic results. The data obtained throughout the study prove that this novel material represents a potential low-cost adsorbent for copper adsorption with improved adsorption capacity and magnetic separation capability compared with raw fly ash.

Rapid determination of soil unconfined compressive strength using reflectance spectroscopy

2021 ◽  
Vol 80 (5) ◽  
pp. 3923-3938
Author(s):  
Fatemeh Mousavi ◽  
Ehsan Abdi ◽  
Parviz Fatehi ◽  
Abbas Ghalandarzadeh ◽  
Hossein Ali Bahrami ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Unconfined Compressive Strength ◽  
Rapid Determination ◽  
Reflectance Spectroscopy

scholarly journals Compression and Strain Predictive Models in Non-Structural Recycled Concretes Made from Construction and Demolition Wastes

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3177
Author(s):  
Evelio Teijón-López-Zuazo ◽  
Jorge López-Rebollo ◽  
Luis Javier Sánchez-Aparicio ◽  
Roberto Garcia-Martín ◽  
Diego Gonzalez-Aguilera
Keyword(s):  
Compressive Strength ◽  
Predictive Models ◽  
Unconfined Compressive Strength ◽  
Image Correlation ◽  
Peak Strain ◽  
Compression Tests ◽  
Maximum Peak ◽  
3D Digital Image Correlation ◽  
Granulometric Analysis ◽  
Physical And Chemical

This work aims to investigate different predictive models for estimating the unconfined compressive strength and the maximum peak strain of non-structural recycled concretes made up by ceramic and concrete wastes. The extensive experimental campaign carried out during this research includes granulometric analysis, physical and chemical analysis, and compression tests along with the use of the 3D digital image correlation as a method to estimate the maximum peak strain. The results obtained show that it is possible to accurately estimate the unconfined compressive strength for both types of concretes, as well as the maximum peak strain of concretes made up by ceramic waste. The peak strain for mixtures with concrete waste shows lower correlation values.

scholarly journals Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO2: Promising Waste-Derived Adsorbents for Balofloxacin

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2295
Author(s):  
Marwa El-Azazy ◽  
Ahmed S. El-Shafie ◽  
Hagar Morsy
Keyword(s):  
Adsorption Capacity ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Spent Coffee Grounds ◽  
Thermal Stabilities ◽  
Coffee Grounds ◽  
Bet Analysis ◽  
Pseudo Second Order ◽  
Set Up ◽  
Adsorption Desorption

Biochars (BC) of spent coffee grounds, both pristine (SCBC) and impregnated with titanium oxide (TiO2@SCBC) were exploited as environmentally friendly and economical sorbents for the fluroquinolone antibiotic balofloxacin (BALX). Surface morphology, functional moieties, and thermal stabilities of both adsorbents were scrutinized using SEM, EDS, TEM, BET, FTIR, Raman, and TG/dT analyses. BET analysis indicated that the impregnation with TiO2 has increased the surface area (50.54 m2/g) and decreased the pore size and volume. Batch adsorption experiments were completed in lights of the experimental set-up of Plackett-Burman design (PBD). Two responses were maximized; the % removal (%R) and the adsorption capacity (qe, mg/g) as a function of four variables: pH, adsorbent dosage (AD), BALX concentration ([BALX]), and contact time (CT). %R of 68.34% and 91.78% were accomplished using the pristine and TiO2@SCBC, respectively. Equilibrium isotherms indicated that Freundlich model was of a perfect fit for adsorption of BALX onto both adsorbents. Maximum adsorption capacity (qmax) of 142.55 mg/g for SCBC and 196.73 mg/g for the TiO2@SCBC. Kinetics of the adsorption process were best demonstrated using the pseudo-second order (PSO) model. The adsorption-desorption studies showed that both adsorbents could be restored with the adsorption efficiency being conserved up to 66.32% after the fifth cycles.

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