scholarly journals Adsorption Mechanism of Ciprofloxacin from Water by Synthesized Birnessite

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Xuebing Xing ◽  
Jingwen Feng ◽  
Guocheng Lv ◽  
Kenan Song ◽  
Lefu Mei ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Quantum Mechanics ◽  
Contact Time ◽  
Adsorption Mechanism ◽  
Surface Adsorption ◽  
Oxidation States ◽  
Alkaline Condition ◽  
X Ray Diffraction ◽  
Solution Ph ◽  
X Ray

The efficiency of ciprofloxacin (CIP) adsorption on synthesized birnessite was systematically studied under varying physicochemical conditions, such as solution pH, contact time, initial CIP concentration, and different average oxidation states (AOS) of Mn in birnessite. X-ray diffraction (XRD), Fourier transform infrared (FTIR), and molecular simulations were employed to investigate the adsorption mechanism of CIP on birnessite. Experimental results showed that surface adsorption instead of cation exchange was responsible for the uptake of CIP on birnessite. The quantum mechanics simulation showed that the final energy of the interaction between CIP and birnessite was smaller under the condition when the AOS of Mn was lower, in comparison to the case when the AOS of Mn was high. The highest CIP adsorption occurred under a weak alkaline condition.

Biosorption of Zn(II) from Aqueous Solution by Amusium pleuronectes Shell

2016 ◽  
Vol 675-676 ◽  
pp. 7-10
Author(s):  
K. Chantarasunthon ◽  
Kanyakorn Teanchai ◽  
Wichian Siriprom
Keyword(s):  
Aqueous Solution ◽  
Experimental Investigation ◽  
Contact Time ◽  
Physical Adsorption ◽  
Absorption Capacity ◽  
X Ray Diffraction ◽  
Batch Method ◽  
Solution Ph ◽  
X Ray ◽  
High Level

In this study, the experimental investigation and assessment the absorption capacity for Zn ion with Amusium Pleuronectes shell. The investigations were carried out by batch method and variables of the batch experiment include solution pH, Contact time, were determind. The mechanism of bisorption is chemisorption or/and physical adsorption was confirmed by X-ray Diffraction (XRD) and Energy Dispersive X-ray Fluorescence (EDXRF). The results showed that the Amusium Pleuronectes shell has a high level of absorption capacity for Zn (II) ions. Another that result of mechanism of biosorption suggests and confirm with the result of XRD and EDXRF.

scholarly journals Effect of Aeration Treatment on Methylene Blue Removal Using TiO2-Zeolite

2019 ◽  
Vol 2 ◽  
pp. 219-224
Author(s):  
Nanda Alzeta Pratama ◽  
Pedy Artsanti
Keyword(s):  
Methylene Blue ◽  
Fourier Transform ◽  
Contact Time ◽  
Fourier Transform Infrared ◽  
Absolute Ethanol ◽  
X Ray Diffraction ◽  
X Ray ◽  
Methylene Blue Removal ◽  
Ft Ir

Effect of aeration treatment on Methylene Blue (MB) removal using TiO2-Zeolite has been investigated. The TiO2-Zeolite was prepared by mixing activated zeolite and TiO2 in absolute ethanol. This composite was characterized using Fourier Transform Infrared (FT-IR) and X-Ray Diffraction (XRD). The MB removal was monitored spectrophotometrically. The effect of contact time, composite mass, and aeration treatment on MB removal was observed. Characterization results showed that there was interaction between TiO2 and SiO/AlO of zeolite. The observation of aeration treatment using oxygen exhibited significant improving on MB removal.

scholarly journals Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite

2016 ◽  
Vol 10 (1) ◽  
pp. 17-23 ◽  
Author(s):  
Tamara Minovic-Arsic ◽  
Ana Kalijadis ◽  
Branko Matovic ◽  
Milovan Stoiljkovic ◽  
Jelena Pantic ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Mechanism ◽  
Nitrogen Adsorption ◽  
Ion Concentration ◽  
X Ray Diffraction ◽  
Solution Ph ◽  
X Ray ◽  
Liquid Phase Adsorption ◽  
Bet Isotherm ◽  
Carbon Cryogel

Carbon cryogel/ceria composite, with 10 wt.% of ceria, was synthesized by mixing of ceria and carbon cryogel (CC). The sample was characterized by field emission scanning electron microscopy, nitrogen adsorption and X-ray diffraction. The adsorption of arsenic(III) ions from aqueous solutions on carbon cryogel/ceria nanocomposite was studied as a function of time, solution pH and As(III) ion concentration. The results are correlated with previous investigations of adsorption mechanism of arsenic(III) on carbon cryogel. Adsorption dose experiments showed that the mass of the adsorbent was reduced for 20 times, in comparison with pure CC, for the same amount of adsorbed arsenic(III) ions. BET isotherm was used to interpret the experimental data for modelling liquid phase adsorption.

scholarly journals Uji Efektivitas dan Karakterisasi Komposit Tanah Andisol/Arang Tempurung Kelapa Untuk Adsorpsi Logam Berat Besi (Fe)

2020 ◽  
Vol 16 (1) ◽  
pp. 50
Author(s):  
Pranoto Pranoto ◽  
Tri Martini ◽  
Winda Maharditya
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Atomic Absorption Spectroscopy ◽  
Contact Time ◽  
Coconut Shell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

<p>Penelitian ini untuk mengetahui kapasitas adsorpsi komposit tanah andisol/arang tempurung kelapa sebagai adsorben logam berat besi (Fe) berdasarkan pada kondisi komposisi, pH dan waktu kontak yang optimum. Tanah andisol diaktivasi dengan larutan NaOH 3 M dan arang tempurung kelapa diaktivasi menggunakan larutan HCl 4 M. Komposit tanah andisol/arang tempurung kelapa dibuat dengan mencampurkan tanah andisol dan arang tempurung kelapa pada variasi komposisi 100:0, 75:25, 50:50, 25:75 dan 0:100 (b/b) Uji adsorpsi terhadap logam besi (Fe) dilakukan pada variasi pH larutan 1, 2, 3, 4, 5 dan 6 serta waktu kontak 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, dan 60 menit dengan sistem <em>batch</em>. Pengukuran konsentrasi akhir pada saat kesetimbangan dilakukan dengan menggunakan <em>Atomic Absorption Spectroscopy</em> (AAS).  Hasil karakterisasi adanya proses aktivasi dan pengompositan ditunjukkan pada spektra <em>Fourier Transform Infra Red</em> (FTIR) yang mengalami pergeseran bilangan gelombang. Karakterisasi pola difraksi <em>X-Ray Diffraction</em> (XRD) yang menunjukkan adanya puncak baru. Hasil analisis <em>Scanning Electron Microscope </em>(SEM) komposit menunjukkan bahwa permukaan adsorben telah ditutupi logam besi (Fe). Pembentukan komposit juga menunjukkan adanya peningkatan luas permukaan dan nilai keasaman komposit. Berdasarkan penelitian ini diperoleh bahwa proses adsorpsi terjadi pada kondisi optimum komposisi komposit tanah andisol/arang tempurung kelapa 75:25 (b/b), pH larutan besi (Fe) 5 dan waktu kontak selama 30 menit dengan kapasitas adsorpsi sebesar 0,54 mg/g dan presentase adsorpsi 91,57%. Isoterm adsorpsi mengikuti isoterm Freundlich dengan nilai R<sup>2</sup> sebesar 0,9456.</p><p><strong>Effectiveness Test and Characterization of Andisol Soil/Coconut Shell Charcoal for Adsorption of Iron (Fe).</strong> This research aims to determine the adsorption capacity composite of andisol soil and coconut shell charcoal as the adsorbent of iron (Fe) metal based on the composition condition, pH, and optimum contact time. Andisol soil was activated with NaOH 3 M solution, and coconut shell charcoal was activated with HCl 4 M solution. The composites were made under various composition of andisol soil/coconut shell charcoal of 100:0, 75:25, 50:50, 25:75 and 0:100 (w/w). The adsorption test was done on the pH variation of 1, 2, 3, 4, 5, 6 and used the contact time variation of 5, 10, 15, 20, 25, 30, 35, 40, 45, 50 and 60 minutes in a batch method. The concentration analysis of iron (Fe) metal was done by atomic absorption spectroscopy (AAS). The characterization result of the activation process can be shown on the Fourier transform infrared (FTIR) spectra with the shifting peak. Characterization of X-ray diffraction (XRD) diffractogram showed the emergence of a new peak in andisol soil and coconut shell charcoal. The result of scanning electron microscope (SEM) characterization analysis showed that the surface of the adsorbent was covered in iron. The composite formation also showed an increase in surface area and composite acidity value. Based on the result of the research, it can be concluded that the adsorption process happens in the optimum condition in andisol soil/coconut shell charcoal composition of 75:25 (w/w), pH solution iron (Fe) metal of 5 and contact time of 30 minutes. The adsorption capacity was 0.54 mg/g and 91.57% for adsorption percentage. The isotherm adsorption followed Freundlich isotherm with R<sup>2</sup> values 0.9456.</p>

scholarly journals Degradation of Tetracycline by Birnessite under Microwave Irradiation

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Meng Liu ◽  
Guocheng Lv ◽  
Lefu Mei ◽  
Xiaoyu Wang ◽  
Xuebing Xing ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Fourier Transform ◽  
Microwave Irradiation ◽  
X Ray Diffraction ◽  
Visible Spectroscopy ◽  
Acidic Media ◽  
Solution Ph ◽  
Factors Affecting ◽  
X Ray ◽  
Structure Degradation

The efficiency and factors affecting tetracycline (TC) degradation by birnessite under microwave irradiation (MI) were investigated under different initial TC concentrations, solution pH, MI time, and MI power. The crystal structure, degradation efficiency, and reaction mechanism were investigated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and ultraviolet-visible spectroscopy (UV-Vis). The results showed that birnessite was an excellent microwave catalyst. The maximum TC removal efficiency by birnessite was 99% under MI at 400 W for 30 min in strongly acidic media. Under MI, the surface activity of birnessite increased, resulting in the ability to accelerate TC removal in high temperature.

scholarly journals Sorption of Pb(II) from Aqueous Solutions by Acid-Modified Clinoptilolite-Rich Tuffs with Different Si/Al Ratios

2019 ◽  
Vol 9 (12) ◽  
pp. 2415 ◽  
Author(s):  
Mohamed Abatal ◽  
Atl V. Córdova Quiroz ◽  
María T. Olguín ◽  
América R. Vázquez-Olmos ◽  
Joel Vargas ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Contact Time ◽  
Point Of Zero Charge ◽  
X Ray Diffraction ◽  
Solution Ph ◽  
Batch Studies ◽  
X Ray ◽  
Pseudo Second Order ◽  
Modified Clinoptilolite ◽  
Adsorbent Dose

The removal of Pb(II) from aqueous solutions by acid-modified clinoptilolite-rich tuff was investigated in this work. Clinoptilolite-rich tuff samples were treated using H2SO4 at different concentrations. Prior to and following acid treatment, the samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and Fourier-transform infrared spectroscopy (FTIR). The pH of the point of zero charge (pHPZC) was also determined as part of this characterization. Batch studies were studied to investigate Pb(II) removal as a function of contact time, initial Pb(II) concentration, adsorbent dosage, and solution pH. The results of the XRD and SEM techniques showed that clinoptilolite is the main mineral of the non- and acid-treated natural zeolite samples. However, EDS analysis indicated that the Si/Al ratio increases as the exchangeable ions decrease with increasing acid concentrations. The optimum conditions for Pb(II) removal for samples with 4.37 ≤ Si/Al ≤ 7.9 were found to be as follows: Contact time of 60–360 min, pH: 6–8, and adsorbent dose of 6 mg g−1; whereas for acid-modified clinoptilolite-rich tuffs with 9.01 ≤ Si/Al ≤ 9.52, these conditions were as follows: Contact time of 1440 min, pH: 8–10, and adsorbent dose of 10 mg g−1. The experimental data were analyzed by kinetic and isotherms models. The results showed that the sorption of Pb(II) on samples with Si/Al ratios of 4.37, 5.31, and 7.91 were in agreement with the pseudo-second order and Langmuir isotherm with qm = 48.54, 37.04, and 14.99 mg g−1, respectively, while the kinetic data and isotherm for samples with 9.01 ≤ Si/Al ≤ 9.52 were found to fit the pseudo-first order and Freundlich model.

scholarly journals Uji Efektivitas dan Karakterisasi Komposit Tanah Andisol/Arang Tempurung Kelapa Untuk Adsorpsi Logam Berat Besi (Fe)

2020 ◽  
Vol 16 (1) ◽  
pp. 50
Author(s):  
Pranoto Pranoto ◽  
Tri Martini ◽  
Winda Maharditya
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Atomic Absorption Spectroscopy ◽  
Contact Time ◽  
Coconut Shell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

<p>Penelitian ini untuk mengetahui kapasitas adsorpsi komposit tanah andisol/arang tempurung kelapa sebagai adsorben logam berat besi (Fe) berdasarkan pada kondisi komposisi, pH dan waktu kontak yang optimum. Tanah andisol diaktivasi dengan larutan NaOH 3 M dan arang tempurung kelapa diaktivasi menggunakan larutan HCl 4 M. Komposit tanah andisol/arang tempurung kelapa dibuat dengan mencampurkan tanah andisol dan arang tempurung kelapa pada variasi komposisi 100:0, 75:25, 50:50, 25:75 dan 0:100 (b/b) Uji adsorpsi terhadap logam besi (Fe) dilakukan pada variasi pH larutan 1, 2, 3, 4, 5 dan 6 serta waktu kontak 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, dan 60 menit dengan sistem <em>batch</em>. Pengukuran konsentrasi akhir pada saat kesetimbangan dilakukan dengan menggunakan <em>Atomic Absorption Spectroscopy</em> (AAS).  Hasil karakterisasi adanya proses aktivasi dan pengompositan ditunjukkan pada spektra <em>Fourier Transform Infra Red</em> (FTIR) yang mengalami pergeseran bilangan gelombang. Karakterisasi pola difraksi <em>X-Ray Diffraction</em> (XRD) yang menunjukkan adanya puncak baru. Hasil analisis <em>Scanning Electron Microscope </em>(SEM) komposit menunjukkan bahwa permukaan adsorben telah ditutupi logam besi (Fe). Pembentukan komposit juga menunjukkan adanya peningkatan luas permukaan dan nilai keasaman komposit. Berdasarkan penelitian ini diperoleh bahwa proses adsorpsi terjadi pada kondisi optimum komposisi komposit tanah andisol/arang tempurung kelapa 75:25 (b/b), pH larutan besi (Fe) 5 dan waktu kontak selama 30 menit dengan kapasitas adsorpsi sebesar 0,54 mg/g dan presentase adsorpsi 91,57%. Isoterm adsorpsi mengikuti isoterm Freundlich dengan nilai R<sup>2</sup> sebesar 0,9456.</p><p><strong>Effectiveness Test and Characterization of Andisol Soil/Coconut Shell Charcoal for Adsorption of Iron (Fe).</strong> This research aims to determine the adsorption capacity composite of andisol soil and coconut shell charcoal as the adsorbent of iron (Fe) metal based on the composition condition, pH, and optimum contact time. Andisol soil was activated with NaOH 3 M solution, and coconut shell charcoal was activated with HCl 4 M solution. The composites were made under various composition of andisol soil/coconut shell charcoal of 100:0, 75:25, 50:50, 25:75 and 0:100 (w/w). The adsorption test was done on the pH variation of 1, 2, 3, 4, 5, 6 and used the contact time variation of 5, 10, 15, 20, 25, 30, 35, 40, 45, 50 and 60 minutes in a batch method. The concentration analysis of iron (Fe) metal was done by atomic absorption spectroscopy (AAS). The characterization result of the activation process can be shown on the Fourier transform infrared (FTIR) spectra with the shifting peak. Characterization of X-ray diffraction (XRD) diffractogram showed the emergence of a new peak in andisol soil and coconut shell charcoal. The result of scanning electron microscope (SEM) characterization analysis showed that the surface of the adsorbent was covered in iron. The composite formation also showed an increase in surface area and composite acidity value. Based on the result of the research, it can be concluded that the adsorption process happens in the optimum condition in andisol soil/coconut shell charcoal composition of 75:25 (w/w), pH solution iron (Fe) metal of 5 and contact time of 30 minutes. The adsorption capacity was 0.54 mg/g and 91.57% for adsorption percentage. The isotherm adsorption followed Freundlich isotherm with R<sup>2</sup> values 0.9456.</p>

The Study of the Removal of Cu(II) from Aqueous Solution by Papia undulates Shell

2016 ◽  
Vol 675-676 ◽  
pp. 664-666
Author(s):  
Noppadon Chamchoi ◽  
Narong Sangwaranatee ◽  
Jakrapong Kaewkhao ◽  
K. Teanchai ◽  
Wichian Siriprom
Keyword(s):  
Aqueous Solution ◽  
Contact Time ◽  
Experimental Result ◽  
X Ray Diffraction ◽  
Solution Ph ◽  
Factors Affecting ◽  
X Ray ◽  
Mixture Phase ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

In present study, the removal of Cu (II) ions from aqueous solution was investigated by both biosorption and investigated by X-ray Diffraction (XRD), Energy Dispersive X-ray Fluorescence (EDXRF) and Fourier transform infrared (FT-IR) spectroscopy. The variable of the batch experiment include solution pH, content time, were conducted to determine the factors affecting capacities sorption of Cu (II). The experimental result explored that that the maximum pH for efficient sorption of Cu (II) was 9. The optimum condition of sorption were found to be contact time of 180 min, and initial Cu concentration 200 mg/L, while the result of XRD reveal that the Paphia undulate shell have aragonite phase and change to mixture phase after sorption which corresponding, with the result of EDXRF which increasing the concentration of Cu

PENGGUNAAN TiO2 PARTIKEL NANO HASIL SINTESIS BERBASIS AIR MENGGUNAKAN METODA SOL-GEL PADA BAHAN KAPAS SEBAGAI APLIKASI UNTUK TEKSTIL ANTI UV

Arena Tekstil ◽  
2013 ◽  
Vol 28 (1) ◽  
Author(s):  
Maya Komalasari ◽  
Bambang Sunendar
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Sol Gel ◽  
Crosslinking Agent ◽  
X Ray Diffraction ◽  
Nano Tio2 ◽  
X Ray ◽  
Infra Red ◽  
Scanning Electron

Partikel nano TiO2 berbasis air dengan pH basa telah berhasil disintesis dengan menggunakan metode sol-gel dan diimobilisasi pada kain kapas dengan menggunakan kitosan sebagai zat pengikat silang. Sintesis dilakukan  dengan prekursor TiCl4 pada konsentrasi 0,3 M, 0,5 M dan 1 M, dan menggunakan templat kanji dengan proses kalsinasi pada suhu 500˚C selama 2 jam. Partikel nano TiO2 diaplikasikan ke kain kapas dengan metoda pad-dry-cure dan menggunakan kitosan sebagai crosslinking agent. Berdasarkan hasil Scanning Electron Microscope (SEM),diketahui bahwa morfologi partikel TiO2 berbentuk spherical dengan ukuran nano (kurang dari 100 nm). Karakterisasi X-Ray Diffraction (XRD) menunjukkan adanya tiga tipe struktur kristal utama, yaitu (100), (101) dan (102) dengan fasa kristal yang terbentuk adalah anatase dan rutile. Pada karakterisasi menggunakan SEM terhadap serbuk dari TiO2 yang telah diaplikasikan ke permukaan kain kapas, terlihat adanya imobilisasi partikel nano TiO2 melalui ikatan hidrogen silang dengan kitosan pada kain kapas. Hasil analisa tersebut kemudian dikonfirmasi dengan FTIR (Fourier Transform Infra Red) yang hasilnya memperlihatkan puncak serapan pada bilangan gelombang 3495 cm-1, 2546 cm-1, dan 511 cm-1,  yang masing-masing diasumsikan sebagai adanya vibrasi gugus fungsi O-H, N-H dan Ti-O-Ti. Hasil SEM menunjukkan pula bahwa kristal nano yang terbentuk diantaranya adalah fasa rutile , yang berdasarkan literatur terbukti dapatberfungsi sebagai anti UV.

PENINGKATAN LAJU DISOLUSI ACYCLOVIR DENGAN METODE SISTEM DISPERSI PADAT MENGGUNAKAN POLOXAMER 188

2016 ◽  
Vol 5 (1) ◽  
pp. 6
Author(s):  
Budi Setiawan ◽  
Erizal Zaini ◽  
Salman Umar
Keyword(s):  
Electron Microscopy ◽  
Thermal Analysis ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
Differential Thermal Analysis ◽  
Fourier Transform Infrared ◽  
X Ray Diffraction ◽  
Poloxamer 188 ◽  
X Ray ◽  
Scanning Electron

Sebuah penelitian tentang sistem dispersi padat dari asiklovir dengan poloxamer 188 telah dilakukan formulasi dengan pencampuran secara fisika dengan rasio 1 : 1, 1 : 3, 1 : 5 dan dispersi padat 1 : 1, 1 : 3, 1 : 5 dan penggilingan 1:1 sebagai pembanding. Dispersi padat dibuat menggunakan metode pencairan (fusi), yang digabung dengan poloxamer 188 pada hotplate kemudian asiklovir dimasukkan ke dalam hasil poloxamer 188 lalu di kocok hingga membentuk masa homogen. Semua formula yang terbentuk termasuk asiklovir poloxamer 188 murni dianalisis karakterisasinya dengan Differential Thermal Analysis (DTA), X-ray Diffraction, Scanning Electron Microscopy (SEM), dan Fourier Transform Infrared (FTIR), kemudian pengambilan dilakukan  (penentuan kadar) mengunakan spektrofotometer UV pada panjang gelombang 257,08 nm dan uji laju disolusi dengan aquadest bebas CO2 menggunakan metode dayung. Hasil pengambilan  (penentuan kadar) menunjukkan bahwa semua formula memenuhi persyaratan farmakope Amerika edisi 30 dan farmakope Indonesia edisi 4 yaitu 95-110%. Sedangkan hasil uji laju disolusi untuk campuran fisik 1: 1, dan dispersi padat 1: 1, dan penggilingan 1: 1 menunjukkan peningkatan yang nyata dibandingkan asiklovir murni. Hal ini juga dapat dilihat dari hasil perhitungan statistik  menggunakan analisis varian satu arah  SPSS 17.

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